Research Article
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Synthesis and characterization of a new 2D-imine-linked covalent organic framework

Year 2020, Volume: 4 Issue: 2, 171 - 178, 31.12.2020

Lalehan Akyüz

https://doi.org/10.32571/ijct.766866

Abstract

Kovalent Organik Yapılar (COF), geniş yüzey alanına ve kimyasal stabiliteye sahip organik polimerik malzemeler olarak tanımlanan, olağanüstü gözenekli katı maddelerdir. COF bileşikleri nanoteknoloji uygulamaları için geniş çapta incelenmektedir. Ek olarak, yarı iletken teknolojilerinde ve ilaç taşıyıcı sistemlerde de kullanılabilirliği konusunda uygulamalar vardır.
Bu proje kapsamında Triformilbenzen (TFB) ve 3,3’,5,5’-tetrametil benzidin (TMB) kullanılarak, daha önce literatürde yer almayan yeni bir kovalent organik kafes (covalent organic framework-COF) yapısı sentezlenmiştir. Sentezlenen bileşik (LA-COF-2) iki boyutlu imin bağlı COF bileşiğidir. Sentezlenen COF bileşiği FT-IR, SEM, TGA, XRD ve elementel analiz kullanılarak karakterize edilmiştir. Sentezlenen bileşik yaklaşık 200 nm boyutunda agrega olmuş taneciklerden oluşmaktadır. Termal kararlılığı yüksek ve literatür ile uyumludur. LA-COF-2 bileşiği baz, DMA ve suya karşı kararlılığını korumuştur.

Keywords

synthesis characterization COF

Supporting Institution

Aksaray Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Bİrimi

Project Number

2018-025

Thanks

This work was supported by Aksaray University Research Fund for financial support through Project numbers BAP 2018-025.

References

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Year 2020, Volume: 4 Issue: 2, 171 - 178, 31.12.2020

Lalehan Akyüz

https://doi.org/10.32571/ijct.766866

Abstract

Project Number

2018-025

References

  • 1. Cote, A. P.; Benin, A. I.; Ockwig, N. W.; O'Keeffe, M.; Matzger, A. J.; Yaghi, O. M. Science 2005, 310 (5751), 1166-1170.
  • 2. El-Kaderi, H. M.; Hunt, J. R.; Mendoza-Cortés, J. L.; Côté, A. P.; Taylor, R. E.; O'Keeffe, M.; Yaghi, O. M. Science 2007, 316 (5822), 268-272.
  • 3. Dogru, M.; Sonnauer, A.; Gavryushin, A.; Knochel, P.; Bein, T. Chem. Commun. 2011, 47 (6), 1707-1709.
  • 4. Spitler, E. L.; Dichtel, W. R. Nature Chem. 2010, 2 (8), 672.
  • 5. Tilford, R. W.; Gemmill, W. R.; zur Loye, H.-C.; Lavigne, J. J. Chem. Mater. 2006, 18 (22), 5296-5301.
  • 6. Uribe-Romo, F. J.; Hunt, J. R.; Furukawa, H.; Klock, C.; O’Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc. 2009, 131 (13), 4570-4571.
  • 7. Wan, S.; Guo, J.; Kim, J.; Ihee, H.; Jiang, D. Angew. Chem. Int. Edit. 2008, 47 (46), 8826-8830.
  • 8. Wan, S.; Guo, J.; Kim, J.; Ihee, H.; Jiang, D. Angew. Chem. Int. Edit. 2009, 48 (30), 5439-5442.
  • 9. Albacete, P.; Martinez, J. I.; Li, X.; Lopez-Moreno, A.; Mena-Hernando, S. a.; Platero-Prats, A. E.; Montoro, C.; Loh, K. P.; Perez, E. M.; Zamora, F. J. Am. Chem. Soc. 2018, 140 (40), 12922-12929.
  • 10. Rabbani, M. G.; Sekizkardes, A. K.; Kahveci, Z.; Reich, T. E.; Ding, R.; El-Kaderi, H. M. Chem. Eur. J 2013, 19 (10), 3324-3328.
  • 11. Akyuz, L. Micropor. Mesopor. Mat. 2020, 294, 109850.
  • 12. Kuhn, P.; Antonietti, M.; Thomas, A. Angew. Chem. Int. Edit. 2008, 47 (18), 3450-3453.
  • 13. Uribe-Romo, F. J.; Doonan, C. J.; Furukawa, H.; Oisaki, K.; Yaghi, O. M. J. Am. Chem. Soc. 2011, 133 (30), 11478-11481.
  • 14. Ding, H.; Li, Y.; Hu, H.; Sun, Y.; Wang, J.; Wang, C.; Wang, C.; Zhang, G.; Wang, B.; Xu, W. Zhang, D. Chem-Eur. J. 2014, 20 (45), 14614-14618.
  • 15. Cai, S.-L.; Zhang, Y.-B.; Pun, A. B.; He, B.; Yang, J.; Toma, F. M.; Sharp, I. D.; Yaghi, O. M.; Fan, J.; Zheng, S. R. Chem. Sci. 2014, 5 (12), 4693-4700.
  • 16. Dogru, M.; Handloser, M.; Auras, F.; Kunz, T.; Medina, D.; Hartschuh, A.; Knochel, P.; Bein, T. Angew. Chem.- Ger Edit 2013, 125 (10), 2992-2996.
  • 17. Zhang, W.; Qiu, L.-G.; Yuan, Y. P.; Xie, A. J.; Shen, Y. H.; Zhu, J. F. J. Hazard. Mater. 2012, 221, 147-154.
  • 18. Ding, S.-Y.; Gao, J.; Wang, Q.; Zhang, Y.; Song, W. G.; Su, C.-Y.; Wang, W. J. Am. Chem. Soc. 2011, 133 (49), 19816-19822.
  • 19. Ben, T.; Shi, K.; Cui, Y.; Pei, C.; Zuo, Y.; Guo, H.; Zhang, D.; Xu, J.; Deng, F.; Tian, Z. J. Mater. Chem. 2011, 21 (45), 18208-18214.
  • 20. Karak, S.; Kandambeth, S.; Biswal, B. P.; Sasmal, H. S.; Kumar, S.; Pachfule, P.; Banerjee, R. J. Am. Chem. Soc. 2017, 139 (5), 1856-1862.
  • 21. Mitra, S.; Sasmal, H. S.; Kundu, T.; Kandambeth, S.; Illath, K.; Diaz Diaz, D.; Banerjee, R. J. Am. Chem. Soc. 2017, 139 (12), 4513-4520.
  • 22. Bunck, D. N.; Dichtel, W. R. J. Am. Chem. Soc. 2013, 135 (40), 14952-14955.
  • 23. Chandra, S.; Kandambeth, S.; Biswal, B. P.; Lukose, B.; Kunjir, S. M.; Chaudhary, M.; Babarao, R.; Heine, T.; Banerjee, R. J. Am. Chem. Soc. 2013, 135 (47), 17853-17861.
  • 24. Wu, C.; Liu, Y.; Liu, H.; Duan, C.; Pan, Q.; Zhu, J.; Hu, F.; Ma, X.; Jiu, T.; Li, Z. J. Am. Chem. Soc. 2018, 140 (31), 10016-10024.
There are 24 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Lalehan Akyüz 0000-0001-8548-3037

