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CdSO4-CdS Composite nanowires synthesized by arc discharge method

Yıl 2022, Cilt: 11 Sayı: 3, 813 - 818, 18.07.2022
https://doi.org/10.28948/ngumuh.820329

Öz

Herein, we successfully carried out the of CdS nanowires doped with CdSO4 nanoparticles by arc discharge method. For this, two cadmium rods with high purity as anode and cathode electrodes were submerged in a liquid nitrogen medium. The cathode electrode was filled with micro-sized sulfur powder to synthesize CdS nanowires. CdS nanowires were obtained by oxidation using low temperature with CdSO4 nanoparticles. After the arc discharge process, the resultant product was characterized to reveal structural and morphological properties. XRD and electron EDX analyses exposed the coexistence of the CdS and CdSO4 phases. Scanning electron microscopy (SEM) investigations revealed that the synthesized nanostructures formed in a 1D wire nanostructure morphology with a diameter of less than 10 nm and several micrometers in length. Besides, the transmission electron microscopy (TEM) analysis was utilized to monitor the CdSO4 nanoparticles located on CdS nanowires surface. It has been found that the absorption band blue-shifted with 0.53 eV. This blue shift originated from the quantum confinement in the nanoparticles.

Kaynakça

  • S. Yuvaraj, A. C. Fernandez, M. Sundararajan, C. S. Dash, and P. Sakthivel, Hydrothermal synthesis of ZnO–CdS nanocomposites: Structural, optical and electrical behavior. Ceram. Int., 46(1), 391–402, 2020. https://doi.org/10.1016/j.ceramint.2019.08.274.
  • A. Pan et al., Stimulated emissions in aligned CdS nanowires at room temperature. J. Phys. Chem. B, 109(51), 24268–24272, 2005. https://doi.org/10.1021/ jp055164m.
  • M. Salavati-Niasari, F. Davar, and M. R. Loghman-Estarki, Long chain polymer assisted synthesis of flower-like cadmium sulfide nanorods via hydrothermal process. J. Alloys Compd., 481(2), 776–780, 2009. https://doi.org/10.1016/j.jallcom.2009.03. 086.
  • R. Agarwal, C. J. Barrelet, and C. M. Lieber, Lasing in single cadmium sulfide nanowire optical cavities. Nano Lett., 5(5), 917–920, 2005. https://doi.org/10.1021/ nl050440u.
  • G. Nagaraju, S. Ashoka, C. N. Tharamani, and G. T. Chandrappa, A facile low temperature hydrothermal route to CdSO4 nanotubes/rods. Mater. Lett., 63(3), 492–495, 2009. https://doi.org/10.1016/j.matlet.2008. 11.032.
  • T. Üstün, V. Eskizeybek, and A. Avcı, Selectively Nanocube Formation of Tungsten Oxide (WO 3 ). Celal Bayar Univ. J. Sci., 16(2), 149–153, 2020. https://doi.org/10.18466/cbayarfbe.677407
  • T. Üstün, V. Eskizeybek, and A. Avcı, CuO Nanoparçacıkların Kolay ve Amorf Yapıda Sentezi. Konya J. Eng. Sci., 7(4), 696–704, 2019. https://doi.org/10.36306/konjes.654449.
  • Z. Li, F. Davar, J. Chen, Z. Li, and X. Fang, CdS/CdSO4 nanoflower-based photodetector with enhanced photoelectric performances. ACS Applied Nano Materials, 3(10), 10190-10199, 2020. https://doi.org/10.1021/acsanm.0c02166.
  • V. Eskizeybek, A. Avcı, and M. Chhowalla, Structural and optical properties of CdO nanowires synthesized from Cd(OH)2 precursors by calcination. Cryst. Res. Technol., 46(10), 1093–1100, 2011. https://doi.org/10.1002/crat.201100221.
  • V. Eskizeybek, O. Demir, A. Avci, and M. Chhowalla, Synthesis and characterization of cadmium hydroxide nanowires by arc discharge method in de-ionized water. J. Nanoparticle Res., 13(10), 4673–4680, 2011. https://doi.org/10.1007/s11051-011-0430-z.
  • V. Eskizeybek, E. S. Karabulut, and A. Avci, Synthesis of carbon nanostructures and CaCO3 nanoparticles by arc discharge in mineral water. J. Nano Res., 15, 57–67, 2011. https://doi.org/10.4028/www.scientific.net/ JNanoR.15.57.
  • T. Charinpanitkul, N. Sano, P. Muthakarn, and W. Tanthapanichakoon, Enhancing effect of monoolein surfactant on carbon nanoparticle synthesis by arc discharge in liquid. Mater. Res. Bull., 44(2), 324–327, 2009. https://doi.org/10.1016/j.materresbull.2008.05.017.
  • N. Sano et al., Properties of carbon onions produced by an arc discharge in water. J. Appl. Phys., 92(5), 2783–2788, 2002. https://doi.org/10.1063/1.1498884.
  • M. Ye, H. Zhong, W. Zheng, R. Li, and Y. Li, Ultralong cadmium hydroxide nanowires: Synthesis, characterization, and transformation into CdO nanostrands. Langmuir, 23(17), 9064–9068, 2007. https://doi.org/10.1021/la070111c.
  • D. F. Zhang, L. D. Sun, J. L. Yin, and C. H. Yan, Low-temperature fabrication of highly crystalline SnO2 nanorods. Adv. Mater., 15(12), 1022–1025, 2003. https://doi.org/10.1002/adma.200304899.
  • D. Redfield and W. J. Burke, Optical absorption edge of LiNbO3. J. Appl. Phys., 45(10), 4566–4571, 1974. https://doi.org/10.1063/1.1663089.
  • R. Venugopal, P. I. Lin, C. C. Liu, and Y. T. Chen, Surface-enhanced Raman scattering and polarized photoluminescence from catalytically grown CdSe nanobelts and sheets. J. Am. Chem. Soc., 127(32), 11262–11268, 2005. https://doi.org/10.1021/ja044270j.
  • S. Yılmaz, İ. Polat, M. A. Olgar, M. Tomakin, S. B. Töreli, and E. Bacaksız, Physical properties of CdS: Ga thin films synthesized by spray pyrolysis technique. Journal of Materials Science: Materials in Electronics, 28(4), 3191-3199, 2017.
  • R. Banerjee, R. Jayakrishnan, and P. Ayyub, Effect of the size-induced structural transformation on the band gap in CdS nanoparticles. Journal of Physics: Condensed Matter, 12(50), 10647, 2000.

