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ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI

Year 2022, Volume: 25 Issue: 4, 670 - 680, 03.12.2022

Abdulkadir Özer

https://doi.org/10.17780/ksujes.1150877

Abstract

Bu çalışmada, kimyasal çöktürme yöntemi ile çinko hidroksi sülfat (Zn4SO4(OH)6)’ın sentezlenmesi esnasında ZnSO4 öncü madde olarak ve boraks (Na2B4O7.10H2O), hekzametilentetramin (CH2)6N4) (HMT) ve sodyum hidroksit (NaOH) bazik çöktürücüler olarak kullanılmıştır. Boraks ve HMT ortamlarında Zn4(OH)6SO4.3H20 ve NaOH ortamında Zn4(OH)6SO4.4H20'in sentezlendiği XRD sonuçları ile tespit edilmiştir. SEM analiz sonuçlarında boraks, HMT ve NaOH ortamlarında sentezlenen örneklerin hegzagonal yapıda tabakalardan oluştuğu görülmektedir. TG ve DSC analizlerinde her üç örnek içinde üç basamaklı bir ağırlık kaybının olduğu görülmektedir. Her bir basamakta sırası ile Zn4(OH)6SO4.0,5H20, Zn3O(SO4)2 ve ZnO’in oluştuğu tespit edilmiştir. Boraks ortamında 3-(N,N-dimetildodesilamonyum)-propansülfonat (SB12) sürfaktan ilave edilerek sentezlenen örneklerin sürfaktansız ortamda sentezlenen örneklere benzer hegzagonal yapıda olduğu görülmektedir. Sodyum dodesil sülfat (SDS) ve N-setil-N,N,N-trimetil-amonyum bromür (CTAB) sürfaktanları ilave edilerek sentezlenen örneklerin ise yaprak benzeri morfolojilere dönüştüğü tespit edilmiştir.

