Araştırma Makalesi
BibTex RIS Kaynak Göster

EFFECT OF DRYING PROCESS ON PESTICIDE RESIDUES IN GRAPES

Yıl 2017, Cilt: 42 Sayı: 2, 204 - 209, 15.04.2017

Öz

In this study, drying kinetics of chlorpyrifos, diazinon, dimethoate and
methidathion pesticides on grape samples were determined. Grapes were dried
under two conditions: by sunlight (for 21 days) and in a ventilated oven at
different temperatures (at 50 °C for 72 hrs, at 60 °C for 60 hrs, at 70 °C for
48 hrs, at 80°C for 36 hrs).
 During sun drying, half-lives
of
chlorpyrifos,
diazinon and methidathion were 5.64, 6.42 and 5.25 days,
respectively. The data for dimethoate did not fit 0th,, 1st
and 2nd order kinetics. During oven-drying, the pesticides followed
the first order kinetic model. When the temperature increased, degradation of
pesticides raised. The activation energies of
dimethoate,
diazinon, chlorpyrifos and methidathion were calculated as 42.02, 42.18, 42.01
and 41.08 J/mol, respectively. 

Kaynakça

  • Göktürk Baydar N, Akkurt M. 2001. Oil Content and Oil Quality Properties of Some Grape Seeds. Turk J Agric For, 25, 163-168.
  • Özden Ç. 2005. Kuru Üzüm (Raisins). T.C.Başbakanlık Dış Ticaret Müsteşarlığı İhracatı Geliştirme Etüd Merkezi. 1-5.
  • Savant RH, Banerjee K, Utture SC, Patil SH, Dasgupta S, Ghaste MS, Adsule PG. 2010. Multiresidue Analysis of 50 Pesticides in Grape, Pomegranate, and Mango by Gas Chromatography-Ion Trap Mass Spectrometry. J Agric Food Chem, 58, 1447–1454.
  • Turgut C, Örnek H, Cutright TJ. 2010. Pesticide residues in dried table grapes from the Aegean region of Turkey. Environ Monit Assess, 67, 143–149.
  • Cabras P, Garau VL, Pirisi FM, Cubeddu M, Cabitza F, Spanedda L. 1995. Fate of Some Insecticides from Vine to Wine. J Agric Food Chem, 43, 2613–2615.
  • Fang Y, Zhang A, Wang H, Li H, Zhang Z, Chen S, Luan L. 2010. Health risk assessment of trace elements in Chinese raisins produced in Xinjiang province. Food Control, 21, 732–739.
  • Amvrazi E, Albanis T. 2008. Multiclass pesticide determination in olives and their processing factors in olive oil: Comparison of different olive oil extraction systems. J Agric Food Chem, 56, 5700–5709.
  • Amvrazi EG. 2010. Report “Fate of Pesticide Residues on Raw Agricultural Crops after Post harvest Storage and Food Processing to Edible Portions”. Pesticides - Formulations, Effects, Fate. 28, 576-594.
  • González-Rodríguez RM, Rial-Otero R, Cancho-Grande B, Gonzalez-Barreiro C, Simal Gándara J. 2011. A Review on the Fate of Pesticides during the Processes within the Food Production Chain. Crit Rev Food Sci Nutr, 51, 99–114.
  • Ke Keikotlhaile, BM, Spanoghe P. 2011. Pesticide Residues in Fruits and Vegetables. In: Stoytcheva M (ed) Pesticides - Formulations, Effects, Fate. Pesticides - Formulations, Effects, Fate Available via InTech. http://www.intechopen.com/books/pesticides- formulations-effects-fate/pesticide-residues-in-fruits-andvegetables.
  • AOAC 1997. Official Methods of Analysis of AOAC International (16th. Pub), (930.15). Arlington, VA, USA.
  • Lehotay SJ, De-Kok A, Hiemstra M, Bodegraven P. 2005. Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection. J AOAC Int, 88, 595-612.
  • JMPR 2009. JMPR Practices in Evaluation of Pesticide Residue Data. In: Submission and Evaluation of Pesticide Residue Data for the Estimation of Maximum Residue Levels in Food and Feed. FAO Plant Production and Protection Paper 197. FAO, Rome, p 68.
  • Cabras P, Angioni A. 2000. Pesticide Residues in Grapes, Wine, and Their Processing Products. J Agric Food Chem, 48, 967–973.
  • Katagi T. 2004. Photodegradation of pesticides on plant and soil surfaces. Rev Environ Contam Toxicol, 182, 181–189.
  • FAO 1988. Diazinon. FAO Specifications For Plant Protection Products
  • FAO 2004. Chlorpyrifos. FAO Specifications For Plant Protection Products
  • FAO 2012. Dimethoate. FAO Specifications For Plant Protection Products
  • Washburn AD. 2003. The Environmental Fate of Methidathion. http://www.cdpr.ca.gov/docs/emon/pubs/fatememo/methidathion.pdf

KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ

Yıl 2017, Cilt: 42 Sayı: 2, 204 - 209, 15.04.2017

Öz

Bu çalışmada üzümlerde bulunan chlorpyrifos,
diazinon, dimethoate ve methidathion pestisitlerinin kurutma kinetikleri
belirlenmiştir. G
üneşte ve
farklı sıcaklılarda (50°C’de 72 saat, 60°C’de 60 saat, 70°C’de 48 saat, 80°C’de
36 saat süre ile) hava akımlı etüvde kurutma işlemi olmak üzere iki farklı
kurutma işlemi uygulanmıştır. Güneşte kurutma işleminde
chlorpyrifos, diazinon ve methidathion pestisitlerinin yarılanma ömürleri
sırasıyla
5.64, 6.42 ve 5.25 gün olarak bulunmuştur. Dimethoate verileri 0., 1. ve 2. derece kinetik uyumu
göstermemiştir. Sıcaklık yükseldikçe pestisitlerin parçalanması artmıştır.
Dimethoate, diazinon, chlorpyrifos ve methidathionun aktivasyon
enerjileri sırasıyla 42.02, 42.18, 42.01 ve 41.08 J/mol olarak hesaplanmıştır.

Kaynakça

  • Göktürk Baydar N, Akkurt M. 2001. Oil Content and Oil Quality Properties of Some Grape Seeds. Turk J Agric For, 25, 163-168.
  • Özden Ç. 2005. Kuru Üzüm (Raisins). T.C.Başbakanlık Dış Ticaret Müsteşarlığı İhracatı Geliştirme Etüd Merkezi. 1-5.
  • Savant RH, Banerjee K, Utture SC, Patil SH, Dasgupta S, Ghaste MS, Adsule PG. 2010. Multiresidue Analysis of 50 Pesticides in Grape, Pomegranate, and Mango by Gas Chromatography-Ion Trap Mass Spectrometry. J Agric Food Chem, 58, 1447–1454.
  • Turgut C, Örnek H, Cutright TJ. 2010. Pesticide residues in dried table grapes from the Aegean region of Turkey. Environ Monit Assess, 67, 143–149.
  • Cabras P, Garau VL, Pirisi FM, Cubeddu M, Cabitza F, Spanedda L. 1995. Fate of Some Insecticides from Vine to Wine. J Agric Food Chem, 43, 2613–2615.
  • Fang Y, Zhang A, Wang H, Li H, Zhang Z, Chen S, Luan L. 2010. Health risk assessment of trace elements in Chinese raisins produced in Xinjiang province. Food Control, 21, 732–739.
  • Amvrazi E, Albanis T. 2008. Multiclass pesticide determination in olives and their processing factors in olive oil: Comparison of different olive oil extraction systems. J Agric Food Chem, 56, 5700–5709.
  • Amvrazi EG. 2010. Report “Fate of Pesticide Residues on Raw Agricultural Crops after Post harvest Storage and Food Processing to Edible Portions”. Pesticides - Formulations, Effects, Fate. 28, 576-594.
  • González-Rodríguez RM, Rial-Otero R, Cancho-Grande B, Gonzalez-Barreiro C, Simal Gándara J. 2011. A Review on the Fate of Pesticides during the Processes within the Food Production Chain. Crit Rev Food Sci Nutr, 51, 99–114.
  • Ke Keikotlhaile, BM, Spanoghe P. 2011. Pesticide Residues in Fruits and Vegetables. In: Stoytcheva M (ed) Pesticides - Formulations, Effects, Fate. Pesticides - Formulations, Effects, Fate Available via InTech. http://www.intechopen.com/books/pesticides- formulations-effects-fate/pesticide-residues-in-fruits-andvegetables.