CdSO4-CdS Kompozit nanotellerin ark deşarj yöntemi ile sentezi

Yıl 2022, Cilt: 11 Sayı: 3, 813 - 818, 18.07.2022
https://doi.org/10.28948/ngumuh.820329

Öz

Bu çalışmada, CdSO4 nanopartikülleri ile doplanmış CdS nanotellerinin sentezini ark deşarj yöntemi ile başarıyla gerçekleştirdik. Bunun için anot ve katot elektrotlar olarak yüksek saflıkta iki kadmiyum çubuk sıvı nitrojen ortamına daldırıldı. Katot elektrotu, CdS nanotellerini sentezlemek için mikro boyutlu kükürt tozu ile doldurulmuştur. CdS nanotelleri düşük sıcaklıkta oksitleme işlemi ile CdSO4 nanoparçacıkları da elde edildi. Ark deşarj işleminden sonra, elde edilen ürün yapısal ve morfolojik özellikleri ortaya çıkarmak için karakterize edildi. X-Işını Kırınımı (XRD) ve elektron dağılımı spektroskopi (EDS) analizleri, CdS ve CdSO4 fazlarının bir arada varlığını açıkça ortaya koymuştur. Taramalı elektron mikroskobu (SEM) incelemeleri, sentezlenmiş nanoyapıların 10 nm'den küçük bir çapa ve birkaç mikrometre uzunluğa sahip bir 1B tel nanoyapı morfolojisinde oluştuğunu ortaya çıkardı. Ayrıca, geçirimli elektron mikroskobu (TEM) analizi, CdS nanotellerinin yüzeyinde bulunan CdSO4 nanopartiküllerini izlemek için kullanıldı. Absorpsiyon bandının maviye kaydığı 0.53 eV ile bulunmuştur. Bu maviye kayma, nanopartiküllerdeki kuantum sınırlamasından kaynaklandı.