Keywords

Kimyasal çöktürme yöntemi Zn4(OH)6SO4 ZnO

References

  • Anandan, S., Wu J. J., & Ashokkumar M. (2015) Sonochemical Synthesis of Layered Copper Hydroxy Nitrate Nanosheets, Chem Phys Chem., 16, 3389–3391. https://doi.org/10.1002/cphc.201500629
  • Arizaga, G. G. C., Satyanarayana, K. G. & Wypych, F. (2007). Layered hydroxide salts: Synthesis, properties and potential applications. Solid State Ionics, 178, 1143–1162. https://doi.org/10.1016/j.ssi.2007.04.016
  • Bear, I. J., Grey, I. E., Newnham, I. E. & Rogers, L. J. (1987). The ZnSO4. 3Zn(OH)2-H2O system. I. Phase formation. Australian journal of Chemistry, 40(3), 539-556. https://doi.org/10.1071/CH9870539
  • Cui, Q. Y., Yu, K., Zhang, N. & Zhu, Z. Q. (2008). Porous ZnO nanobelts evolved from layered basic zinc acetate nanobelts. Appl. Surf. Sci., 254, 3517–3521. https://doi.org/10.1016/j.apsusc.2007.11.044
  • Darezereshki E., Alizadeh M., Bakhtiari F., Schaffie M. & Ranjbar M. (2011). A novel thermal decomposition method for the synthesis of ZnO nanoparticles from low concentration ZnSO4 solutions, Applied Clay Science 54, 107–111. https://doi.org/10.1016/j.clay.2011.07.023
  • Evans, D. G. & Duan X. (2006). Preparation of layered double hydroxides and their applications as additives in polymers, as precursors to magnetic materials and in biology and medicine. Chem. Commun., 5, 485–496. https://doi.org/10.1039/B510313B
  • Gao, X. D., Li, X. M., Yu, W. D., Peng, F. & Zhang, C.Y. (2006). Oversized hexagonal nanosheets of layered zinc hydroxysulfates via the hexamethylenetetramine-mediated solution route. Mater. Res. Bull. 41, 608–611. https://doi.org/10.1016/j.materresbull.2005.09.001
  • Germann, L. S., Dinnebier, R. E., Liu X., Dong Y. & Li W. (2016). On the Crystal Structure of a Previously Unknown Anhydrous Zinc Hydroxide Sulfate. Z. Anorg. Allg. Chem., 642 (3), 255–259. https://doi.org/10.1002/zaac.201500774
  • Huang, J. R., Wu, Y. J., Gu, C. P., Zhai, M. H., Sun, Y. F. & Liu, J. H. (2011). Fabrication and gas-sensing properties of hierarchically porous ZnO architectures. Sens. Actuators B: Chem., 155, 126–133. https://doi.org/10.1016/j.snb.2010.11.036
  • Hwang, S. H., Han, Y. S. & Choy, J. H. (2001). Intercalation of Functional Organic Molecules with Pharmaceutical, Cosmeceutical and Nutraceutical Functions into Layered Double Hydroxides and Zinc Basic Salts. Bull. Korean Chem. Soc., 22, 1019–1022. https://doi.org/10.5012/bkcs.2001.22.9.1019
  • LaGrow A. P., Ingham B., Toney M. F. & Tilley R. D. (2013). Effect of surfactant concentration and aggregation on the growth kinetics of nickel nanoparticles. J Phys Chem C, 117:16709–16718. https://doi.org/10.1021/jp405314g
  • Machovsky, M., Kuritka, I., Sedlák, J. & Pastorek, M. (2013). Hexagonal ZnO porous plates prepared from microwave synthesized layered zinc hydroxide sulphate via thermal decomposition. Materials Research Bulletin, 48(10), 4002-4007. https://doi.org/10.1016/j.materresbull.2013.06.018
  • Moezzi, A., McDonagh, A. M. & Cortie, M. B. (2012). Zinc oxide particles: Synthesis, properties and applications. Chemical engineering journal, 185, 1-22. https://doi.org/10.1016/j.cej.2012.01.076
  • Moezzi, A., Cortie, M. B. & McDonagh, A. M. (2013). Zinc hydroxide sulphate and its transformation to crystalline zinc oxide. Dalton Transactions, 42(40), 14432-14437. https://doi.org/10.1039/C3DT51638E
  • Newman, S. P & Jones, W. (1999). Comparative Study of Some Layered Hydroxide Salts Containing Exchangeable Interlayer Anions. J. Solid State Chem., 148 (1), 26–40. https://doi.org/10.1006/jssc.1999.8330
  • Othman, M. R., Helwani, Z. & Fernando, W. J. N. (2009). Synthetic hydrotalcites from different routes and their application as catalysts and gas adsorbents: a review. Appl. Organomet. Chem., 23, 335–346. https://doi.org/10.1002/aoc.1517
  • Peng, H., Dong, G. X., Bin, W. L., Wu, J. Z., Lu, W. C. & Min, L.X. (2013). Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance. Acta Phys.-Chim. Sin., 29 (4), 874-880. https://doi.org/10.3866/PKU.WHXB201302045
  • Rajamathi, M., Thomas, G. S. & Kamath, P. V. (2001). The many ways of making anionic clays. Journal of Chemical Sciences, 113, (5–6), 671–680. https://doi.org/10.1007/BF02708799
  • Rujiwatra, A., Mander, G. J., Kepert, C. J. & Rosseinsky, M. J. (2005). Synthesis and Characterization of Subcell− Supercell Related Ethylenediamine-Pillared Zinc Hydroxysulfates. Crystal growth & design, 5(1), 183-189. https://doi.org/10.1021/cg034242x
  • Staminirova, T., Petrova, N. & Kirov, G. (2016). Thermal decomposition of zinc hydroxy-sulfate-hydrate minerals. J Therm Anal Calorim., 125, 85–96. https://doi.org/10.1007/s10973-016-5325-x
  • Xue, L., Mei, X., Zhang, W., Yuan, L., Hu, X., Huang, Y. & Yanagisawa, K. (2010). Synthesis and assembly of zinc hydroxide sulfate large flakes: Application in gas sensor based on a novel surface mount technology. Sensor and Actuators B: Chemical, 147(2), 495-501. https://doi.org/10.1016/j.snb.2010.03.016
  • Zhang, W. X. & Yanagisawa, K. (2007). Hydrothermal Synthesis of Zinc Hydroxide Chloride Sheets and Their Conversion to ZnO. Chem. Mater., 19, 2329–2334. https://doi.org/10.1021/cm0626841
  • Zhang, F.Z., Xiang, X., Li, F. & Duan, X. (2008). Layered Double Hydroxides as Catalytic Materials: Recent Development. Catal. Surv. Asia, 12, 253–265. https://doi.org/10.1007/s10563-008-9061-5

