Araştırma Makalesi
BibTex RIS Kaynak Göster

Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat ve Hidrojen Peroksit Aktivasyonu ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı ile Reaksiyon Koşullarının Optimizasyonu

Yıl 2023, Cilt: 13 Sayı: 4, 2790 - 2808, 01.12.2023
https://doi.org/10.21597/jist.1269180

Öz

Bu çalışmada, çeşitli tabakalı çift hidroksit (TÇH) katalizörlerinin peroksimonosülfat ve hidrojen peroksit aktivasyonu performansları, model gıda boyası olarak seçilen tartrazinin sulu çözeltilerden uzaklaştırılmasında test edilmiştir. Cu-Fe-TÇH, Co-Fe-TÇH ve Ni-Fe-TÇH’nin peroksimonosülfat ve hidrojen peroksit varlığında katalitik aktiviteleri karşılaştırılmıştır. Farklı oksidanlar kullanılarak gerçekleştirilen katalizör tarama deneylerinde Co-Fe-TÇH ve peroksimonosülfat en uygun katalizör ve oksidan olarak belirlenmiştir. Katalizör yüklemesi, pH ve oksidan/boya molar oranının etkileşimli etkileri araştırılmış ve Box-Behnken Design ve tepki yüzeyi metodolojisi kullanılarak reaksiyon koşulları optimize edilmiştir. 2 g/L katalizör yüklemesi, pH 3 ve 11,36 oksidan/boya molar oranı olarak belirlenen optimum reaksiyon koşullarında %87.35 organik madde giderimi ve %97.47 renk giderimi elde edilmiştir.

Destekleyen Kurum

Ege Üniversitesi

Proje Numarası

FKB-2021-22402

Teşekkür

Bu çalışma Ege Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi tarafından desteklenmiştir (Proje Numarası: FKB-2021-22402).

