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Investigation of the liquefaction possibility of Ermenek lignite as an alternative clean energy source

Yıl 2021, Cilt: 4 Sayı: 2, 5 - 9, 08.12.2021

Aydan Aksoğan Korkmaz

https://doi.org/10.54565/jphcfum.1001620

Öz

Coal liquefaction; can be defined as the transformation of coal into products that have a high energy density, can be easily stored and transported and do not create environmental pollution, to meet both fuel and chemical raw material requirements.
This study was carried out to determine the yields of the products formed as a result of the liquefaction of Konya-Ermenek lignite in the N2 atmosphere and under non-catalytic conditions. Proximate and ultimate analysis of the obtained solid and liquid products was made. The composition of the oil product was determined by GC-MS. As a result of liquefaction, the char yield was 71.37%, the preasphaltene yield was 12.24%, the asphaltene yield was 2.23% and the oil + gas yield was 14.16%. It was determined that the higher heating value of 4199 kcal/kg in raw lignite is twice as high in liquefaction products. It was determined that the sulfur content of 3.94% in raw lignite decreased to 1.54%, 0.85% and 0.44% in char, preasphaltene and oil, respectively.

Anahtar Kelimeler

Lignite Liquefaction Energy Char Oil

Kaynakça

  • [1] Li J, Yang J, Liu Z. (2009). Hydrogenation of heavy liquids from a direct coal liquefaction residue for improved oil yield, Fuel Processing Technology, 90: 490-495.
  • [2] Kural O. (1994). Coal Resources, Properties, Utilization, Pollution, Ozgun Press, İstanbul, p. 494.
  • [3] Ateşok G. (2009) Coal Use and Clean Coal Technologies, Karaktercolor Press, İstanbul, p. 333.
  • [4] Gül Ö, Gafarova P, Hesenov A, Schobert H.H, Erbatur O. (2004). Catalytic direct liquefaction of high sulfur lignites: temperature and solvent effect on product distributions, Prepr.Pap.-Am.Chem.Soc., Div.Fuel Chem., 49 (2): 559-561.
  • [5] Yıldız Z, Koyunoğlu, C, Karaca H. (2006). Liquefaction of Elbistan lignite and biomass under catalytic and non-catalytic conditions, 7th National Chemical Engineering Congress, 5-8 September, Eskişehir, Turkey, 1-7.
  • [6] Rahman M, Adesanwo, T, Gupta R, Klerk A. (2015). Effect of direct coal liquefaction conditions on coal liquid quality, Energy Fuels, 29: 3649-3657.
  • [7] Kanca A, Dodd M, Reimer J.A, Uner D. (2016). Following the structure and reactivity of Tunçbilek lignite during pyrolysis and hydrogenation, Fuel Processing Technology, 152: 266-273.
  • [8] Lievens C, Ci D, Bai Y, Ma L, Zhang R, Chen J.Y, Gai Q. (2013). A study of slow pyrolysis of one low rank coal via pyrolysis-GC/MS, Fuel Processing Technology, 116: 85-93.
  • [9] Xu Y, Zhang Y, Wang Y, Zhang G, Chen L. (2013). Gas evolution characteristics of lignite during low-temperature pyrolysis, Journal of Analytical and Applied Pyrolysis, 104: 625-631.
  • [10] Meng F, Yu J, Tahmasebi A, Han Y, Zhao H, Lucas J, Wall T. (2013). Characteristics of chars from low-temperature pyrolysis of lignite, Energy Fuels, 28: 275-284.
  • [11] He Q, Wan K, Hoadley A, Yeasmin H, Miao Z. (2015). TG-GC-MS study of volatile products from Shengli lignite pyrolysis, Fuel, 156: 121-128.
  • [12] Li X, Xue Y, Feng J, Yi Q, Li W, Guo X, Liu K. (2015). Co-pyrolysis of lignite and Shendong coal direct liquefaction residue, Fuel, 144: 342-348.
  • [13] Omais B, Courtiade M, Charon N, Thiebaut D, Quignard A. (2010). Characterization of oxygenated species in coal liquefaction products: An overview, Energy and Fuels, 24: 5807-5816.
  • [14] You Q, Wu S.Y, Wu Y.Q, Huang S, Gao J.S, Shang J.X, Min X.J, Zheng H.A. (2017). Product distributions and characterizations for integrated mild-liquefaction and carbonization of low rank coals, Fuel Processing Technology, 156: 54-61.
  • [15] Speight J.G. (1994). The Chemistry and Technology of Coal (2nd Edition), New York.
  • [16] Methakhup S, Ngamprasertsith S, Prasassarakich P. (2007). Improvement of oil yield and its distribution from coal extraction using sulfide catalysts, Fuel, 86: 2485-2490.
  • [17] Karaca H, Koyunuoğlu C. (2010a). Co-liquefaction of Elbistan lignite and biomass. Part I: The effect of the process parameters on the conversion of liquefaction products, Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 32: 495-511.
  • [18] Karaca H, Koyunuoğlu C. (2010b). The co-liquefaction of Elbistan lignite and biomass. Part II: The characterization of liquefaction products, Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 32: 1167-1175.
  • [19] Wang A, Tang Y, Schobert H.H, Guo Y, Su Y. (2013). Petrology and structural studies in liquefaction reactions of Late Permian coals from Southern China, Fuel, 107: 518-524.
  • [20] Aksoğan Korkmaz A, Bentli İ. (2019). A study on the investigation of improvement in coal liquefaction product efficiency, Eskişehir Technical Unıversity Journal of Science and Technology A- Applied Sciences and Engineering, 20 (4): 406-412.

