Research Article
Sulu Çözeltilerden Fosfor Gideriminde Demir ile Kaplanmış Aktif Karbonun Kullanılabilirliğinin Araştırılması
Abstract
Fosfor canlılar için temel bir nütrient olmasının yanı sıra sucul ortamlarda çok düşük konsantrasyonlarda ötröfikasyon adı verilen çevresel bir probleme sebep olmaktadır. Bu araştırmada ticari olarak satışı olan aktif karbon malzemesi demir ile kaplanarak sentezlenen yeni malzeme (DKK) ile fosfor giderimi araştırılmıştır. Yapılan laboratuvar çalışmaları sonucunda DKK’nın sulu çözeltilerde fosfor gideriminde işlevsel olarak kullanılabileceği anlaşılmıştır. Ayrıca malzemenin fosfor tutma kapasitesinin 4,26 mg PO43-/g DKK olduğu tespit edilmiştir. Adsorpsiyonun Langmuir matematiksel modeline uyduğu ve üretim için uygun şartların sağlanması ile birlikte ticari olarak üretiminin gerçekleştirilerek fosfor gideriminde yaygın olarak kullanılabileceği sonucuna varılmıştır.
References
- 1. Choi, J., Lee, S., Park, K., Lee, K., Kim, D., Lee, S., 2011. Investigation of Phosphorous Removal From Wastewater Through Ion Exchange of Mesostructure Based on İnorganic Material. Desalination, 266, 281-285.
- 2. Novillo, C., Guaya, D., Allen-Perkins Avendaňo, A., Armijos, C., Cortina, J.L., Cota, I., 2014. Evaluation of Phosphate Removal Capacity of Mg/Al Layered Double Hydroxides from Aqueos Solutions. Fuel, 138, 72-79.
- 3. Koh, K.Y., Wang, C., Chen, J.P, 2019. A New Adsorbent of GAdolinium-1,4-benzenedicarboxylate Composite for Better Phosphorous Removal in Aqueous Solutions. Journal of Colloidal and Interface Science, 543, 343-351.
- 4. Das, J., Patra, B.S., Baliarsingh, N., Parida, KM., 2006. Adsorption of Phosphate by Layered Double Hydroxides in Aqueous Solutions. Applied Clay Science, 32, 252-260.
- 5. Föllmi, K.B., 1996. The Phosphorus Cycle, Phosphogenesis and Marine Phosphate-rich Deposits. Earth Science Reviews, 40, 55-124.
- 6. Karageorgiu, K., Paschalis, M., Anastassakis, G.N., 2007. Removal of PHOSPHATE SPECİES from Solution by Adsorption onto Calcite Used as Natural Adsorbent. Journal of Hazardous Materials, 139, 447-452.
- 7. Nur, T., Johir, M.A.H., Loganathan, P., Nguyen, T., Vigneswaran, S., Kandasamy, J., 2014. Phosphate removal from Water Using and Iron Oxide Impregnated Strong Base Anion Exhange Resin. Journal of Industrial and Engineering Chemistry. 20, 1301-1307.
- 8. Caravelli, A.H., Contreras, E.M., Zaritzky, N.E., 2010. Phosphorous Removal in Batch Systems Using Ferric Chloride in the Presence of Activated Sludges. Journal of Hazardous Materials, 177, 199-208.
- 9. Kpannieu, D.E., Mallet, M., Coulibaly, L., 2019. Phosphate Removal from Water by Naturally Occurring Shale, Sandstone and Laterite: Tehe Role of Iron Oxides and of Soluble Species, 351, 37-47.
- 10. Yin, H., Yun, Y., Zhang, Y., Fan, C., 2011. Phosphate Removal From Wastewaters by a Naturally Occurring, Calcium-rich Sepiolite. Journal of Hazardous Materials, 198, 362-369.
- 11. Kuzawa, K., Jung, Y., Kiso, Y., Yamada, T., Nagai, M., Lee, T., 2006. Phosphate Removal and Recovery with a Synthetic Hydrotalcite as an Adsorbent. Chemosphere, 62, 45-52.