Kaynakça

  • Akay, S. (2020). Ultrasonik Ortamda Biyokömür Kullanarak Sulu Çözeltiden 5-Florourasilin Giderilmesi: Yanıt Yüzey Modellemesi ve Optimizasyonu. Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi, 15(2), 264–286. https://doi.org/10.29233/sdufeffd.800157
  • Alcantara-Cobos, A., Gutiérrez-Segura, E., Solache-Ríos, M., Amaya-Chávez, A. ve Solís-Casados, D. A. (2020). Tartrazine removal by ZnO nanoparticles and a zeolite-ZnO nanoparticles composite and the phytotoxicity of ZnO nanoparticles. Microporous and Mesoporous Materials, 302. https://doi.org/10.1016/j.micromeso.2020.110212
  • Alipour, M., Vosoughi, M., Mokhtari, S. A., Sadeghi, H., Rashtbari, Y., Shirmardi, M. ve Azad, R. (2021). Optimising the basic violet 16 adsorption from aqueous solutions by magnetic graphene oxide using the response surface model based on the Box–Behnken design. International Journal of Environmental Analytical Chemistry, 101(6), 758–777. https://doi.org/10.1080/03067319.2019.1671378
  • Ba-Abbad, M. M., Chai, P. V., Takriff, M. S., Benamor, A. ve Mohammad, A. W. (2015). Optimization of nickel oxide nanoparticle synthesis through the sol-gel method using Box-Behnken design. Materials and Design, 86, 948–956. https://doi.org/10.1016/j.matdes.2015.07.176
  • Bai, J., Liu, Y., Yin, X., Duan, H. ve Ma, J. (2017). Efficient removal of nitrobenzene by Fenton-like process with Co-Fe layered double hydroxide. Applied Surface Science, 416, 45–50. https://doi.org/10.1016/j.apsusc.2017.04.117
  • Bouzayani, B., Rosales, E., Pazos, M., Elaoud, S. C. ve Sanromán, M. A. (2019). Homogeneous and heterogeneous peroxymonosulfate activation by transition metals for the degradation of industrial leather dye. Journal of Cleaner Production, 228, 222–230. https://doi.org/10.1016/j.jclepro.2019.04.217
  • Buu, T. T., Ngoc, B. K., Quan, V. M., Hai, N. D., Nam, N. T. H. ve Hieu, N. H. (2023). The removal enhancement of organic contaminations and optimization of the photocatalytic efficiency by Box-Behnken design using ZnO-TiO2/porous graphene aerogel. Environmental Science and Pollution Research. https://doi.org/10.1007/s11356-023-28100-z
  • Chen, D., Ma, X., Zhou, J., Chen, X. ve Qian, G. (2014). Sulfate radical-induced degradation of Acid Orange 7 by a new magnetic composite catalyzed peroxymonosulfate oxidation process. Journal of Hazardous Materials, 279, 476–484. https://doi.org/10.1016/j.jhazmat.2014.06.004
  • Chen, X., Zhou, Y., Li, J., Pillai, S. C., Bolan, N., He, J., … Wang, H. (2022). Activated peroxydisulfate by sorghum straw-based biochar for enhanced tartrazine degradation: Roles of adsorption and radical/nonradical processes. Environmental Pollution, 316(P2), 120665. https://doi.org/10.1016/j.envpol.2022.120665
  • de Oliveira, A. G., Ribeiro, J. P., Neto, E. F. A., de Lima, A. C. A., Amazonas, Á. A., da Silva, L. T. V. ve do Nascimento, R. F. (2020). Removal of natural organic matter from aqueous solutions using electrocoagulation pulsed current: optimization using response surface methodology. Water Science and Technology. https://doi.org/10.2166/wst.2020.323
  • Deng, Y., Zou, X., Liu, Z., Wang, J., Wang, Z. ve Tang, J. (2021). Co7Fe3/CoFe2O4@C Lamellar composites derived from Co–Fe LDH/PVA as an effective heterogeneous activator of peroxymonosulfate. Journal of Alloys and Compounds, 854, 157244. https://doi.org/10.1016/j.jallcom.2020.157244
  • Dos Santos, J. R., de Sousa Soares, L., Soares, B. M., de Gomes Farias, M., de Oliveira, V. A., de Sousa, N. A. B., … de Castro E Sousa, J. M. (2022). Cytotoxic and mutagenic effects of the food additive tartrazine on eukaryotic cells. BMC Pharmacology & Toxicology, 23(1), 95. https://doi.org/10.1186/s40360-022-00638-7
  • Dung, N. T., Duong, L. T., Hoa, N. T., Thao, V. D., Ngan, L. V. ve Huy, N. N. (2022). A comprehensive study on the heterogeneous electro-Fenton degradation of tartrazine in water using CoFe2O4/carbon felt cathode. Chemosphere, 287(P2), 132141. https://doi.org/10.1016/j.chemosphere.2021.132141
  • Farhan Hanafi, M. ve Sapawe, N. (2020). A review on the water problem associate with organic pollutants derived from phenol, methyl orange, and remazol brilliant blue dyes. Materials Today: Proceedings, 31(Part 1), A141–A150. https://doi.org/10.1016/j.matpr.2021.01.258
  • Fu, H., Ma, S., Zhao, P., Xu, S. ve Zhan, S. (2019). Activation of peroxymonosulfate by graphitized hierarchical porous biochar and MnFe2O4 magnetic nanoarchitecture for organic pollutants degradation: Structure dependence and mechanism. Chemical Engineering Journal, 360, 157–170. https://doi.org/10.1016/j.cej.2018.11.207
  • Fu, H., Zhao, P., Xu, S., Cheng, G., Li, Z., Li, Y., … Ma, S. (2019). Fabrication of Fe3O4 and graphitized porous biochar composites for activating peroxymonosulfate to degrade p-hydroxybenzoic acid: Insights on the mechanism. Chemical Engineering Journal, 375, 121980. https://doi.org/10.1016/j.cej.2019.121980
  • Gholami, P., Dinpazhoh, L., Khataee, A., Hassani, A. ve Bhatnagar, A. (2020). Facile hydrothermal synthesis of novel Fe-Cu layered double hydroxide/biochar nanocomposite with enhanced sonocatalytic activity for degradation of cefazolin sodium. Journal of Hazardous Materials, 381, 120742. https://doi.org/10.1016/j.jhazmat.2019.120742
  • Gong, C., Chen, F., Yang, Q., Luo, K., Yao, F., Wang, S., … Zeng, G. (2017). Heterogeneous activation of peroxymonosulfate by Fe-Co layered doubled hydroxide for efficient catalytic degradation of Rhoadmine B. Chemical Engineering Journal, 321, 222–232. https://doi.org/10.1016/j.cej.2017.03.117
  • Gupta, A. D., Singh, H., Varjani, S., Awasthi, M. K., Giri, B. S. ve Pandey, A. (2022). A critical review on biochar-based catalysts for the abatement of toxic pollutants from water via advanced oxidation processes (AOPs). Science of the Total Environment, 849, 157831. https://doi.org/10.1016/j.scitotenv.2022.157831
  • Hong, Y., Peng, J., Zhao, X., Yan, Y., Lai, B. ve Yao, G. (2019). Efficient degradation of atrazine by CoMgAl layered double oxides catalyzed peroxymonosulfate: Optimization, degradation pathways and mechanism. Chemical Engineering Journal, 370, 354–363. https://doi.org/10.1016/j.cej.2019.03.127