Project Number 2018-025
Publication Date December 31, 2020
Published in Issue Year 2020 Volume: 4 Issue: 2

Cite

APA Akyüz, L. (2020). Synthesis and characterization of a new 2D-imine-linked covalent organic framework. International Journal of Chemistry and Technology, 4(2), 171-178. https://doi.org/10.32571/ijct.766866
AMA Akyüz L. Synthesis and characterization of a new 2D-imine-linked covalent organic framework. Int. J. Chem. Technol. December 2020;4(2):171-178. doi:10.32571/ijct.766866
Chicago Akyüz, Lalehan. “Synthesis and Characterization of a New 2D-Imine-Linked Covalent Organic Framework”. International Journal of Chemistry and Technology 4, no. 2 (December 2020): 171-78. https://doi.org/10.32571/ijct.766866.
EndNote Akyüz L (December 1, 2020) Synthesis and characterization of a new 2D-imine-linked covalent organic framework. International Journal of Chemistry and Technology 4 2 171–178.
IEEE L. Akyüz, “Synthesis and characterization of a new 2D-imine-linked covalent organic framework”, Int. J. Chem. Technol., vol. 4, no. 2, pp. 171–178, 2020, doi: 10.32571/ijct.766866.
ISNAD Akyüz, Lalehan. “Synthesis and Characterization of a New 2D-Imine-Linked Covalent Organic Framework”. International Journal of Chemistry and Technology 4/2 (December 2020), 171-178. https://doi.org/10.32571/ijct.766866.
JAMA Akyüz L. Synthesis and characterization of a new 2D-imine-linked covalent organic framework. Int. J. Chem. Technol. 2020;4:171–178.
MLA Akyüz, Lalehan. “Synthesis and Characterization of a New 2D-Imine-Linked Covalent Organic Framework”. International Journal of Chemistry and Technology, vol. 4, no. 2, 2020, pp. 171-8, doi:10.32571/ijct.766866.
Vancouver Akyüz L. Synthesis and characterization of a new 2D-imine-linked covalent organic framework. Int. J. Chem. Technol. 2020;4(2):171-8.

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