- 12. Zhong-Liang, S., Fu-Mei, L., Shu-Hua, Y., 2011. Adsorptive Removal of Phosphate from Aqueous Solutions Using Activated Carbon Loaded with Fe(III) Oxide. New Carbon Material, 26(4), 299-306.
- 13. Zhang, L., Liu, J., Guo, X., 2018. Investigation on Mechanism of Phosphate Removal on Carbonized Sludge Adsorbent, Journal of Environmental Sciences, 64, 335-344.
- 14. Yeşiltaş, H.K., Yilmaz, T., 2018. Çift Katmanlı Hidroksitler ile Fosfor Gideriminin Araştırılması, Ç.Ü. Fen ve Mühendislik Bilimleri Dergisi, 35-8, 106-115.
- 15. Gisi, S.D., Lofrano, G., Grassi, M., Notarnicola, M., 2016. Characteristics and Adsorption Capacities of Low-cost Sorbent for Wastewater Treatment: A Review, Sustainable Materials and Technologies, 9, 10-40.
- 16. Bottani, E.J., Tascón, J.M.D., 2008. Adsorption by Carbons, Elsevier Science, 776.
- 17. Rice, E.W., Baird, R.B., Eaton, A.D., Clesceri, LS., 2012. Standard Methods for the Examination of Water and Wastewater, Washington, 1496.
- 18. Behnamfard, A., Salarirad, M.M., 2009. Equilibrium and Kinetic Studies on Free Cyanide Adsorption from Aqueous Solution by Activated Carbon. Journal of Hazardous Materials, 170, 127-133.
- 19. Barca, C., Gérente, C., Meyer, D., Chazarenc, F., Andrés, Y., 2012. Phosphate Removal from Synthetic and Real Wastewater Using Steel Slags Produced in Europe, Water Research, 40, 2376-2384.
- 20. Krishna, K.C.B., Niaz, M.R., Sarker, D.C., Jansen, T., 2017. Phosphorous Removal from Aqueous Solution Can Be Enhanced Through the Calcination of Lime Sludge, Journal of Encironmental Management, 200, 359-365.
- 21. Yang, J., Wang, S., Lu, Z., Yang, J., Lou, S., 2009. Converter Slag-coal Cinder Columns fort he Removal of Phosphorous and Other Pollutants, Journal of Hazardous Materials, 168, 331-337.
Investigation of Usability of Iron Coated Activated Carbon for Phosphorus Removal from Aqueous Solutions
Abstract
Phosphorus is a basis nutrient for living organisms, but also causes an environmental problem called eutrophication at very low concentrations in aquatic environments. In this research, the commercially available activated carbon material was coating with iron and phosphorus removal was investigated with synthesized new material (DKK). As a result of laboratory studies, it was found that DKK can be used functionally in phosphorus removal in aqueous solutions. In addition, the phosphorus holding capacity of the material was found to be 4.26 mg PO43-/g DKK. It has been concluded that adsorption complies with the Langmuir mathematical model and can be used in phosphorus removal by commercially synthesizing with appropriate conditions for production.
References
- 1. Choi, J., Lee, S., Park, K., Lee, K., Kim, D., Lee, S., 2011. Investigation of Phosphorous Removal From Wastewater Through Ion Exchange of Mesostructure Based on İnorganic Material. Desalination, 266, 281-285.
- 2. Novillo, C., Guaya, D., Allen-Perkins Avendaňo, A., Armijos, C., Cortina, J.L., Cota, I., 2014. Evaluation of Phosphate Removal Capacity of Mg/Al Layered Double Hydroxides from Aqueos Solutions. Fuel, 138, 72-79.
- 3. Koh, K.Y., Wang, C., Chen, J.P, 2019. A New Adsorbent of GAdolinium-1,4-benzenedicarboxylate Composite for Better Phosphorous Removal in Aqueous Solutions. Journal of Colloidal and Interface Science, 543, 343-351.
- 4. Das, J., Patra, B.S., Baliarsingh, N., Parida, KM., 2006. Adsorption of Phosphate by Layered Double Hydroxides in Aqueous Solutions. Applied Clay Science, 32, 252-260.
- 5. Föllmi, K.B., 1996. The Phosphorus Cycle, Phosphogenesis and Marine Phosphate-rich Deposits. Earth Science Reviews, 40, 55-124.