  • Huang, T., Chen, J., Wang, Z., Guo, X. ve Crittenden, J. C. (2017). Excellent performance of cobalt-impregnated activated carbon in peroxymonosulfate activation for acid orange 7 oxidation. Environmental Science and Pollution Research, 24(10), 9651–9661. https://doi.org/10.1007/s11356-017-8648-7
  • Jemini, Singh, S. ve Pal, B. (2022). Efficient ZnCr LDH/monoclinic‐WO3 composites for Degradation of Tetracycline under Visible Light. ChemistrySelect, 7(48). https://doi.org/10.1002/slct.202203846
  • Jin, X., Huang, Y., He, S., Chen, G., Liu, X., He, C., Chen, Q. (2023). Preparation of Co-Fe based Prussian blue analogs loaded nickel foams for Fenton-like degradation of tetracycline. Applied Catalysis A: General, 650, 118985. https://doi.org/10.1016/j.apcata.2022.118985
  • Khan, S. A., Khan, S. B. ve Asiri, A. M. (2016). Layered double hydroxide of Cd-Al/C for the Mineralization and De-coloration of Dyes in Solar and Visible Light Exposure. Scientific Reports, 6, 14–18. https://doi.org/10.1038/srep35107
  • Khataee, A., Sadeghi Rad, T., Nikzat, S., Hassani, A., Aslan, M. H., Kobya, M. ve Demirbaş, E. (2019). Fabrication of NiFe layered double hydroxide/reduced graphene oxide (NiFe-LDH/rGO) nanocomposite with enhanced sonophotocatalytic activity for the degradation of moxifloxacin. Chemical Engineering Journal, 375, 122102. https://doi.org/10.1016/j.cej.2019.122102
  • Khodayar, N., Noori, A., Rahmanifar, M. S., Shabangoli, Y., Baghervand, A., El‐Kady, M. F., … Mousavi, M. F. (2022). Super‐Fast and Super‐Long‐Life Rechargeable Zinc Battery. Advanced Energy Materials, 12(43), 2202784. https://doi.org/10.1002/aenm.202202784
  • Luo, L., Wang, Y., Zhu, M., Cheng, X., Zhang, X., Meng, X., … Hao, H. (2019). Co-Cu-Al Layered Double Oxides as Heterogeneous Catalyst for Enhanced Degradation of Organic Pollutants in Wastewater by Activating Peroxymonosulfate: Performance and Synergistic Effect. Industrial and Engineering Chemistry Research. https://doi.org/10.1021/acs.iecr.9b00167
  • Mahdavi, R. ve Ashraf Talesh, S. S. (2021). Enhanced selective photocatalytic and sonocatalytic degradation in mixed dye aqueous solution by ZnO/GO nanocomposites: Response surface methodology. Materials Chemistry and Physics, 267, 124581. https://doi.org/10.1016/j.matchemphys.2021.124581
  • Mandal, S., Mayadevi, S. ve Kulkarni, B. D. (2009). Adsorption of aqueous selenite [Se(IV)] species on synthetic layered double Hydroxide Materials. Industrial and Engineering Chemistry Research, 48(17), 7893–7898. https://doi.org/10.1021/ie900136s
  • Mandel, K., Drenkova-Tuhtan, A., Hutter, F., Gellermann, C., Steinmetz, H. ve Sextl, G. (2013). Layered double hydroxide ion exchangers on superparamagnetic microparticles for recovery of phosphate from waste water. J. Mater. Chem. A, 1(5), 1840–1848. https://doi.org/10.1039/C2TA00571A
  • Mikami, G., Grosu, F., Kawamura, S., Yoshida, Y., Carja, G. ve Izumi, Y. (2016). Harnessing self-supported Au nanoparticles on layered double hydroxides comprising Zn and Al for enhanced phenol decomposition under solar light. Applied Catalysis B: Environmental, 199, 260–271. https://doi.org/10.1016/j.apcatb.2016.06.031
  • Oh, W. Da, Zaeni, J. R. J., Lisak, G., Lin, K. Y. A., Leong, K. H. ve Choong, Z. Y. (2021). Accelerated organics degradation by peroxymonosulfate activated with biochar co-doped with nitrogen and sulfur. Chemosphere, 277, 130313. https://doi.org/10.1016/j.chemosphere.2021.130313
  • Oktav Akdemir, E. (2022). Zeytinyağı Endüstrisi Atıksularının Kitosan ile Koagülasyonunda Box-Behnken İstatistiksel Deney Tasarım Yönteminin Uygulanması, Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 9(1), 241–248.
  • Ouassif, H., Moujahid, E. M., Lahkale, R., Sadik, R., Bouragba, F. Z., Sabbar, E. M. ve Diouri, M. (2020). Zinc-Aluminum layered double hydroxide: High efficient removal by adsorption of tartrazine dye from aqueous solution. Surfaces and Interfaces, 18, 100401. https://doi.org/10.1016/j.surfin.2019.100401
  • Rathee, G., Awasthi, A., Sood, D., Tomar, R., Tomar, V. ve Chandra, R. (2019). A new biocompatible ternary Layered Double Hydroxide Adsorbent for ultrafast removal of anionic organic dyes. Scientific Reports, 9(1), 1–14. https://doi.org/10.1038/s41598-019-52849-4
  • Rodriguez, J. A., Ibarra, I. S., Miranda, J. M., Barrado, E. ve Santos, E. M. (2016). Magnetic solid phase extraction based on fullerene and activated carbon adsorbents for determination of azo dyes in water samples by capillary electrophoresis. Analytical Methods, 8(48), 8466–8473. https://doi.org/10.1039/c6ay02631a
  • Rosaiah, P., Vadivel, S., Prakash, N. G., Dhananjaya, M., Al-Asbahi, B. A., Roy, S., … Park, S.-H. (2023). Fabrication of Porous Ni-Co LDH Nanocomposites as Efficient Electrodes for Supercapacitors. International Journal of Energy Research, 2023, 1–10. https://doi.org/10.1155/2023/5793868
  • Rouahna, N., Ouakouak, A., Barkat, D. ve Srasra, E. (2020). Zn-Al layered double hydroxide: Synthesis, characterization and application for orthophosphates ions adsorption in aqueous medium. Materials Research Express, 7(4). https://doi.org/10.1088/2053-1591/ab73fe
  • Said, S., Elhossieny, M., Riad, M. ve Mikhail, S. (2018). Pristine Cu (Co)/Fe layered double hydroxides (Co(Cu)/Fe-LDH) as active catalysts for the transalkylation of toluene to trimethylbenzenes. Molecular Catalysis, 445, 213–222. https://doi.org/10.1016/j.mcat.2017.11.038
  • Shamsayei, M., Yamini, Y. ve Asiabi, H. (2020). A novel diatomite supported layered double hydroxide as reusable adsorbent for efficient removal of acidic dyes. International Journal of Environmental Analytical Chemistry, 00(00), 1–17. https://doi.org/10.1080/03067319.2020.1743833
  • Sharma, P., Singh, L. ve Dilbaghi, N. (2009). Optimization of process variables for decolorization of Disperse Yellow 211 by Bacillus subtilis using Box–Behnken design. Journal of Hazardous Materials, 164(2–3), 1024–1029. https://doi.org/10.1016/j.jhazmat.2008.08.104
  • Shi, Z., Wang, Y., Sun, S., Zhang, C. ve Wang, H. (2020). Removal of methylene blue from aqueous solution using Mg-Fe, Zn-Fe, Mn-Fe layered double hydroxide. Water Science and Technology, 81(12), 2522–2532. https://doi.org/10.2166/wst.2020.313
