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Geochemistry of Miocene evaporites from the Aşkale (Erzurum, Eastern Turkey) area: constraints for paleo-environment

Yıl 2021, Cilt: 165 Sayı: 165, 113 - 140, 19.08.2021
https://doi.org/10.19111/bulletinofmre.772360

Öz

The Aşkale sub - basin hosts Early Miocene evaporites intercalated with clastic sediments and carbonates. Gypsum - and anhydrite - rich evaporite samples are characterized by high CaO and SO4 contents, and low Na2O, K2O, MgO, and B contents. The Sr contents are 228 - 13100 ppm in evaporite samples, 169 - 992 ppm in claystone, 181 - 60090 ppm in marl, and 15150 ppm in limestone. All the samples are also characterized by enrichment in light rare earth elements (REE) with LaN / LuN = 0.667 - 4.243 and have variable CeN / Ce* (0.823 - 1.353) ratios. Measured EuN / Eu* values of the samples display strong and ariable negative and positive Eu anomalies. δ34SCDT and δ18O values of gypsum - and anhydrite samples have wide ranges from 21.30 ‰ to 25.62 ‰, and 11.5 ‰ to 19.1 ‰, respectively. Most of these values  are heavier than expected Miocene marine gypsum composition and may be resulted from reduction and oxidation reactions of sulfide species in brines. 87Sr / 86Sr ratios range from 0.707475 (ΔSW = −169.8) to 0.708175 (ΔSW = −99.8), close to and / or slightly lower than an Early - Miocene marine isotopic composition. Petrochemical and isotopic data indicate that the Aşkale basin evaporites developed in subtropical conditions via multiple marine transgressions onto a shallow platform or lagoonal environment.

Teşekkür

This study was funded by the Turkish Scientific Research Council (TÜBİTAK - ÇAYDAG project no: 110Y023). The authors are grateful to the editor in chief H. Mutlu, reviwers Z.S. Karakaş and O. Ersoy for their constructive comments to improve the paper.

Kaynakça

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Yıl 2021, Cilt: 165 Sayı: 165, 113 - 140, 19.08.2021
https://doi.org/10.19111/bulletinofmre.772360