  • AOAC 1997. Official Methods of Analysis of AOAC International (16th. Pub), (930.15). Arlington, VA, USA.
  • Lehotay SJ, De-Kok A, Hiemstra M, Bodegraven P. 2005. Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection. J AOAC Int, 88, 595-612.
  • JMPR 2009. JMPR Practices in Evaluation of Pesticide Residue Data. In: Submission and Evaluation of Pesticide Residue Data for the Estimation of Maximum Residue Levels in Food and Feed. FAO Plant Production and Protection Paper 197. FAO, Rome, p 68.
  • Cabras P, Angioni A. 2000. Pesticide Residues in Grapes, Wine, and Their Processing Products. J Agric Food Chem, 48, 967–973.
  • Katagi T. 2004. Photodegradation of pesticides on plant and soil surfaces. Rev Environ Contam Toxicol, 182, 181–189.
  • FAO 1988. Diazinon. FAO Specifications For Plant Protection Products
  • FAO 2004. Chlorpyrifos. FAO Specifications For Plant Protection Products
  • FAO 2012. Dimethoate. FAO Specifications For Plant Protection Products
  • Washburn AD. 2003. The Environmental Fate of Methidathion. http://www.cdpr.ca.gov/docs/emon/pubs/fatememo/methidathion.pdf
Toplam 19 adet kaynakça vardır.

Ayrıntılar

Bölüm Makaleler
Yazarlar

Ayşe Özbey, Şeyda Karagöz, Ali Cingöz

Yayımlanma Tarihi 15 Nisan 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 42 Sayı: 2

Kaynak Göster

APA Şeyda Karagöz, Ali Cingöz, A. Ö. (2017). KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ. Gıda, 42(2), 204-209.
AMA Şeyda Karagöz, Ali Cingöz AÖ. KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ. GIDA. Nisan 2017;42(2):204-209.
Chicago Şeyda Karagöz, Ali Cingöz, Ayşe Özbey,. “KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ”. Gıda 42, sy. 2 (Nisan 2017): 204-9.
EndNote Şeyda Karagöz, Ali Cingöz AÖ (01 Nisan 2017) KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ. Gıda 42 2 204–209.
IEEE A. Ö. Şeyda Karagöz, Ali Cingöz, “KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ”, GIDA, c. 42, sy. 2, ss. 204–209, 2017.
ISNAD Şeyda Karagöz, Ali Cingöz, Ayşe Özbey,. “KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ”. Gıda 42/2 (Nisan 2017), 204-209.
JAMA Şeyda Karagöz, Ali Cingöz AÖ. KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ. GIDA. 2017;42:204–209.
MLA Şeyda Karagöz, Ali Cingöz, Ayşe Özbey,. “KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ”. Gıda, c. 42, sy. 2, 2017, ss. 204-9.
Vancouver Şeyda Karagöz, Ali Cingöz AÖ. KURUTMA İŞLEMİNİN ÜZÜMLERDE BULUNAN PESTİSİTLER ÜZERİNE ETKİSİ. GIDA. 2017;42(2):204-9.

by-nc.png

GIDA Dergisi Creative Commons Atıf-Gayri Ticari 4.0 (CC BY-NC 4.0) Uluslararası Lisansı ile lisanslanmıştır. 

GIDA / The Journal of FOOD is licensed under a Creative Commons Attribution-Non Commercial 4.0 International (CC BY-NC 4.0).

https://creativecommons.org/licenses/by-nc/4.0/