  • Solak, M. (2019). Kimyasal Spreyleme Atıksuyunun Arıtımında Elektrokoagülasyon Prosesinin Optimizasyonu: Box-Behnken Dizaynı. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, 7(3), 1367–1377. https://doi.org/10.29130/dubited.518579
  • Soufi, A., Hajjaoui, H., Elmoubarki, R., Abdennouri, M., Qourzal, S. ve Barka, N. (2022). Heterogeneous Fenton-like degradation of tartrazine using CuFe2O4 nanoparticles synthesized by sol-gel combustion. Applied Surface Science Advances, 9, 100251. https://doi.org/10.1016/j.apsadv.2022.100251
  • Stevanović, G., Jović-Jovičić, N., Krstić, J., Milutinović-Nikolić, A., Banković, P., Popović, A. ve Ajduković, M. (2022). Nanocomposite Co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine. Applied Clay Science, 230, 106718. https://doi.org/10.1016/j.clay.2022.106718
  • Tonelli, D., Gualandi, I., Musella, E. ve Scavetta, E. (2021). Synthesis and characterization of layered double hydroxides as materials for electrocatalytic applications. Nanomaterials, 11(3), 1–20. https://doi.org/10.3390/nano11030725
  • Tuna, Ö. ve Simsek, E. B. (2023). Enhanced visible-light-assisted peroxymonosulfate activation of low-cost perovskite CaFe2O4 for tartrazine degradation: Experimental design modelling. Materials Research Bulletin, 159, 112090. https://doi.org/10.1016/j.materresbull.2022.112090
  • Utami, H. P., Ahmad, N., Zahara, Z. A., Lesbani, A. ve Mohadi, R. (2022). Green Synthesis of Nickel Aluminum Layered Double Hydroxide using Chitosan as Template for Adsorption of Phenol. Science and Technology Indonesia, 7(4), 530–535. https://doi.org/10.26554/sti.2022.7.4.530-535
  • Vashisht, A., Rai, R., Thakur, S., Kondal, S., Singh, K. A., Manju, … Gilhotra, V. (2022). Anaerobic Processes in Dye Removal. In Biological Approaches in Dye-Containing Wastewater (s. 95–118). https://doi.org/10.1007/978-981-19-0545-2_4
  • Villabona-Ortíz, Á., Figueroa-Lopez, K. J. ve Ortega-Toro, R. (2022). Kinetics and Adsorption Equilibrium in the Removal of Azo-Anionic Dyes by Modified Cellulose. Sustainability, 14(6). https://doi.org/10.3390/su14063640
  • Wu, H., Zhang, Y., Long, S., Zhang, L. ve Jie, X. (2020). Tribological behavior of graphene anchored Mg-Al layered double hydroxide film on Mg alloy pre-sprayed Al coating. Applied Surface Science, 530, 146536. https://doi.org/10.1016/j.apsusc.2020.146536
  • Wu, L., Zheng, Z., Pan, F., Tang, A., Zhang, G. ve Liu, L. (2017). Influence of Reaction Temperature on the Controlled Growth of Mg-Al LDH Film. International Journal of Electrochemical Science, 6352–6364. https://doi.org/10.20964/2017.07.74
  • Xu, H., Yuan, Y., Liao, Y., Xie, J., Qu, Z., Shangguan, W. ve Yan, N. (2017). [MoS4]2– Cluster Bridges in Co–Fe Layered Double Hydroxides for Mercury Uptake from S–Hg Mixed Flue Gas. Environmental Science & Technology, 51(17), 10109–10116. https://doi.org/10.1021/acs.est.7b02537
  • Yan, J., Chen, Y., Qian, L., Gao, W., Ouyang, D. ve Chen, M. (2017). Heterogeneously catalyzed persulfate with a CuMgFe layered double hydroxide for the degradation of ethylbenzene. Journal of Hazardous Materials, 338, 372–380. https://doi.org/10.1016/j.jhazmat.2017.05.007
  • Yetilmezsoy, K., Demirel, S. ve Vanderbei, R. J. (2009). Response surface modeling of Pb(II) removal from aqueous solution by Pistacia vera L.: Box–Behnken experimental design. Journal of Hazardous Materials, 171(1–3), 551–562. https://doi.org/10.1016/j.jhazmat.2009.06.035
  • You, W., Liu, L., Xu, J., Jin, T., Fu, L. ve Pan, Y. (2022). Effect of Anions and Cations on Tartrazine Removal by the Zero-Valent Iron/Peroxymonosulfate Process: Efficiency and Major Radicals. Catalysts, 12(10), 1114. https://doi.org/10.3390/catal12101114
  • Yusuf, S., Moheb, A. ve Dinari, M. (2021). Green phenol hydroxylation by ultrasonic-assisted synthesized Mg/Cu/Al-LDH catalyst with different molar ratios of Cu2+/Mg2+. Research on Chemical Intermediates, 47(4), 1297–1313. https://doi.org/10.1007/s11164-021-04402-0
  • Zeng, H., Zhang, W., Deng, L., Luo, J., Zhou, S., Liu, X., … Crittenden, J. (2018). Degradation of dyes by peroxymonosulfate activated by ternary CoFeNi-layered double hydroxide: Catalytic performance, mechanism and kinetic modeling. Journal of Colloid and Interface Science, 515, 92–100. https://doi.org/10.1016/j.jcis.2018.01.016
  • Zhang, B., Zhang, Y., Xiang, W., Teng, Y. ve Wang, Y. (2017). Comparison of the catalytic performances of different commercial cobalt oxides for peroxymonosulfate activation during dye degradation. Chemical Research in Chinese Universities, 33(5), 822–827. https://doi.org/10.1007/s40242-017-6413-6
  • Zhang, H., Zhang, G., Bi, X. ve Chen, X. (2013). Facile assembly of a hierarchical core@shell Fe3O4@CuMgAl-LDH (layered double hydroxide) magnetic nanocatalyst for the hydroxylation of phenol. Journal of Materials Chemistry A, 1(19), 5934. https://doi.org/10.1039/c3ta10349h
  • Zhao, C., Shao, B., Yan, M., Liu, Z., Liang, Q., He, Q., … Tang, L. (2021). Activation of peroxymonosulfate by biochar-based catalysts and applications in the degradation of organic contaminants: A review. Chemical Engineering Journal, 416, 128829. https://doi.org/10.1016/j.cej.2021.128829
  • Zhao, G., Chen, X., Zou, J., Li, C., Liu, L., Zhang, T., … Jiao, F. (2018). Activation of peroxymonosulfate by Fe3O4-CsxWO3/NiAl layered double hydroxide composites for the degradation of 2,4-dichlorophenoxyacetic acid. Industrial and Engineering Chemistry Research, 57(48), 16308–16317. https://doi.org/10.1021/acs.iecr.8b04453
  • Zheng, Y. ve Chen, Y. (2017). Preparation of polypropylene/Mg-Al layered double hydroxides nanocomposites through wet pan-milling: formation of a second-staging structure in LDHs intercalates. RSC Advances, 7(3), 1520–1530. https://doi.org/10.1039/c6ra26050k
  • Zhu, J., Zhu, Z., Zhang, H., Lu, H. ve Qiu, Y. (2019). Efficient degradation of organic pollutants by peroxymonosulfate activated with MgCuFe-layered double hydroxide. RSC Advances, 9(4), 2284–2291. https://doi.org/10.1039/C8RA09841G
  • Zolgharnein, J., Shahmoradi, A. ve Ghasemi, J. B. (2013). Comparative study of Box-Behnken, central composite, and Doehlert matrix for multivariate optimization of Pb (II) adsorption onto Robinia tree leaves. Journal of Chemometrics, 27(1–2), 12–20. https://doi.org/10.1002/cem.2487