Yıl 2021, Cilt: 4 Sayı: 2, 5 - 9, 08.12.2021

Aydan Aksoğan Korkmaz

https://doi.org/10.54565/jphcfum.1001620

Öz

Kaynakça

  • [1] Li J, Yang J, Liu Z. (2009). Hydrogenation of heavy liquids from a direct coal liquefaction residue for improved oil yield, Fuel Processing Technology, 90: 490-495.
  • [2] Kural O. (1994). Coal Resources, Properties, Utilization, Pollution, Ozgun Press, İstanbul, p. 494.
  • [3] Ateşok G. (2009) Coal Use and Clean Coal Technologies, Karaktercolor Press, İstanbul, p. 333.
  • [4] Gül Ö, Gafarova P, Hesenov A, Schobert H.H, Erbatur O. (2004). Catalytic direct liquefaction of high sulfur lignites: temperature and solvent effect on product distributions, Prepr.Pap.-Am.Chem.Soc., Div.Fuel Chem., 49 (2): 559-561.
  • [5] Yıldız Z, Koyunoğlu, C, Karaca H. (2006). Liquefaction of Elbistan lignite and biomass under catalytic and non-catalytic conditions, 7th National Chemical Engineering Congress, 5-8 September, Eskişehir, Turkey, 1-7.
  • [6] Rahman M, Adesanwo, T, Gupta R, Klerk A. (2015). Effect of direct coal liquefaction conditions on coal liquid quality, Energy Fuels, 29: 3649-3657.
  • [7] Kanca A, Dodd M, Reimer J.A, Uner D. (2016). Following the structure and reactivity of Tunçbilek lignite during pyrolysis and hydrogenation, Fuel Processing Technology, 152: 266-273.
  • [8] Lievens C, Ci D, Bai Y, Ma L, Zhang R, Chen J.Y, Gai Q. (2013). A study of slow pyrolysis of one low rank coal via pyrolysis-GC/MS, Fuel Processing Technology, 116: 85-93.
  • [9] Xu Y, Zhang Y, Wang Y, Zhang G, Chen L. (2013). Gas evolution characteristics of lignite during low-temperature pyrolysis, Journal of Analytical and Applied Pyrolysis, 104: 625-631.
  • [10] Meng F, Yu J, Tahmasebi A, Han Y, Zhao H, Lucas J, Wall T. (2013). Characteristics of chars from low-temperature pyrolysis of lignite, Energy Fuels, 28: 275-284.
  • [11] He Q, Wan K, Hoadley A, Yeasmin H, Miao Z. (2015). TG-GC-MS study of volatile products from Shengli lignite pyrolysis, Fuel, 156: 121-128.
  • [12] Li X, Xue Y, Feng J, Yi Q, Li W, Guo X, Liu K. (2015). Co-pyrolysis of lignite and Shendong coal direct liquefaction residue, Fuel, 144: 342-348.
  • [13] Omais B, Courtiade M, Charon N, Thiebaut D, Quignard A. (2010). Characterization of oxygenated species in coal liquefaction products: An overview, Energy and Fuels, 24: 5807-5816.
  • [14] You Q, Wu S.Y, Wu Y.Q, Huang S, Gao J.S, Shang J.X, Min X.J, Zheng H.A. (2017). Product distributions and characterizations for integrated mild-liquefaction and carbonization of low rank coals, Fuel Processing Technology, 156: 54-61.
  • [15] Speight J.G. (1994). The Chemistry and Technology of Coal (2nd Edition), New York.
  • [16] Methakhup S, Ngamprasertsith S, Prasassarakich P. (2007). Improvement of oil yield and its distribution from coal extraction using sulfide catalysts, Fuel, 86: 2485-2490.
  • [17] Karaca H, Koyunuoğlu C. (2010a). Co-liquefaction of Elbistan lignite and biomass. Part I: The effect of the process parameters on the conversion of liquefaction products, Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 32: 495-511.
  • [18] Karaca H, Koyunuoğlu C. (2010b). The co-liquefaction of Elbistan lignite and biomass. Part II: The characterization of liquefaction products, Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 32: 1167-1175.
  • [19] Wang A, Tang Y, Schobert H.H, Guo Y, Su Y. (2013). Petrology and structural studies in liquefaction reactions of Late Permian coals from Southern China, Fuel, 107: 518-524.
  • [20] Aksoğan Korkmaz A, Bentli İ. (2019). A study on the investigation of improvement in coal liquefaction product efficiency, Eskişehir Technical Unıversity Journal of Science and Technology A- Applied Sciences and Engineering, 20 (4): 406-412.
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Malzeme Üretim Teknolojileri
Bölüm Makaleler
Yazarlar

