EFFECT OF DEPOSITION TIME ON THE OPTOELECTRICAL PROPERTIES OF ELECTROSPUN PAN/AGNO3 NANOFIBERS

Sebnem Duzyer

doi:10.32710/tekstilvekonfeksiyon.568353

Research Article

EFFECT OF DEPOSITION TIME ON THE OPTOELECTRICAL PROPERTIES OF ELECTROSPUN PAN/AGNO3 NANOFIBERS

Year 2020, Volume: 30 Issue: 1, 29 - 34, 25.03.2020

Sebnem Duzyer

https://doi.org/10.32710/tekstilvekonfeksiyon.568353

Cited By: 3

Abstract

The aim of this study is to produce optically
transparent nanofibers with adequate electrical conductivity for optoelectrical
applications where transparency and conductivity are needed. Therefore, conducting polyacrylonitrile/silver nitrate (PAN/AgNO₃)
nanofibers were produced by electrospinning with different deposition times ranging
from 1 minute to 10 minutes. The effect deposition time on the sheet resistance
and optical transparency of the nanofibers were investigated. The surface
characteristics, electrical properties and transmittance values of the
electrospun mats were evaluated. Nanofibers with diameters under 700 nm were
obtained. With the increasing deposition time, the sheet resistance and
transparency of the samples were decreased. In order to figure out the optimum
deposition time, figure of merit of the samples were calculated. Figure of
merit results showed that the sample deposited for three minutes had the best
performance among the others. It was seen that the results were comparable with
the literature and conducting PAN/AgNO₃ nanofibers are promising for
future applications.

Keywords

sheet resistance, optical transparency, polyacrylonitrile, silver nitrate, electrospinning, nanofiber

Supporting Institution

TUBITAK

Project Number

118M670

Thanks

The authors would like to thank Assoc. Prof. Dr. Serpil Koral Koc and Dr. Serkan Tezel for their fruitful contributions to the study. This study is financially supported by The Scientific and Technological Research Council of Turkey (TUBITAK) with the project number of 118M670.