Removal of Food Dyes by Peroxymonosulfate and Hydrogen Peroxide Activation Using Layered Double Hydroxide Catalysts: Optimization of Reaction Conditions by Box-Behnken Design

Yıl 2023, Cilt: 13 Sayı: 4, 2790 - 2808, 01.12.2023
https://doi.org/10.21597/jist.1269180

Öz

In the present study, peroxymonosulfate and hydrogen peroxide activation performances of various layered double hydroxide (LDH) catalysts were tested for the removal of the model food dye, tartrazine, from aqueous solutions. Catalytic activities of Cu-Fe-LDH, Co-Fe-LDH and Ni-Fe-LDH were compared in the presence of peroxymonosulfate and hydrogen peroxide. In the catalyst screening experiments performed by using different oxidants, Co-Fe-LDH and peroxymonosulfate were determined as the most suitable catalyst and the oxidant, respectively. The interactive effects of the catalyst loading, pH and the molar ratio of the oxidant to dye were investigated and the reaction conditions were optimized by using Box-Behnken Design and response surface methodology. Under the optimum reaction conditions determined as 2 g/L of catalyst loading, pH 3, and 11.36 oxidant/dye molar ratio, 87.35% organic matter removal and 97.47% decolorization efficiencies were achieved.

Proje Numarası

FKB-2021-22402

Kaynakça

  • Akay, S. (2020). Ultrasonik Ortamda Biyokömür Kullanarak Sulu Çözeltiden 5-Florourasilin Giderilmesi: Yanıt Yüzey Modellemesi ve Optimizasyonu. Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi, 15(2), 264–286. https://doi.org/10.29233/sdufeffd.800157
  • Alcantara-Cobos, A., Gutiérrez-Segura, E., Solache-Ríos, M., Amaya-Chávez, A. ve Solís-Casados, D. A. (2020). Tartrazine removal by ZnO nanoparticles and a zeolite-ZnO nanoparticles composite and the phytotoxicity of ZnO nanoparticles. Microporous and Mesoporous Materials, 302. https://doi.org/10.1016/j.micromeso.2020.110212
  • Alipour, M., Vosoughi, M., Mokhtari, S. A., Sadeghi, H., Rashtbari, Y., Shirmardi, M. ve Azad, R. (2021). Optimising the basic violet 16 adsorption from aqueous solutions by magnetic graphene oxide using the response surface model based on the Box–Behnken design. International Journal of Environmental Analytical Chemistry, 101(6), 758–777. https://doi.org/10.1080/03067319.2019.1671378
  • Ba-Abbad, M. M., Chai, P. V., Takriff, M. S., Benamor, A. ve Mohammad, A. W. (2015). Optimization of nickel oxide nanoparticle synthesis through the sol-gel method using Box-Behnken design. Materials and Design, 86, 948–956. https://doi.org/10.1016/j.matdes.2015.07.176
  • Bai, J., Liu, Y., Yin, X., Duan, H. ve Ma, J. (2017). Efficient removal of nitrobenzene by Fenton-like process with Co-Fe layered double hydroxide. Applied Surface Science, 416, 45–50. https://doi.org/10.1016/j.apsusc.2017.04.117
  • Bouzayani, B., Rosales, E., Pazos, M., Elaoud, S. C. ve Sanromán, M. A. (2019). Homogeneous and heterogeneous peroxymonosulfate activation by transition metals for the degradation of industrial leather dye. Journal of Cleaner Production, 228, 222–230. https://doi.org/10.1016/j.jclepro.2019.04.217
  • Buu, T. T., Ngoc, B. K., Quan, V. M., Hai, N. D., Nam, N. T. H. ve Hieu, N. H. (2023). The removal enhancement of organic contaminations and optimization of the photocatalytic efficiency by Box-Behnken design using ZnO-TiO2/porous graphene aerogel. Environmental Science and Pollution Research. https://doi.org/10.1007/s11356-023-28100-z
  • Chen, D., Ma, X., Zhou, J., Chen, X. ve Qian, G. (2014). Sulfate radical-induced degradation of Acid Orange 7 by a new magnetic composite catalyzed peroxymonosulfate oxidation process. Journal of Hazardous Materials, 279, 476–484. https://doi.org/10.1016/j.jhazmat.2014.06.004
  • Chen, X., Zhou, Y., Li, J., Pillai, S. C., Bolan, N., He, J., … Wang, H. (2022). Activated peroxydisulfate by sorghum straw-based biochar for enhanced tartrazine degradation: Roles of adsorption and radical/nonradical processes. Environmental Pollution, 316(P2), 120665. https://doi.org/10.1016/j.envpol.2022.120665
  • de Oliveira, A. G., Ribeiro, J. P., Neto, E. F. A., de Lima, A. C. A., Amazonas, Á. A., da Silva, L. T. V. ve do Nascimento, R. F. (2020). Removal of natural organic matter from aqueous solutions using electrocoagulation pulsed current: optimization using response surface methodology. Water Science and Technology. https://doi.org/10.2166/wst.2020.323
  • Deng, Y., Zou, X., Liu, Z., Wang, J., Wang, Z. ve Tang, J. (2021). Co7Fe3/CoFe2O4@C Lamellar composites derived from Co–Fe LDH/PVA as an effective heterogeneous activator of peroxymonosulfate. Journal of Alloys and Compounds, 854, 157244. https://doi.org/10.1016/j.jallcom.2020.157244
  • Dos Santos, J. R., de Sousa Soares, L., Soares, B. M., de Gomes Farias, M., de Oliveira, V. A., de Sousa, N. A. B., … de Castro E Sousa, J. M. (2022). Cytotoxic and mutagenic effects of the food additive tartrazine on eukaryotic cells. BMC Pharmacology & Toxicology, 23(1), 95. https://doi.org/10.1186/s40360-022-00638-7
  • Dung, N. T., Duong, L. T., Hoa, N. T., Thao, V. D., Ngan, L. V. ve Huy, N. N. (2022). A comprehensive study on the heterogeneous electro-Fenton degradation of tartrazine in water using CoFe2O4/carbon felt cathode. Chemosphere, 287(P2), 132141. https://doi.org/10.1016/j.chemosphere.2021.132141
  • Farhan Hanafi, M. ve Sapawe, N. (2020). A review on the water problem associate with organic pollutants derived from phenol, methyl orange, and remazol brilliant blue dyes. Materials Today: Proceedings, 31(Part 1), A141–A150. https://doi.org/10.1016/j.matpr.2021.01.258
  • Fu, H., Ma, S., Zhao, P., Xu, S. ve Zhan, S. (2019). Activation of peroxymonosulfate by graphitized hierarchical porous biochar and MnFe2O4 magnetic nanoarchitecture for organic pollutants degradation: Structure dependence and mechanism. Chemical Engineering Journal, 360, 157–170. https://doi.org/10.1016/j.cej.2018.11.207
  • Fu, H., Zhao, P., Xu, S., Cheng, G., Li, Z., Li, Y., … Ma, S. (2019). Fabrication of Fe3O4 and graphitized porous biochar composites for activating peroxymonosulfate to degrade p-hydroxybenzoic acid: Insights on the mechanism. Chemical Engineering Journal, 375, 121980. https://doi.org/10.1016/j.cej.2019.121980
  • Gholami, P., Dinpazhoh, L., Khataee, A., Hassani, A. ve Bhatnagar, A. (2020). Facile hydrothermal synthesis of novel Fe-Cu layered double hydroxide/biochar nanocomposite with enhanced sonocatalytic activity for degradation of cefazolin sodium. Journal of Hazardous Materials, 381, 120742. https://doi.org/10.1016/j.jhazmat.2019.120742
  • Gong, C., Chen, F., Yang, Q., Luo, K., Yao, F., Wang, S., … Zeng, G. (2017). Heterogeneous activation of peroxymonosulfate by Fe-Co layered doubled hydroxide for efficient catalytic degradation of Rhoadmine B. Chemical Engineering Journal, 321, 222–232. https://doi.org/10.1016/j.cej.2017.03.117