Year 2022, Volume: 25 Issue: 4, 670 - 680, 03.12.2022

Abdulkadir Özer

https://doi.org/10.17780/ksujes.1150877

Abstract

References

  • Anandan, S., Wu J. J., & Ashokkumar M. (2015) Sonochemical Synthesis of Layered Copper Hydroxy Nitrate Nanosheets, Chem Phys Chem., 16, 3389–3391. https://doi.org/10.1002/cphc.201500629
  • Arizaga, G. G. C., Satyanarayana, K. G. & Wypych, F. (2007). Layered hydroxide salts: Synthesis, properties and potential applications. Solid State Ionics, 178, 1143–1162. https://doi.org/10.1016/j.ssi.2007.04.016
  • Bear, I. J., Grey, I. E., Newnham, I. E. & Rogers, L. J. (1987). The ZnSO4. 3Zn(OH)2-H2O system. I. Phase formation. Australian journal of Chemistry, 40(3), 539-556. https://doi.org/10.1071/CH9870539
  • Cui, Q. Y., Yu, K., Zhang, N. & Zhu, Z. Q. (2008). Porous ZnO nanobelts evolved from layered basic zinc acetate nanobelts. Appl. Surf. Sci., 254, 3517–3521. https://doi.org/10.1016/j.apsusc.2007.11.044
  • Darezereshki E., Alizadeh M., Bakhtiari F., Schaffie M. & Ranjbar M. (2011). A novel thermal decomposition method for the synthesis of ZnO nanoparticles from low concentration ZnSO4 solutions, Applied Clay Science 54, 107–111. https://doi.org/10.1016/j.clay.2011.07.023
  • Evans, D. G. & Duan X. (2006). Preparation of layered double hydroxides and their applications as additives in polymers, as precursors to magnetic materials and in biology and medicine. Chem. Commun., 5, 485–496. https://doi.org/10.1039/B510313B
  • Gao, X. D., Li, X. M., Yu, W. D., Peng, F. & Zhang, C.Y. (2006). Oversized hexagonal nanosheets of layered zinc hydroxysulfates via the hexamethylenetetramine-mediated solution route. Mater. Res. Bull. 41, 608–611. https://doi.org/10.1016/j.materresbull.2005.09.001
  • Germann, L. S., Dinnebier, R. E., Liu X., Dong Y. & Li W. (2016). On the Crystal Structure of a Previously Unknown Anhydrous Zinc Hydroxide Sulfate. Z. Anorg. Allg. Chem., 642 (3), 255–259. https://doi.org/10.1002/zaac.201500774
  • Huang, J. R., Wu, Y. J., Gu, C. P., Zhai, M. H., Sun, Y. F. & Liu, J. H. (2011). Fabrication and gas-sensing properties of hierarchically porous ZnO architectures. Sens. Actuators B: Chem., 155, 126–133. https://doi.org/10.1016/j.snb.2010.11.036
  • Hwang, S. H., Han, Y. S. & Choy, J. H. (2001). Intercalation of Functional Organic Molecules with Pharmaceutical, Cosmeceutical and Nutraceutical Functions into Layered Double Hydroxides and Zinc Basic Salts. Bull. Korean Chem. Soc., 22, 1019–1022. https://doi.org/10.5012/bkcs.2001.22.9.1019
  • LaGrow A. P., Ingham B., Toney M. F. & Tilley R. D. (2013). Effect of surfactant concentration and aggregation on the growth kinetics of nickel nanoparticles. J Phys Chem C, 117:16709–16718. https://doi.org/10.1021/jp405314g
  • Machovsky, M., Kuritka, I., Sedlák, J. & Pastorek, M. (2013). Hexagonal ZnO porous plates prepared from microwave synthesized layered zinc hydroxide sulphate via thermal decomposition. Materials Research Bulletin, 48(10), 4002-4007. https://doi.org/10.1016/j.materresbull.2013.06.018