References

1. Huang, Z.M., Zhang, Y.Z., Kotaki, M., Ramakrishna, S. (2003). A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Comp. Sci. and Technol., 63 (15): 2223-2253.
2. Bhardwaj, N., Kundu, S.C. (2010). Electrospinning: a fascinating fiber fabrication technique. Biotechnol. Adv. 28: 325-347.
3. Greiner, A., Wendorff, J.H. (2007). Electrospinning: a fascinating method for the preparation of ultrathin fibers, Angew. Chemie Int. Ed., 46: 5670-5703.
4. Li, D.., Xia, Y. (2004). Electrospinning of Nanofibers: Reinventing the Wheel?, Adv. Mater., 16:1151-1171.
5. Almetwally, A.A., El-Sakhawy, Mohamed, Elshakankery, M.H., Kasem, M.H.. (2017). Technology of nano-fibers: production techniques and properties - critical review, Journal of the Textile Association, 78:5-14.
6. Nayak, R., Padhye, R., Kyratzis, I.L., Truong, Y.B., Arnold, L. (2012). Recent advances in nanofibre fabrication techniques, Text. Res. J. 82:129-147.
7. Hu, L., Wu, H., Cui, Y. (2011). Metal nanogrids, nanowires, and nanofibers for transparent electrodes, MRS Bulletin Cambridge, 36(10):760-776.
8. Wu, H., Hu, L., Rowell, M.W., Kong, D., Cha, J.J., McDonough, J.R., Zhu, J., Yang, Y., McGehee, M.D., Cui, Y. (2010). Electrospun metal nanofiber webs as high-performance transparent electrode, Nano Lett. 10(10): 4242-4248.
9. Li, H., Pan, W., Zhang, W., Huang, S., Wu, H. (2013). TiN Nanofibers: A New Material with High Conductivity and Transmittance for Transparent Conductive Electrodes, Adv. Funct. Mater. 23(2):209-214.
10. MacDiarmid, A.G. (2001). "Synthetic Metals": A Novel Role for Organic Polymers (Nobel Lecture), Angew. Chemie Int. Ed. 40(14):2581-2590.
11. Zhao, W., Yalcin, B., Cakmak, M. (2015). Dynamic assembly of electrically conductive PEDOT:PSS nanofibers in electrospinning process studied by high speed video, Synth. Met. 203:107-116.
12. Wang, Y., Jing, X. (2007). Transparent conductive thin films based on polyaniline nanofibers, Mater. Sci. Eng., B. 138:95-100.
13. Chronakis, I. S., Grapenson, S., Jakob, A. (2006). Conductive polypyrrole nanofibers via electrospinning: Electrical and morphological properties, Polymer, 47(5), 1597-1603.
14. Duzyer, S. (2019). Different Methods of Fabricating Conductive Nanofibers, Tekstil ve Konfeksiyon, 29(1):78-85.
15. Ko, F., Gogotsi, Y., Ali, A., Naguib, N., Ye, H., Yang, G.L., Li, C., Willis, P. (2003). Electrospinning of continuous carbon nanotube-filled nanofiber yarns, Adv. Mater. 15(14):1161-1165.
16. Fu, Y., Liu, L., Zhang, L., Wang, W. (2014). Highly conductive one-dimensional nanofibers: silvered electrospun silica nanofibers via poly(dopamine) functionalization, ACS Appl Mater Interfaces. 6(7):5105-5112.
17. Demirsoy N., Uçar N., Önen, A., Karacan, I., Kızıldağ, I., Eren, O., Borazan, I. (2014). The effect dispersion technique, silver particle loading and reduction method on the properties of polyacrylonitrile-silver composite nanofiber, Journal of Industrial Textiles, 45(6), 1173-1187.
18. Ucar, N., Demirsoy, N., Onen, A., Karacan, I., Kizildag, N:, Eren, O., Vurur, O.F., Sezer, E., Ustamehmetoglu B. (2015). The effect of reduction methods and stabilizer (PVP) on the properties of polyacrylonitrile (PAN) composite nanofibers in the presence of nanosilver, Journal of Materials Science, 50(4): 1855-1864.
19. Rashid, M.U., Bhuiyan, Md. K.H., Quayum, M. E. (2013). Synthesis of silver nano particles (ag-nps) and their uses for quantitative analysis of vitamin c tablets, Dhaka Univ. J. Pharm. Sci. 12(1):29-33.
20. Çunayev, Ş., Düzyer, Ş., Tezel, S., Koral Koç, S. (April, 2019). Effect of Reduction Time on the Electrical Properties of PAN/AgNO3 Nanofibers”, 2nd International Congress on Engineering and Life Sciences (ICELIS), Kastamonu, Turkey, 2019
21. Kim, Y.S., Park, J.H., Choi, D.H., Jang, H.S., Lee, J.H., Park, H.J., Choi, J.I., Ju, D.H., Lee, J.Y., Kim, D. (2007). ITO/Au/ITO multilayer thin films for transparent conducting electrode applications, Appl. Surf. Sci. 254, 1524-1527.
22. Haacke, G. (1976). New figure of merit for transparent conductors, J. Appl. Phys. 47:4086-4089.