  • Gupta, A. D., Singh, H., Varjani, S., Awasthi, M. K., Giri, B. S. ve Pandey, A. (2022). A critical review on biochar-based catalysts for the abatement of toxic pollutants from water via advanced oxidation processes (AOPs). Science of the Total Environment, 849, 157831. https://doi.org/10.1016/j.scitotenv.2022.157831
  • Hong, Y., Peng, J., Zhao, X., Yan, Y., Lai, B. ve Yao, G. (2019). Efficient degradation of atrazine by CoMgAl layered double oxides catalyzed peroxymonosulfate: Optimization, degradation pathways and mechanism. Chemical Engineering Journal, 370, 354–363. https://doi.org/10.1016/j.cej.2019.03.127
  • Huang, T., Chen, J., Wang, Z., Guo, X. ve Crittenden, J. C. (2017). Excellent performance of cobalt-impregnated activated carbon in peroxymonosulfate activation for acid orange 7 oxidation. Environmental Science and Pollution Research, 24(10), 9651–9661. https://doi.org/10.1007/s11356-017-8648-7
  • Jemini, Singh, S. ve Pal, B. (2022). Efficient ZnCr LDH/monoclinic‐WO3 composites for Degradation of Tetracycline under Visible Light. ChemistrySelect, 7(48). https://doi.org/10.1002/slct.202203846
  • Jin, X., Huang, Y., He, S., Chen, G., Liu, X., He, C., Chen, Q. (2023). Preparation of Co-Fe based Prussian blue analogs loaded nickel foams for Fenton-like degradation of tetracycline. Applied Catalysis A: General, 650, 118985. https://doi.org/10.1016/j.apcata.2022.118985
  • Khan, S. A., Khan, S. B. ve Asiri, A. M. (2016). Layered double hydroxide of Cd-Al/C for the Mineralization and De-coloration of Dyes in Solar and Visible Light Exposure. Scientific Reports, 6, 14–18. https://doi.org/10.1038/srep35107
  • Khataee, A., Sadeghi Rad, T., Nikzat, S., Hassani, A., Aslan, M. H., Kobya, M. ve Demirbaş, E. (2019). Fabrication of NiFe layered double hydroxide/reduced graphene oxide (NiFe-LDH/rGO) nanocomposite with enhanced sonophotocatalytic activity for the degradation of moxifloxacin. Chemical Engineering Journal, 375, 122102. https://doi.org/10.1016/j.cej.2019.122102
  • Khodayar, N., Noori, A., Rahmanifar, M. S., Shabangoli, Y., Baghervand, A., El‐Kady, M. F., … Mousavi, M. F. (2022). Super‐Fast and Super‐Long‐Life Rechargeable Zinc Battery. Advanced Energy Materials, 12(43), 2202784. https://doi.org/10.1002/aenm.202202784
  • Luo, L., Wang, Y., Zhu, M., Cheng, X., Zhang, X., Meng, X., … Hao, H. (2019). Co-Cu-Al Layered Double Oxides as Heterogeneous Catalyst for Enhanced Degradation of Organic Pollutants in Wastewater by Activating Peroxymonosulfate: Performance and Synergistic Effect. Industrial and Engineering Chemistry Research. https://doi.org/10.1021/acs.iecr.9b00167
  • Mahdavi, R. ve Ashraf Talesh, S. S. (2021). Enhanced selective photocatalytic and sonocatalytic degradation in mixed dye aqueous solution by ZnO/GO nanocomposites: Response surface methodology. Materials Chemistry and Physics, 267, 124581. https://doi.org/10.1016/j.matchemphys.2021.124581
  • Mandal, S., Mayadevi, S. ve Kulkarni, B. D. (2009). Adsorption of aqueous selenite [Se(IV)] species on synthetic layered double Hydroxide Materials. Industrial and Engineering Chemistry Research, 48(17), 7893–7898. https://doi.org/10.1021/ie900136s
  • Mandel, K., Drenkova-Tuhtan, A., Hutter, F., Gellermann, C., Steinmetz, H. ve Sextl, G. (2013). Layered double hydroxide ion exchangers on superparamagnetic microparticles for recovery of phosphate from waste water. J. Mater. Chem. A, 1(5), 1840–1848. https://doi.org/10.1039/C2TA00571A
  • Mikami, G., Grosu, F., Kawamura, S., Yoshida, Y., Carja, G. ve Izumi, Y. (2016). Harnessing self-supported Au nanoparticles on layered double hydroxides comprising Zn and Al for enhanced phenol decomposition under solar light. Applied Catalysis B: Environmental, 199, 260–271. https://doi.org/10.1016/j.apcatb.2016.06.031
  • Oh, W. Da, Zaeni, J. R. J., Lisak, G., Lin, K. Y. A., Leong, K. H. ve Choong, Z. Y. (2021). Accelerated organics degradation by peroxymonosulfate activated with biochar co-doped with nitrogen and sulfur. Chemosphere, 277, 130313. https://doi.org/10.1016/j.chemosphere.2021.130313
  • Oktav Akdemir, E. (2022). Zeytinyağı Endüstrisi Atıksularının Kitosan ile Koagülasyonunda Box-Behnken İstatistiksel Deney Tasarım Yönteminin Uygulanması, Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 9(1), 241–248.
  • Ouassif, H., Moujahid, E. M., Lahkale, R., Sadik, R., Bouragba, F. Z., Sabbar, E. M. ve Diouri, M. (2020). Zinc-Aluminum layered double hydroxide: High efficient removal by adsorption of tartrazine dye from aqueous solution. Surfaces and Interfaces, 18, 100401. https://doi.org/10.1016/j.surfin.2019.100401
  • Rathee, G., Awasthi, A., Sood, D., Tomar, R., Tomar, V. ve Chandra, R. (2019). A new biocompatible ternary Layered Double Hydroxide Adsorbent for ultrafast removal of anionic organic dyes. Scientific Reports, 9(1), 1–14. https://doi.org/10.1038/s41598-019-52849-4
  • Rodriguez, J. A., Ibarra, I. S., Miranda, J. M., Barrado, E. ve Santos, E. M. (2016). Magnetic solid phase extraction based on fullerene and activated carbon adsorbents for determination of azo dyes in water samples by capillary electrophoresis. Analytical Methods, 8(48), 8466–8473. https://doi.org/10.1039/c6ay02631a
  • Rosaiah, P., Vadivel, S., Prakash, N. G., Dhananjaya, M., Al-Asbahi, B. A., Roy, S., … Park, S.-H. (2023). Fabrication of Porous Ni-Co LDH Nanocomposites as Efficient Electrodes for Supercapacitors. International Journal of Energy Research, 2023, 1–10. https://doi.org/10.1155/2023/5793868
  • Rouahna, N., Ouakouak, A., Barkat, D. ve Srasra, E. (2020). Zn-Al layered double hydroxide: Synthesis, characterization and application for orthophosphates ions adsorption in aqueous medium. Materials Research Express, 7(4). https://doi.org/10.1088/2053-1591/ab73fe
  • Said, S., Elhossieny, M., Riad, M. ve Mikhail, S. (2018). Pristine Cu (Co)/Fe layered double hydroxides (Co(Cu)/Fe-LDH) as active catalysts for the transalkylation of toluene to trimethylbenzenes. Molecular Catalysis, 445, 213–222. https://doi.org/10.1016/j.mcat.2017.11.038
  • Shamsayei, M., Yamini, Y. ve Asiabi, H. (2020). A novel diatomite supported layered double hydroxide as reusable adsorbent for efficient removal of acidic dyes. International Journal of Environmental Analytical Chemistry, 00(00), 1–17. https://doi.org/10.1080/03067319.2020.1743833
  • Sharma, P., Singh, L. ve Dilbaghi, N. (2009). Optimization of process variables for decolorization of Disperse Yellow 211 by Bacillus subtilis using Box–Behnken design. Journal of Hazardous Materials, 164(2–3), 1024–1029. https://doi.org/10.1016/j.jhazmat.2008.08.104