Aydan Aksoğan Korkmaz 0000-0002-3309-9719

Yayımlanma Tarihi 8 Aralık 2021
Gönderilme Tarihi 27 Eylül 2021
Kabul Tarihi 11 Ekim 2021
Yayımlandığı Sayı Yıl 2021 Cilt: 4 Sayı: 2

Kaynak Göster

APA Aksoğan Korkmaz, A. (2021). Investigation of the liquefaction possibility of Ermenek lignite as an alternative clean energy source. Journal of Physical Chemistry and Functional Materials, 4(2), 5-9. https://doi.org/10.54565/jphcfum.1001620
AMA Aksoğan Korkmaz A. Investigation of the liquefaction possibility of Ermenek lignite as an alternative clean energy source. Journal of Physical Chemistry and Functional Materials. Aralık 2021;4(2):5-9. doi:10.54565/jphcfum.1001620
Chicago Aksoğan Korkmaz, Aydan. “Investigation of the Liquefaction Possibility of Ermenek Lignite As an Alternative Clean Energy Source”. Journal of Physical Chemistry and Functional Materials 4, sy. 2 (Aralık 2021): 5-9. https://doi.org/10.54565/jphcfum.1001620.
EndNote Aksoğan Korkmaz A (01 Aralık 2021) Investigation of the liquefaction possibility of Ermenek lignite as an alternative clean energy source. Journal of Physical Chemistry and Functional Materials 4 2 5–9.
IEEE A. Aksoğan Korkmaz, “Investigation of the liquefaction possibility of Ermenek lignite as an alternative clean energy source”, Journal of Physical Chemistry and Functional Materials, c. 4, sy. 2, ss. 5–9, 2021, doi: 10.54565/jphcfum.1001620.
ISNAD Aksoğan Korkmaz, Aydan. “Investigation of the Liquefaction Possibility of Ermenek Lignite As an Alternative Clean Energy Source”. Journal of Physical Chemistry and Functional Materials 4/2 (Aralık 2021), 5-9. https://doi.org/10.54565/jphcfum.1001620.
JAMA Aksoğan Korkmaz A. Investigation of the liquefaction possibility of Ermenek lignite as an alternative clean energy source. Journal of Physical Chemistry and Functional Materials. 2021;4:5–9.
MLA Aksoğan Korkmaz, Aydan. “Investigation of the Liquefaction Possibility of Ermenek Lignite As an Alternative Clean Energy Source”. Journal of Physical Chemistry and Functional Materials, c. 4, sy. 2, 2021, ss. 5-9, doi:10.54565/jphcfum.1001620.
Vancouver Aksoğan Korkmaz A. Investigation of the liquefaction possibility of Ermenek lignite as an alternative clean energy source. Journal of Physical Chemistry and Functional Materials. 2021;4(2):5-9.
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