Kaynakça

  • S. Yuvaraj, A. C. Fernandez, M. Sundararajan, C. S. Dash, and P. Sakthivel, Hydrothermal synthesis of ZnO–CdS nanocomposites: Structural, optical and electrical behavior. Ceram. Int., 46(1), 391–402, 2020. https://doi.org/10.1016/j.ceramint.2019.08.274.
  • A. Pan et al., Stimulated emissions in aligned CdS nanowires at room temperature. J. Phys. Chem. B, 109(51), 24268–24272, 2005. https://doi.org/10.1021/ jp055164m.
  • M. Salavati-Niasari, F. Davar, and M. R. Loghman-Estarki, Long chain polymer assisted synthesis of flower-like cadmium sulfide nanorods via hydrothermal process. J. Alloys Compd., 481(2), 776–780, 2009. https://doi.org/10.1016/j.jallcom.2009.03. 086.
  • R. Agarwal, C. J. Barrelet, and C. M. Lieber, Lasing in single cadmium sulfide nanowire optical cavities. Nano Lett., 5(5), 917–920, 2005. https://doi.org/10.1021/ nl050440u.
  • G. Nagaraju, S. Ashoka, C. N. Tharamani, and G. T. Chandrappa, A facile low temperature hydrothermal route to CdSO4 nanotubes/rods. Mater. Lett., 63(3), 492–495, 2009. https://doi.org/10.1016/j.matlet.2008. 11.032.
  • T. Üstün, V. Eskizeybek, and A. Avcı, Selectively Nanocube Formation of Tungsten Oxide (WO 3 ). Celal Bayar Univ. J. Sci., 16(2), 149–153, 2020. https://doi.org/10.18466/cbayarfbe.677407
  • T. Üstün, V. Eskizeybek, and A. Avcı, CuO Nanoparçacıkların Kolay ve Amorf Yapıda Sentezi. Konya J. Eng. Sci., 7(4), 696–704, 2019. https://doi.org/10.36306/konjes.654449.
  • Z. Li, F. Davar, J. Chen, Z. Li, and X. Fang, CdS/CdSO4 nanoflower-based photodetector with enhanced photoelectric performances. ACS Applied Nano Materials, 3(10), 10190-10199, 2020. https://doi.org/10.1021/acsanm.0c02166.
  • V. Eskizeybek, A. Avcı, and M. Chhowalla, Structural and optical properties of CdO nanowires synthesized from Cd(OH)2 precursors by calcination. Cryst. Res. Technol., 46(10), 1093–1100, 2011. https://doi.org/10.1002/crat.201100221.
  • V. Eskizeybek, O. Demir, A. Avci, and M. Chhowalla, Synthesis and characterization of cadmium hydroxide nanowires by arc discharge method in de-ionized water. J. Nanoparticle Res., 13(10), 4673–4680, 2011. https://doi.org/10.1007/s11051-011-0430-z.
  • V. Eskizeybek, E. S. Karabulut, and A. Avci, Synthesis of carbon nanostructures and CaCO3 nanoparticles by arc discharge in mineral water. J. Nano Res., 15, 57–67, 2011. https://doi.org/10.4028/www.scientific.net/ JNanoR.15.57.
  • T. Charinpanitkul, N. Sano, P. Muthakarn, and W. Tanthapanichakoon, Enhancing effect of monoolein surfactant on carbon nanoparticle synthesis by arc discharge in liquid. Mater. Res. Bull., 44(2), 324–327, 2009. https://doi.org/10.1016/j.materresbull.2008.05.017.
  • N. Sano et al., Properties of carbon onions produced by an arc discharge in water. J. Appl. Phys., 92(5), 2783–2788, 2002. https://doi.org/10.1063/1.1498884.
  • M. Ye, H. Zhong, W. Zheng, R. Li, and Y. Li, Ultralong cadmium hydroxide nanowires: Synthesis, characterization, and transformation into CdO nanostrands. Langmuir, 23(17), 9064–9068, 2007. https://doi.org/10.1021/la070111c.
  • D. F. Zhang, L. D. Sun, J. L. Yin, and C. H. Yan, Low-temperature fabrication of highly crystalline SnO2 nanorods. Adv. Mater., 15(12), 1022–1025, 2003. https://doi.org/10.1002/adma.200304899.
  • D. Redfield and W. J. Burke, Optical absorption edge of LiNbO3. J. Appl. Phys., 45(10), 4566–4571, 1974. https://doi.org/10.1063/1.1663089.
  • R. Venugopal, P. I. Lin, C. C. Liu, and Y. T. Chen, Surface-enhanced Raman scattering and polarized photoluminescence from catalytically grown CdSe nanobelts and sheets. J. Am. Chem. Soc., 127(32), 11262–11268, 2005. https://doi.org/10.1021/ja044270j.
  • S. Yılmaz, İ. Polat, M. A. Olgar, M. Tomakin, S. B. Töreli, and E. Bacaksız, Physical properties of CdS: Ga thin films synthesized by spray pyrolysis technique. Journal of Materials Science: Materials in Electronics, 28(4), 3191-3199, 2017.
  • R. Banerjee, R. Jayakrishnan, and P. Ayyub, Effect of the size-induced structural transformation on the band gap in CdS nanoparticles. Journal of Physics: Condensed Matter, 12(50), 10647, 2000.
Toplam 19 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Makine Mühendisliği, Malzeme Üretim Teknolojileri
Bölüm Makine Mühendisliği
Yazarlar