  • Shi, Z., Wang, Y., Sun, S., Zhang, C. ve Wang, H. (2020). Removal of methylene blue from aqueous solution using Mg-Fe, Zn-Fe, Mn-Fe layered double hydroxide. Water Science and Technology, 81(12), 2522–2532. https://doi.org/10.2166/wst.2020.313
  • Solak, M. (2019). Kimyasal Spreyleme Atıksuyunun Arıtımında Elektrokoagülasyon Prosesinin Optimizasyonu: Box-Behnken Dizaynı. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, 7(3), 1367–1377. https://doi.org/10.29130/dubited.518579
  • Soufi, A., Hajjaoui, H., Elmoubarki, R., Abdennouri, M., Qourzal, S. ve Barka, N. (2022). Heterogeneous Fenton-like degradation of tartrazine using CuFe2O4 nanoparticles synthesized by sol-gel combustion. Applied Surface Science Advances, 9, 100251. https://doi.org/10.1016/j.apsadv.2022.100251
  • Stevanović, G., Jović-Jovičić, N., Krstić, J., Milutinović-Nikolić, A., Banković, P., Popović, A. ve Ajduković, M. (2022). Nanocomposite Co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine. Applied Clay Science, 230, 106718. https://doi.org/10.1016/j.clay.2022.106718
  • Tonelli, D., Gualandi, I., Musella, E. ve Scavetta, E. (2021). Synthesis and characterization of layered double hydroxides as materials for electrocatalytic applications. Nanomaterials, 11(3), 1–20. https://doi.org/10.3390/nano11030725
  • Tuna, Ö. ve Simsek, E. B. (2023). Enhanced visible-light-assisted peroxymonosulfate activation of low-cost perovskite CaFe2O4 for tartrazine degradation: Experimental design modelling. Materials Research Bulletin, 159, 112090. https://doi.org/10.1016/j.materresbull.2022.112090
  • Utami, H. P., Ahmad, N., Zahara, Z. A., Lesbani, A. ve Mohadi, R. (2022). Green Synthesis of Nickel Aluminum Layered Double Hydroxide using Chitosan as Template for Adsorption of Phenol. Science and Technology Indonesia, 7(4), 530–535. https://doi.org/10.26554/sti.2022.7.4.530-535
  • Vashisht, A., Rai, R., Thakur, S., Kondal, S., Singh, K. A., Manju, … Gilhotra, V. (2022). Anaerobic Processes in Dye Removal. In Biological Approaches in Dye-Containing Wastewater (s. 95–118). https://doi.org/10.1007/978-981-19-0545-2_4
  • Villabona-Ortíz, Á., Figueroa-Lopez, K. J. ve Ortega-Toro, R. (2022). Kinetics and Adsorption Equilibrium in the Removal of Azo-Anionic Dyes by Modified Cellulose. Sustainability, 14(6). https://doi.org/10.3390/su14063640
  • Wu, H., Zhang, Y., Long, S., Zhang, L. ve Jie, X. (2020). Tribological behavior of graphene anchored Mg-Al layered double hydroxide film on Mg alloy pre-sprayed Al coating. Applied Surface Science, 530, 146536. https://doi.org/10.1016/j.apsusc.2020.146536
  • Wu, L., Zheng, Z., Pan, F., Tang, A., Zhang, G. ve Liu, L. (2017). Influence of Reaction Temperature on the Controlled Growth of Mg-Al LDH Film. International Journal of Electrochemical Science, 6352–6364. https://doi.org/10.20964/2017.07.74
  • Xu, H., Yuan, Y., Liao, Y., Xie, J., Qu, Z., Shangguan, W. ve Yan, N. (2017). [MoS4]2– Cluster Bridges in Co–Fe Layered Double Hydroxides for Mercury Uptake from S–Hg Mixed Flue Gas. Environmental Science & Technology, 51(17), 10109–10116. https://doi.org/10.1021/acs.est.7b02537
  • Yan, J., Chen, Y., Qian, L., Gao, W., Ouyang, D. ve Chen, M. (2017). Heterogeneously catalyzed persulfate with a CuMgFe layered double hydroxide for the degradation of ethylbenzene. Journal of Hazardous Materials, 338, 372–380. https://doi.org/10.1016/j.jhazmat.2017.05.007
  • Yetilmezsoy, K., Demirel, S. ve Vanderbei, R. J. (2009). Response surface modeling of Pb(II) removal from aqueous solution by Pistacia vera L.: Box–Behnken experimental design. Journal of Hazardous Materials, 171(1–3), 551–562. https://doi.org/10.1016/j.jhazmat.2009.06.035
  • You, W., Liu, L., Xu, J., Jin, T., Fu, L. ve Pan, Y. (2022). Effect of Anions and Cations on Tartrazine Removal by the Zero-Valent Iron/Peroxymonosulfate Process: Efficiency and Major Radicals. Catalysts, 12(10), 1114. https://doi.org/10.3390/catal12101114
  • Yusuf, S., Moheb, A. ve Dinari, M. (2021). Green phenol hydroxylation by ultrasonic-assisted synthesized Mg/Cu/Al-LDH catalyst with different molar ratios of Cu2+/Mg2+. Research on Chemical Intermediates, 47(4), 1297–1313. https://doi.org/10.1007/s11164-021-04402-0
  • Zeng, H., Zhang, W., Deng, L., Luo, J., Zhou, S., Liu, X., … Crittenden, J. (2018). Degradation of dyes by peroxymonosulfate activated by ternary CoFeNi-layered double hydroxide: Catalytic performance, mechanism and kinetic modeling. Journal of Colloid and Interface Science, 515, 92–100. https://doi.org/10.1016/j.jcis.2018.01.016
  • Zhang, B., Zhang, Y., Xiang, W., Teng, Y. ve Wang, Y. (2017). Comparison of the catalytic performances of different commercial cobalt oxides for peroxymonosulfate activation during dye degradation. Chemical Research in Chinese Universities, 33(5), 822–827. https://doi.org/10.1007/s40242-017-6413-6
  • Zhang, H., Zhang, G., Bi, X. ve Chen, X. (2013). Facile assembly of a hierarchical core@shell Fe3O4@CuMgAl-LDH (layered double hydroxide) magnetic nanocatalyst for the hydroxylation of phenol. Journal of Materials Chemistry A, 1(19), 5934. https://doi.org/10.1039/c3ta10349h
  • Zhao, C., Shao, B., Yan, M., Liu, Z., Liang, Q., He, Q., … Tang, L. (2021). Activation of peroxymonosulfate by biochar-based catalysts and applications in the degradation of organic contaminants: A review. Chemical Engineering Journal, 416, 128829. https://doi.org/10.1016/j.cej.2021.128829
  • Zhao, G., Chen, X., Zou, J., Li, C., Liu, L., Zhang, T., … Jiao, F. (2018). Activation of peroxymonosulfate by Fe3O4-CsxWO3/NiAl layered double hydroxide composites for the degradation of 2,4-dichlorophenoxyacetic acid. Industrial and Engineering Chemistry Research, 57(48), 16308–16317. https://doi.org/10.1021/acs.iecr.8b04453
  • Zheng, Y. ve Chen, Y. (2017). Preparation of polypropylene/Mg-Al layered double hydroxides nanocomposites through wet pan-milling: formation of a second-staging structure in LDHs intercalates. RSC Advances, 7(3), 1520–1530. https://doi.org/10.1039/c6ra26050k
  • Zhu, J., Zhu, Z., Zhang, H., Lu, H. ve Qiu, Y. (2019). Efficient degradation of organic pollutants by peroxymonosulfate activated with MgCuFe-layered double hydroxide. RSC Advances, 9(4), 2284–2291. https://doi.org/10.1039/C8RA09841G
  • Zolgharnein, J., Shahmoradi, A. ve Ghasemi, J. B. (2013). Comparative study of Box-Behnken, central composite, and Doehlert matrix for multivariate optimization of Pb (II) adsorption onto Robinia tree leaves. Journal of Chemometrics, 27(1–2), 12–20. https://doi.org/10.1002/cem.2487
Toplam 65 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Kimya Mühendisliği
Bölüm Kimya / Chemistry
Yazarlar