Year 2020, Volume: 30 Issue: 1, 29 - 34, 25.03.2020

Sebnem Duzyer

https://doi.org/10.32710/tekstilvekonfeksiyon.568353

Cited By: 3

Abstract

Project Number

118M670

References

1. Huang, Z.M., Zhang, Y.Z., Kotaki, M., Ramakrishna, S. (2003). A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Comp. Sci. and Technol., 63 (15): 2223-2253.
2. Bhardwaj, N., Kundu, S.C. (2010). Electrospinning: a fascinating fiber fabrication technique. Biotechnol. Adv. 28: 325-347.
3. Greiner, A., Wendorff, J.H. (2007). Electrospinning: a fascinating method for the preparation of ultrathin fibers, Angew. Chemie Int. Ed., 46: 5670-5703.
4. Li, D.., Xia, Y. (2004). Electrospinning of Nanofibers: Reinventing the Wheel?, Adv. Mater., 16:1151-1171.
5. Almetwally, A.A., El-Sakhawy, Mohamed, Elshakankery, M.H., Kasem, M.H.. (2017). Technology of nano-fibers: production techniques and properties - critical review, Journal of the Textile Association, 78:5-14.
6. Nayak, R., Padhye, R., Kyratzis, I.L., Truong, Y.B., Arnold, L. (2012). Recent advances in nanofibre fabrication techniques, Text. Res. J. 82:129-147.
7. Hu, L., Wu, H., Cui, Y. (2011). Metal nanogrids, nanowires, and nanofibers for transparent electrodes, MRS Bulletin Cambridge, 36(10):760-776.
8. Wu, H., Hu, L., Rowell, M.W., Kong, D., Cha, J.J., McDonough, J.R., Zhu, J., Yang, Y., McGehee, M.D., Cui, Y. (2010). Electrospun metal nanofiber webs as high-performance transparent electrode, Nano Lett. 10(10): 4242-4248.
9. Li, H., Pan, W., Zhang, W., Huang, S., Wu, H. (2013). TiN Nanofibers: A New Material with High Conductivity and Transmittance for Transparent Conductive Electrodes, Adv. Funct. Mater. 23(2):209-214.
10. MacDiarmid, A.G. (2001). "Synthetic Metals": A Novel Role for Organic Polymers (Nobel Lecture), Angew. Chemie Int. Ed. 40(14):2581-2590.
11. Zhao, W., Yalcin, B., Cakmak, M. (2015). Dynamic assembly of electrically conductive PEDOT:PSS nanofibers in electrospinning process studied by high speed video, Synth. Met. 203:107-116.
12. Wang, Y., Jing, X. (2007). Transparent conductive thin films based on polyaniline nanofibers, Mater. Sci. Eng., B. 138:95-100.
13. Chronakis, I. S., Grapenson, S., Jakob, A. (2006). Conductive polypyrrole nanofibers via electrospinning: Electrical and morphological properties, Polymer, 47(5), 1597-1603.
14. Duzyer, S. (2019). Different Methods of Fabricating Conductive Nanofibers, Tekstil ve Konfeksiyon, 29(1):78-85.
15. Ko, F., Gogotsi, Y., Ali, A., Naguib, N., Ye, H., Yang, G.L., Li, C., Willis, P. (2003). Electrospinning of continuous carbon nanotube-filled nanofiber yarns, Adv. Mater. 15(14):1161-1165.
16. Fu, Y., Liu, L., Zhang, L., Wang, W. (2014). Highly conductive one-dimensional nanofibers: silvered electrospun silica nanofibers via poly(dopamine) functionalization, ACS Appl Mater Interfaces. 6(7):5105-5112.
17. Demirsoy N., Uçar N., Önen, A., Karacan, I., Kızıldağ, I., Eren, O., Borazan, I. (2014). The effect dispersion technique, silver particle loading and reduction method on the properties of polyacrylonitrile-silver composite nanofiber, Journal of Industrial Textiles, 45(6), 1173-1187.
18. Ucar, N., Demirsoy, N., Onen, A., Karacan, I., Kizildag, N:, Eren, O., Vurur, O.F., Sezer, E., Ustamehmetoglu B. (2015). The effect of reduction methods and stabilizer (PVP) on the properties of polyacrylonitrile (PAN) composite nanofibers in the presence of nanosilver, Journal of Materials Science, 50(4): 1855-1864.
19. Rashid, M.U., Bhuiyan, Md. K.H., Quayum, M. E. (2013). Synthesis of silver nano particles (ag-nps) and their uses for quantitative analysis of vitamin c tablets, Dhaka Univ. J. Pharm. Sci. 12(1):29-33.
20. Çunayev, Ş., Düzyer, Ş., Tezel, S., Koral Koç, S. (April, 2019). Effect of Reduction Time on the Electrical Properties of PAN/AgNO3 Nanofibers”, 2nd International Congress on Engineering and Life Sciences (ICELIS), Kastamonu, Turkey, 2019
21. Kim, Y.S., Park, J.H., Choi, D.H., Jang, H.S., Lee, J.H., Park, H.J., Choi, J.I., Ju, D.H., Lee, J.Y., Kim, D. (2007). ITO/Au/ITO multilayer thin films for transparent conducting electrode applications, Appl. Surf. Sci. 254, 1524-1527.
22. Haacke, G. (1976). New figure of merit for transparent conductors, J. Appl. Phys. 47:4086-4089.

There are 22 citations in total.

Details

Primary Language	English
Subjects	Wearable Materials
Journal Section	Articles
Authors	Sebnem Duzyer
Project Number	118M670
Publication Date	March 25, 2020
Submission Date	May 21, 2019
Acceptance Date	March 17, 2020
Published in Issue	Year 2020 Volume: 30 Issue: 1

Cite

APA	Duzyer, S. (2020). EFFECT OF DEPOSITION TIME ON THE OPTOELECTRICAL PROPERTIES OF ELECTROSPUN PAN/AGNO3 NANOFIBERS. Textile and Apparel, 30(1), 29-34. https://doi.org/10.32710/tekstilvekonfeksiyon.568353

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