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Polycaprolactone (PCL) based polymer composites filled wheat straw flour

Year 2016, Volume: 16 Issue: 1, 0 - 0, 02.06.2016

Kadir Karakus

https://doi.org/10.17475/kujff.03251

Abstract

In this study, polycaprolactone (PCL) based polymer composites were manufactured through injection moulding machine. Polycaprolactone (PCL) and wheat straw flour was used  as polymer matrix and organic filler respectively. The effects of wheat straw flour loading on the mechanical properties of the manufactured composites were investigated. The thermal behaviors (TGA and DSC), mechanical properties (tensile, flexural and impact strength), of manufactured composites were determined. According to test results the addition of  wheat straw into PCL matrix reduced tensile strength, elongation at break and impact strength of composites while improving the tensile, flexural strength and flexural modulus.

References

  • Arbelaiz A., Fernandez B., Valea A., Mondragon I. 2006. Mechanical properties of short flax fiber bundle/poly(-caprolactone) composites: influence of matrix modification and fiber content, Carbohydrate Polymers, 64 (2), 224-232.
  • Avella M., Rota G.L., Martuscelli E., Raimo M., Sadocco P., Elegir G., Riva R. 2000. Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and wheat straw fibre composites: thermal, mechanical properties and biodegradation behaviour, Journal of Materials Science, 35 (4), 829-836.
  • Averous L., Boquillon N. 2004. Biocomposites based on plasticized starch: thermal and mechanical behaviours, Carbonhydrate Polymers, 56, 111–122.
  • Aydemir D., Kızıltas A., Kızıltas E.E., Gardner D.J., Gunduz G. 2015. Heat treated wood–nylon 6 composites, Composites: Part B, 68, 414-423.
  • Chen X., Guo Q., Mi Y. 1998. Bamboo fiber-reinforced polypropylene composites: A study of the mechanical properties, J. Appl. Polym. Sci., 69 (10), 1891-1899.
  • Digabel L., Boquillon F., Dole N., Monties P., Averous L. 2004. Properties of thermoplastic composites based on wheat-straw lignocellulosic fillers, Journal of Applied Polymer Science, 93 (1), 428-436.
  • Dong C., Davies I.J. 2011. Flexural properties of wheat straw reinforced polyester composites, American Journal of Materials Science, 1 (2), 71-75.
  • Donmez Cavdar A., Kalaycıoğlu H., Mengeloğlu F. 2011. Tea mill waste fibers filled thermoplastic composites: The effects of plastic type and fiber loading, Journal Reinforced Plastics and Composites, 30, 833–844.
  • Donmez Cavdar A., Kalaycıoğlu H., Mengeloğlu F. 2015. Technological properties of thermoplastic composites filled with fire retardant and tea mill waste fiber, Journal of Composite Materials, DOI: 10.1177/0021998315595113.
  • Hornsby P.R., Hinrichsen E., Tarverdi K. 1997. Preparation and properties of polypropylene composites reinforced with wheat and flax straw fibres: Part I Fibre characterization, Journal of Materials Science, 32 (2), 443-449.
  • Kaymakci A., Ayrilmis N., Gulec T., 2013. Surface properties of polypropylene composites filled with agricultural flour, Bioresources, 8, 592-602.
  • Matuana L.M., Balatinecz J.J. 1998. Effect of surface properties on the adhesion between PVC and wood veener laminates, Polym. Eng. Sci., 38 (5), 765-773.
  • Mengeloglu F., Karakus K. 2008. Thermal degradation, mechanical properties and morphology of wheat straw flour filled recycled thermoplastic composites, Sensors, 8 (1), 500-519.
  • Mengeloglu F., Karakus K. 2012. Mechanical properties of injection-molded foamed wheat straw filled HDPE biocomposites: The effects of filler loading and coupling agent contents, Bioresources, 7 (3), 3293-3305.
  • Mishra S., Sain M. 2009. Commercialization of wheat straw as reinforcing filler for commodity thermoplastics, Journal of Natural Fibers, 6 (1), 83-97.
  • Pan M., Zhang S.Y., Zhou D. 2009. Preparation and properties of wheat straw fiber-polypropylene composites. Part II. Investigation of surface treatments on the thermo-mechanical and rheological properties of the composites, Journal of Composite Materials, 114 (5), 3049-3056.
  • Ruseckaite C.R., Jimenez A. 2003. Thermal degradation of mixture of polycaprolactone with cellulose derivatives, Polymer Degradation and Stability, 81 (2), 353–358.
  • Shibata S, Fukumoto I, Cao Y. 2006. Effects of fiber compression and length distribution on the flexural properties of short kenaf fiber-reinforced biodegradable composites, Polymer Composites, 27, 170-176.
  • Velde V.D., Kiekens K. 2002. Biopolymers: overwiev of several properties and consequences on their applications, Polymer Testing, 21 (4), 433–442.