Burcu Palas 0000-0002-2815-0057

Gülin Ersöz 0000-0002-5875-5946

Süheyda Atalay 0000-0002-1703-1044

Proje Numarası FKB-2021-22402
Erken Görünüm Tarihi 30 Kasım 2023
Yayımlanma Tarihi 1 Aralık 2023
Gönderilme Tarihi 22 Mart 2023
Kabul Tarihi 11 Temmuz 2023
Yayımlandığı Sayı Yıl 2023 Cilt: 13 Sayı: 4

Kaynak Göster

APA Palas, B., Ersöz, G., & Atalay, S. (2023). Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat ve Hidrojen Peroksit Aktivasyonu ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı ile Reaksiyon Koşullarının Optimizasyonu. Journal of the Institute of Science and Technology, 13(4), 2790-2808. https://doi.org/10.21597/jist.1269180
AMA Palas B, Ersöz G, Atalay S. Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat ve Hidrojen Peroksit Aktivasyonu ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı ile Reaksiyon Koşullarının Optimizasyonu. Iğdır Üniv. Fen Bil Enst. Der. Aralık 2023;13(4):2790-2808. doi:10.21597/jist.1269180
Chicago Palas, Burcu, Gülin Ersöz, ve Süheyda Atalay. “Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat Ve Hidrojen Peroksit Aktivasyonu Ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı Ile Reaksiyon Koşullarının Optimizasyonu”. Journal of the Institute of Science and Technology 13, sy. 4 (Aralık 2023): 2790-2808. https://doi.org/10.21597/jist.1269180.
EndNote Palas B, Ersöz G, Atalay S (01 Aralık 2023) Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat ve Hidrojen Peroksit Aktivasyonu ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı ile Reaksiyon Koşullarının Optimizasyonu. Journal of the Institute of Science and Technology 13 4 2790–2808.
IEEE B. Palas, G. Ersöz, ve S. Atalay, “Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat ve Hidrojen Peroksit Aktivasyonu ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı ile Reaksiyon Koşullarının Optimizasyonu”, Iğdır Üniv. Fen Bil Enst. Der., c. 13, sy. 4, ss. 2790–2808, 2023, doi: 10.21597/jist.1269180.
ISNAD Palas, Burcu vd. “Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat Ve Hidrojen Peroksit Aktivasyonu Ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı Ile Reaksiyon Koşullarının Optimizasyonu”. Journal of the Institute of Science and Technology 13/4 (Aralık 2023), 2790-2808. https://doi.org/10.21597/jist.1269180.
JAMA Palas B, Ersöz G, Atalay S. Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat ve Hidrojen Peroksit Aktivasyonu ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı ile Reaksiyon Koşullarının Optimizasyonu. Iğdır Üniv. Fen Bil Enst. Der. 2023;13:2790–2808.
MLA Palas, Burcu vd. “Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat Ve Hidrojen Peroksit Aktivasyonu Ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı Ile Reaksiyon Koşullarının Optimizasyonu”. Journal of the Institute of Science and Technology, c. 13, sy. 4, 2023, ss. 2790-08, doi:10.21597/jist.1269180.
Vancouver Palas B, Ersöz G, Atalay S. Tabakalı Çift Hidroksit Katalizörler Kullanılarak Peroksimonosülfat ve Hidrojen Peroksit Aktivasyonu ile Gıda Boyalarının Giderimi: Box-Behnken Tasarımı ile Reaksiyon Koşullarının Optimizasyonu. Iğdır Üniv. Fen Bil Enst. Der. 2023;13(4):2790-808.