  • Moezzi, A., McDonagh, A. M. & Cortie, M. B. (2012). Zinc oxide particles: Synthesis, properties and applications. Chemical engineering journal, 185, 1-22. https://doi.org/10.1016/j.cej.2012.01.076
  • Moezzi, A., Cortie, M. B. & McDonagh, A. M. (2013). Zinc hydroxide sulphate and its transformation to crystalline zinc oxide. Dalton Transactions, 42(40), 14432-14437. https://doi.org/10.1039/C3DT51638E
  • Newman, S. P & Jones, W. (1999). Comparative Study of Some Layered Hydroxide Salts Containing Exchangeable Interlayer Anions. J. Solid State Chem., 148 (1), 26–40. https://doi.org/10.1006/jssc.1999.8330
  • Othman, M. R., Helwani, Z. & Fernando, W. J. N. (2009). Synthetic hydrotalcites from different routes and their application as catalysts and gas adsorbents: a review. Appl. Organomet. Chem., 23, 335–346. https://doi.org/10.1002/aoc.1517
  • Peng, H., Dong, G. X., Bin, W. L., Wu, J. Z., Lu, W. C. & Min, L.X. (2013). Porous ZnO Sheets Transformed from Zinc Sulfate Hydroxide Hydrate and Their Photoluminescence Performance. Acta Phys.-Chim. Sin., 29 (4), 874-880. https://doi.org/10.3866/PKU.WHXB201302045
  • Rajamathi, M., Thomas, G. S. & Kamath, P. V. (2001). The many ways of making anionic clays. Journal of Chemical Sciences, 113, (5–6), 671–680. https://doi.org/10.1007/BF02708799
  • Rujiwatra, A., Mander, G. J., Kepert, C. J. & Rosseinsky, M. J. (2005). Synthesis and Characterization of Subcell− Supercell Related Ethylenediamine-Pillared Zinc Hydroxysulfates. Crystal growth & design, 5(1), 183-189. https://doi.org/10.1021/cg034242x
  • Staminirova, T., Petrova, N. & Kirov, G. (2016). Thermal decomposition of zinc hydroxy-sulfate-hydrate minerals. J Therm Anal Calorim., 125, 85–96. https://doi.org/10.1007/s10973-016-5325-x
  • Xue, L., Mei, X., Zhang, W., Yuan, L., Hu, X., Huang, Y. & Yanagisawa, K. (2010). Synthesis and assembly of zinc hydroxide sulfate large flakes: Application in gas sensor based on a novel surface mount technology. Sensor and Actuators B: Chemical, 147(2), 495-501. https://doi.org/10.1016/j.snb.2010.03.016
  • Zhang, W. X. & Yanagisawa, K. (2007). Hydrothermal Synthesis of Zinc Hydroxide Chloride Sheets and Their Conversion to ZnO. Chem. Mater., 19, 2329–2334. https://doi.org/10.1021/cm0626841
  • Zhang, F.Z., Xiang, X., Li, F. & Duan, X. (2008). Layered Double Hydroxides as Catalytic Materials: Recent Development. Catal. Surv. Asia, 12, 253–265. https://doi.org/10.1007/s10563-008-9061-5
There are 23 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Chemical Engineering
Authors

Abdulkadir Özer 0000-0002-0487-3680

Publication Date December 3, 2022
Submission Date August 1, 2022
Published in Issue Year 2022Volume: 25 Issue: 4

Cite

APA Özer, A. (2022). ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 25(4), 670-680. https://doi.org/10.17780/ksujes.1150877
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