Tugay Üstün 0000-0001-5365-3054

Volkan Eskizeybek 0000-0002-5373-0379

Omar Toumıat Bu kişi benim 0000-0003-4623-346X

Ahmet Avcı Bu kişi benim 0000-0003-3434-1711

Yayımlanma Tarihi 18 Temmuz 2022
Gönderilme Tarihi 3 Kasım 2020
Kabul Tarihi 17 Mayıs 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 11 Sayı: 3

Kaynak Göster

APA Üstün, T., Eskizeybek, V., Toumıat, O., Avcı, A. (2022). CdSO4-CdS Composite nanowires synthesized by arc discharge method. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 11(3), 813-818. https://doi.org/10.28948/ngumuh.820329
AMA Üstün T, Eskizeybek V, Toumıat O, Avcı A. CdSO4-CdS Composite nanowires synthesized by arc discharge method. NÖHÜ Müh. Bilim. Derg. Temmuz 2022;11(3):813-818. doi:10.28948/ngumuh.820329
Chicago Üstün, Tugay, Volkan Eskizeybek, Omar Toumıat, ve Ahmet Avcı. “CdSO4-CdS Composite Nanowires Synthesized by Arc Discharge Method”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11, sy. 3 (Temmuz 2022): 813-18. https://doi.org/10.28948/ngumuh.820329.
EndNote Üstün T, Eskizeybek V, Toumıat O, Avcı A (01 Temmuz 2022) CdSO4-CdS Composite nanowires synthesized by arc discharge method. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11 3 813–818.
IEEE T. Üstün, V. Eskizeybek, O. Toumıat, ve A. Avcı, “CdSO4-CdS Composite nanowires synthesized by arc discharge method”, NÖHÜ Müh. Bilim. Derg., c. 11, sy. 3, ss. 813–818, 2022, doi: 10.28948/ngumuh.820329.
ISNAD Üstün, Tugay vd. “CdSO4-CdS Composite Nanowires Synthesized by Arc Discharge Method”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11/3 (Temmuz 2022), 813-818. https://doi.org/10.28948/ngumuh.820329.
JAMA Üstün T, Eskizeybek V, Toumıat O, Avcı A. CdSO4-CdS Composite nanowires synthesized by arc discharge method. NÖHÜ Müh. Bilim. Derg. 2022;11:813–818.
MLA Üstün, Tugay vd. “CdSO4-CdS Composite Nanowires Synthesized by Arc Discharge Method”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, c. 11, sy. 3, 2022, ss. 813-8, doi:10.28948/ngumuh.820329.
Vancouver Üstün T, Eskizeybek V, Toumıat O, Avcı A. CdSO4-CdS Composite nanowires synthesized by arc discharge method. NÖHÜ Müh. Bilim. Derg. 2022;11(3):813-8.

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