- 6. Karageorgiu, K., Paschalis, M., Anastassakis, G.N., 2007. Removal of PHOSPHATE SPECİES from Solution by Adsorption onto Calcite Used as Natural Adsorbent. Journal of Hazardous Materials, 139, 447-452.
- 7. Nur, T., Johir, M.A.H., Loganathan, P., Nguyen, T., Vigneswaran, S., Kandasamy, J., 2014. Phosphate removal from Water Using and Iron Oxide Impregnated Strong Base Anion Exhange Resin. Journal of Industrial and Engineering Chemistry. 20, 1301-1307.
- 8. Caravelli, A.H., Contreras, E.M., Zaritzky, N.E., 2010. Phosphorous Removal in Batch Systems Using Ferric Chloride in the Presence of Activated Sludges. Journal of Hazardous Materials, 177, 199-208.
- 9. Kpannieu, D.E., Mallet, M., Coulibaly, L., 2019. Phosphate Removal from Water by Naturally Occurring Shale, Sandstone and Laterite: Tehe Role of Iron Oxides and of Soluble Species, 351, 37-47.
- 10. Yin, H., Yun, Y., Zhang, Y., Fan, C., 2011. Phosphate Removal From Wastewaters by a Naturally Occurring, Calcium-rich Sepiolite. Journal of Hazardous Materials, 198, 362-369.
- 11. Kuzawa, K., Jung, Y., Kiso, Y., Yamada, T., Nagai, M., Lee, T., 2006. Phosphate Removal and Recovery with a Synthetic Hydrotalcite as an Adsorbent. Chemosphere, 62, 45-52.
- 12. Zhong-Liang, S., Fu-Mei, L., Shu-Hua, Y., 2011. Adsorptive Removal of Phosphate from Aqueous Solutions Using Activated Carbon Loaded with Fe(III) Oxide. New Carbon Material, 26(4), 299-306.
- 13. Zhang, L., Liu, J., Guo, X., 2018. Investigation on Mechanism of Phosphate Removal on Carbonized Sludge Adsorbent, Journal of Environmental Sciences, 64, 335-344.
- 14. Yeşiltaş, H.K., Yilmaz, T., 2018. Çift Katmanlı Hidroksitler ile Fosfor Gideriminin Araştırılması, Ç.Ü. Fen ve Mühendislik Bilimleri Dergisi, 35-8, 106-115.
- 15. Gisi, S.D., Lofrano, G., Grassi, M., Notarnicola, M., 2016. Characteristics and Adsorption Capacities of Low-cost Sorbent for Wastewater Treatment: A Review, Sustainable Materials and Technologies, 9, 10-40.
- 16. Bottani, E.J., Tascón, J.M.D., 2008. Adsorption by Carbons, Elsevier Science, 776.
- 17. Rice, E.W., Baird, R.B., Eaton, A.D., Clesceri, LS., 2012. Standard Methods for the Examination of Water and Wastewater, Washington, 1496.
- 18. Behnamfard, A., Salarirad, M.M., 2009. Equilibrium and Kinetic Studies on Free Cyanide Adsorption from Aqueous Solution by Activated Carbon. Journal of Hazardous Materials, 170, 127-133.
- 19. Barca, C., Gérente, C., Meyer, D., Chazarenc, F., Andrés, Y., 2012. Phosphate Removal from Synthetic and Real Wastewater Using Steel Slags Produced in Europe, Water Research, 40, 2376-2384.
- 20. Krishna, K.C.B., Niaz, M.R., Sarker, D.C., Jansen, T., 2017. Phosphorous Removal from Aqueous Solution Can Be Enhanced Through the Calcination of Lime Sludge, Journal of Encironmental Management, 200, 359-365.
- 21. Yang, J., Wang, S., Lu, Z., Yang, J., Lou, S., 2009. Converter Slag-coal Cinder Columns fort he Removal of Phosphorous and Other Pollutants, Journal of Hazardous Materials, 168, 331-337.
There are 21 citations in total.
Details
| Primary Language | Turkish |
|---|---|
| Journal Section | Articles |
| Authors | |
| Publication Date | December 31, 2019 |
| Published in Issue | Year 2019 Volume: 34 Issue: 4 |