Öz

Kaynakça

  • Abdioğlu, E., Arslan, M., Gündoğan, İ., Helvacı, C. 2013. Aşkale (Erzurum) Civarındaki Evaporitlerin Mineralojik, Jeokimyasal ve İzotopik Özellikleri, KD Türkiye. TÜBİTAK Projesi, Proje no: 110Y023.
  • Abdioğlu, E., Arslan, M., Aydınçakır, D., Gündoğan, İ., Helvacı, C. 2015. Stratigraphy, mineralogy and depositional environment of the evaporite unit in the Aşkale (Erzurum) sub - basin, Eastern Anatolia (Turkey). Journal of African Earth Sciences 111, 100-112.
  • Adabi, M. H. 2004. Sedimentary Geochemistry. Arianzamin Publication, Iran.
  • Alptekin, Ö. 1973. Focal Mechanism of Earthquakes in Western Turkey and Their Tectonic Implications. PhD Thesis, New Mexico Institute of Mining and Technology, Socorro, USA.
  • Aydınçakır, D. 2013. Pırnakapan (Aşkale, Erzurum) civarındaki evaporitlerin mineralojik, petrografik ve jeokimyasal incelenmesi. Karadeniz Teknik Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi.
  • Bahadori, A., Carranza, E. J. M., Soleimani, B. 2011. Geochemical analysis of evaporite sedimentation in Gachsaran Formation, Zeloi oil field, southwest Iran. Journal of Geochemical Exploration 111, 97- 112.
  • Baysal, O., Ataman, G. 1980. Sedimentology, mineralogy and geochemistry of a sulphate series (Sivas - Turkey). Sedimentary Geology 25, 67-81.
  • Brinkmann, R. 1976. Geology of Turkey. Elsevier, Amsterdam.
  • Burke, W. H., Denison, R. E., Hetherington, E. A., Koepnik, R. B., Nelson, H. F., Otto, J. B. 1982. Variation of seawater 87Sr / 86Sr throughout Phanerozoic time. Geology 10, 516-519.
  • Cendón, D. I., Chivas, A. R., García, A. 2004. Chemistry of the rivers in the Gulf of Carpentaria drainage division and possible correlations with the sedimentary record during lake phases. 17th Australian Geological Convention. Dynamic Earth: Past, Present and Future. Hobart, Australia, 73, 228.
  • Claypool, G. E., Holser, W. T., Kaplan, I. R., Sakai, H., Zak, I. 1980. The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation. Chemical Geology 28, 199-260.
  • Crockford, P. W., Kunzmann, M., Bekker, A., Hayles, J., Bao, H., Halverson, G. P., Peng, Y., Bui, T. H., Cox, G. M., Gibson, T. M., Wörndle, S., Rainbird, R., Lepland, A., Swanson - Hysell, N. L., Master, S., Sreenivas, B., Kuznetsov, A., Krupenik, V., Wing, B. A. 2019. Claypool continued: Extending the isotopic record of sedimentary sulfate. Chemical Geology 513, 200-225.
  • Çiner, A., Koşun, E., Deynoux, M. 2002. Fluvial, evaporitic and shallow-marine facies architecture, depositional evolution and cyclicity in the Sivas Basin (Lower to Middle Miocene), Central Turkey. Journal of Asian Earth Sciences 21, 147- 165.
  • Dejonghe, L., Demaiffe, D., Weis, D. 1998. Strontium isotope geochemistry of anhydrites and calcite pseudomorphs after anhydrite from Paleozoic formations in Belgium. Chemical Geology 144,63-71.
  • Denison, R. E., Kırkland, D. W., Ewans, R. 1998. Using strontium isotopes to determine the age and origin of anhydrite and gypsum beds. The Journal of Geology 106, 1-7.
  • Emelyanov, E. M., Shimkus, K. M. 1986. Geochemistry and Sedimentology of the Mediterranean Sea. Springer, Paris.
  • Emery, D., Robinson, A. 1992. Inorganic Geochemistry Applications to Petroleum Geology. Blackwell Scientific Publications, Oxford.
  • Faure, G., Powell, J. L. 1972. Strontium Isotope Geology.Springer-Verlag, New York.
  • Gallet, S., Jahn, B. M., Torii, M. 1996. Geochemical characterization of the Luochuan loesspaleosol sequence, China, and paleoclimatic implications. Chemical Geology 133, 67-88.
  • Garrels, R. M., Lerman,A. 1984. Coupling of the sedimentary sulfur and carbon cycles; an improved model. American Journal of Science 284, 989-1007.
  • Gökçe, A., Ceyhan, F. 1988. Sivas güneydoğusundaki Miyosen yaşlı jipsli çökellerin stratigrafisi, yapısal özellikleri ve oluşumu. Cumhuriyet Earth Science Journal 5, 1, 91-113 (in Turkish).
  • Gündoğan, İ. 2000. Geology, Mineralogy-Petrography and Economic Potential of the Upper Miocene Evaporites in The Beypazarı and Çankırı - Çorum Basins. PhD Thesis, The Graduate School of Natural and Applied Sciences, DEU.
  • Gündoğan, İ., Önal, M., Depçi, T. 2005. Sedimentology, petrography and diagenesis of Eocene - Oligocene evaporites: the Tuzhisar Formation, SW Sivas Basin, Turkey. Journal of Asian Earth Sciences 25, 791-803.
  • Gündoğan, İ., Helvacı, C., Sözbilir, H. 2008. Gypsiferious carbonates at Honaz Dağı (Denizli): First documentation of Triassic gypsum in western Turkey and its tectonic significance. Journal of Asian Earth Sciences 32, 49-65.
  • Hasselöv, M., Lyvén, D., Haraldsson, C., Sirinawin, W. 1999. Determation of continous size and trace element distribution of field-flow fractionation with ICPMS. Analytical Chemistry 71, 3497-3502.
  • Helvacı, C. Yağmurlu, F. 1995. Geological setting and economic potential of the lignite and evaporite- bearing Neogene basins of Western Anatolia, Turkey. Israel Journal of Earth Sciences 44, 91- 105.
  • Horner, T. J., Pryer, H. V., Nielsen, S. G., Crockford, P. W., Gauglitz, J. M., Wing, B. A., Ricketts, R. D. 2017. Pelagic barite precipitation at micromolar ambient sulfate, Nature Communications 8, Article number: 1342.
  • Kamber, B. S., Greig, A., Collerson, K. D. 2005. A new estimate for the composition of weathered young upper contitnental crust from alluvial sediments, Queensland, Australia. Geochimica et Cosmochimica Acta 69, 4, 1041-1058.
  • Kasprzyk, A. 2003. Sedimentological and diagenetic patterns of anhydrite deposits in the Badenian evaporite basin of the Carpathian Foredeep, southern Poland. Sedimentary Geology 158, 167-194.
  • Keskin, M. 2003. Magma generation by slab steepening and breakoff beneath a subduction-accretion complex: An alternative model for collision- related volcanism in Eastern Anatolia, Turkey. Geophysical Research Letters 30, 24, 1-4.
  • Ketin, İ. 1966. Tectonic units of Anatolia (Asia Minor). Bulletin of the Mineral Research and Exploration 66, 23-34.
  • Kornexl, B. E., Gehre, M., Höfling, R., Werner, R. A. 1999. On-line δ18O Measurement of organic and inorganic substances. Rapid Communications in Mass Spectrometry 13, 1685-1693.
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Toplam 87 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Emel Abdioğlu 0000-0001-5196-8060