Year 2016, Volume: 16 Issue: 1, 0 - 0, 02.06.2016

Kadir Karakus

https://doi.org/10.17475/kujff.03251

Abstract

References

  • Arbelaiz A., Fernandez B., Valea A., Mondragon I. 2006. Mechanical properties of short flax fiber bundle/poly(-caprolactone) composites: influence of matrix modification and fiber content, Carbohydrate Polymers, 64 (2), 224-232.
  • Avella M., Rota G.L., Martuscelli E., Raimo M., Sadocco P., Elegir G., Riva R. 2000. Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and wheat straw fibre composites: thermal, mechanical properties and biodegradation behaviour, Journal of Materials Science, 35 (4), 829-836.
  • Averous L., Boquillon N. 2004. Biocomposites based on plasticized starch: thermal and mechanical behaviours, Carbonhydrate Polymers, 56, 111–122.
  • Aydemir D., Kızıltas A., Kızıltas E.E., Gardner D.J., Gunduz G. 2015. Heat treated wood–nylon 6 composites, Composites: Part B, 68, 414-423.
  • Chen X., Guo Q., Mi Y. 1998. Bamboo fiber-reinforced polypropylene composites: A study of the mechanical properties, J. Appl. Polym. Sci., 69 (10), 1891-1899.
  • Digabel L., Boquillon F., Dole N., Monties P., Averous L. 2004. Properties of thermoplastic composites based on wheat-straw lignocellulosic fillers, Journal of Applied Polymer Science, 93 (1), 428-436.
  • Dong C., Davies I.J. 2011. Flexural properties of wheat straw reinforced polyester composites, American Journal of Materials Science, 1 (2), 71-75.
  • Donmez Cavdar A., Kalaycıoğlu H., Mengeloğlu F. 2011. Tea mill waste fibers filled thermoplastic composites: The effects of plastic type and fiber loading, Journal Reinforced Plastics and Composites, 30, 833–844.
  • Donmez Cavdar A., Kalaycıoğlu H., Mengeloğlu F. 2015. Technological properties of thermoplastic composites filled with fire retardant and tea mill waste fiber, Journal of Composite Materials, DOI: 10.1177/0021998315595113.
  • Hornsby P.R., Hinrichsen E., Tarverdi K. 1997. Preparation and properties of polypropylene composites reinforced with wheat and flax straw fibres: Part I Fibre characterization, Journal of Materials Science, 32 (2), 443-449.
  • Kaymakci A., Ayrilmis N., Gulec T., 2013. Surface properties of polypropylene composites filled with agricultural flour, Bioresources, 8, 592-602.
  • Matuana L.M., Balatinecz J.J. 1998. Effect of surface properties on the adhesion between PVC and wood veener laminates, Polym. Eng. Sci., 38 (5), 765-773.
  • Mengeloglu F., Karakus K. 2008. Thermal degradation, mechanical properties and morphology of wheat straw flour filled recycled thermoplastic composites, Sensors, 8 (1), 500-519.
  • Mengeloglu F., Karakus K. 2012. Mechanical properties of injection-molded foamed wheat straw filled HDPE biocomposites: The effects of filler loading and coupling agent contents, Bioresources, 7 (3), 3293-3305.
  • Mishra S., Sain M. 2009. Commercialization of wheat straw as reinforcing filler for commodity thermoplastics, Journal of Natural Fibers, 6 (1), 83-97.
  • Pan M., Zhang S.Y., Zhou D. 2009. Preparation and properties of wheat straw fiber-polypropylene composites. Part II. Investigation of surface treatments on the thermo-mechanical and rheological properties of the composites, Journal of Composite Materials, 114 (5), 3049-3056.
  • Ruseckaite C.R., Jimenez A. 2003. Thermal degradation of mixture of polycaprolactone with cellulose derivatives, Polymer Degradation and Stability, 81 (2), 353–358.
  • Shibata S, Fukumoto I, Cao Y. 2006. Effects of fiber compression and length distribution on the flexural properties of short kenaf fiber-reinforced biodegradable composites, Polymer Composites, 27, 170-176.
  • Velde V.D., Kiekens K. 2002. Biopolymers: overwiev of several properties and consequences on their applications, Polymer Testing, 21 (4), 433–442.
There are 19 citations in total.

Details

Journal Section Articles
Authors

Kadir Karakus

Publication Date June 2, 2016
Published in Issue Year 2016 Volume: 16 Issue: 1

Cite

APA Karakus, K. (2016). Polycaprolactone (PCL) based polymer composites filled wheat straw flour. Kastamonu University Journal of Forestry Faculty, 16(1). https://doi.org/10.17475/kujff.03251
AMA Karakus K. Polycaprolactone (PCL) based polymer composites filled wheat straw flour. Kastamonu University Journal of Forestry Faculty. June 2016;16(1). doi:10.17475/kujff.03251
Chicago Karakus, Kadir. “Polycaprolactone (PCL) Based Polymer Composites Filled Wheat Straw Flour”. Kastamonu University Journal of Forestry Faculty 16, no. 1 (June 2016). https://doi.org/10.17475/kujff.03251.
EndNote Karakus K (June 1, 2016) Polycaprolactone (PCL) based polymer composites filled wheat straw flour. Kastamonu University Journal of Forestry Faculty 16 1
IEEE K. Karakus, “Polycaprolactone (PCL) based polymer composites filled wheat straw flour”, Kastamonu University Journal of Forestry Faculty, vol. 16, no. 1, 2016, doi: 10.17475/kujff.03251.
ISNAD Karakus, Kadir. “Polycaprolactone (PCL) Based Polymer Composites Filled Wheat Straw Flour”. Kastamonu University Journal of Forestry Faculty 16/1 (June 2016). https://doi.org/10.17475/kujff.03251.
JAMA Karakus K. Polycaprolactone (PCL) based polymer composites filled wheat straw flour. Kastamonu University Journal of Forestry Faculty. 2016;16. doi:10.17475/kujff.03251.
MLA Karakus, Kadir. “Polycaprolactone (PCL) Based Polymer Composites Filled Wheat Straw Flour”. Kastamonu University Journal of Forestry Faculty, vol. 16, no. 1, 2016, doi:10.17475/kujff.03251.
Vancouver Karakus K. Polycaprolactone (PCL) based polymer composites filled wheat straw flour. Kastamonu University Journal of Forestry Faculty. 2016;16(1).

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