Mehmet Arslan Bu kişi benim 0000-0003-0816-4168

Cahit Helvacı Bu kişi benim 0000-0002-8659-1141

İbrahim Gündoğan Bu kişi benim 0000-0002-2148-3377

İrfan Temizel 0000-0002-6293-8649

Didem Aydınçakır Bu kişi benim 0000-0001-8369-9651

Yayımlanma Tarihi 19 Ağustos 2021
Yayımlandığı Sayı Yıl 2021 Cilt: 165 Sayı: 165

Kaynak Göster

APA Abdioğlu, E., Arslan, M., Helvacı, C., Gündoğan, İ., vd. (2021). Geochemistry of Miocene evaporites from the Aşkale (Erzurum, Eastern Turkey) area: constraints for paleo-environment. Bulletin of the Mineral Research and Exploration, 165(165), 113-140. https://doi.org/10.19111/bulletinofmre.772360
AMA Abdioğlu E, Arslan M, Helvacı C, Gündoğan İ, Temizel İ, Aydınçakır D. Geochemistry of Miocene evaporites from the Aşkale (Erzurum, Eastern Turkey) area: constraints for paleo-environment. Bull.Min.Res.Exp. Ağustos 2021;165(165):113-140. doi:10.19111/bulletinofmre.772360
Chicago Abdioğlu, Emel, Mehmet Arslan, Cahit Helvacı, İbrahim Gündoğan, İrfan Temizel, ve Didem Aydınçakır. “Geochemistry of Miocene Evaporites from the Aşkale (Erzurum, Eastern Turkey) Area: Constraints for Paleo-Environment”. Bulletin of the Mineral Research and Exploration 165, sy. 165 (Ağustos 2021): 113-40. https://doi.org/10.19111/bulletinofmre.772360.
EndNote Abdioğlu E, Arslan M, Helvacı C, Gündoğan İ, Temizel İ, Aydınçakır D (01 Ağustos 2021) Geochemistry of Miocene evaporites from the Aşkale (Erzurum, Eastern Turkey) area: constraints for paleo-environment. Bulletin of the Mineral Research and Exploration 165 165 113–140.
IEEE E. Abdioğlu, M. Arslan, C. Helvacı, İ. Gündoğan, İ. Temizel, ve D. Aydınçakır, “Geochemistry of Miocene evaporites from the Aşkale (Erzurum, Eastern Turkey) area: constraints for paleo-environment”, Bull.Min.Res.Exp., c. 165, sy. 165, ss. 113–140, 2021, doi: 10.19111/bulletinofmre.772360.
ISNAD Abdioğlu, Emel vd. “Geochemistry of Miocene Evaporites from the Aşkale (Erzurum, Eastern Turkey) Area: Constraints for Paleo-Environment”. Bulletin of the Mineral Research and Exploration 165/165 (Ağustos 2021), 113-140. https://doi.org/10.19111/bulletinofmre.772360.
JAMA Abdioğlu E, Arslan M, Helvacı C, Gündoğan İ, Temizel İ, Aydınçakır D. Geochemistry of Miocene evaporites from the Aşkale (Erzurum, Eastern Turkey) area: constraints for paleo-environment. Bull.Min.Res.Exp. 2021;165:113–140.
MLA Abdioğlu, Emel vd. “Geochemistry of Miocene Evaporites from the Aşkale (Erzurum, Eastern Turkey) Area: Constraints for Paleo-Environment”. Bulletin of the Mineral Research and Exploration, c. 165, sy. 165, 2021, ss. 113-40, doi:10.19111/bulletinofmre.772360.
Vancouver Abdioğlu E, Arslan M, Helvacı C, Gündoğan İ, Temizel İ, Aydınçakır D. Geochemistry of Miocene evaporites from the Aşkale (Erzurum, Eastern Turkey) area: constraints for paleo-environment. Bull.Min.Res.Exp. 2021;165(165):113-40.

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