CuII-N,N’-bis(salisiliden)-2-aminobenzilaminin) kompleksinin Poli (pirol-ko-o-anisidin) kompozit filmlerinin yüzeyine immobilizasyonu ve hidrojen peroksit tayini
Öz
Bu çalışmada, CuII-(N,N’-bis(salisiliden)-2-aminobenzilaminin) (CuL) kompleksinin pol(pirol-ko-o-anisidin)/kitosan kompozit (Kz) filmlerinin yüzeyine immobilizasyon işlemi 0,15 M asetonitril-LiClO4 çözeltisinde 0,2-2,0 V arasında dönüşümlü voltametri tekniği ile gerçekleştirilmiştir. Schiff bazı metal kompleksinin farklı monomer mol oranlarındaki çözeltilerde platin elektrota kaplanan kompozit filmlerin yüzeyine immobilizasyon işleminin gerçekleştiği SEM görüntüleri ile belirlenmiştir. Schiff bazı metal komplekslerinin kompozit filmlerin yüzeyine tutunduğu SEM görüntülerinde ortaya çıkan Schiff bazı metal komplekslerinin karakteristik şekilleri olan çiçek ve çubuk şeklindeki yapıların varlığından açık bir şekilde kanıtlanmıştır. Bunun yanında elektrokimyasal kararlılık çalışmaları kompozit filmlerinin immobilizasyon işlemi gerçekleştikten sonra herhangi bir bozulmaya uğramadığını ve oldukça elektroaktif olduklarını göstermiştir. Yapılan elektroanalitik çalışmalar sonucunda peroksit tayini için en iyi elektrotun Schiff bazı metal kompleksi tutturulmuş 9:1 oranındaki modifiye elektrot olduğu bu elektrotun uygulamada alternatif olabileceği belirlenmiştir.
Anahtar Kelimeler
Destekleyen Kurum
Türkiye Bilimsel ve Teknoloji Araştırma Kurumu (TÜBİTAK)
Proje Numarası
112T523
Teşekkür
6 Şubat 2023 Kahramanmaraş depreminde vefat eden makalenin ikinci yazarı çok iyi bir bilim insanı ve bir anne olan değerli çalışma arkadaşım ve kıymetli dostum Doç. Dr. Didem ÇAKMAK’ a sonsuz teşekkürlerimi sunuyorum. Kendisini kaybetmiş olmanın derin üzüntüsü içinde birlikte paylaştığım anılarla sonsuza kadar yaşatarak, bu makaleyi ona atfediyorum. Çalışmanın finansal desteğini sağlayan Türkiye Bilimsel ve Teknoloji Araştırma Kurumu’na (TÜBİTAK) teşekkür ederim (proje No : 112T523). Bu çalışmada Schiff bazı metal kompleksini hazırlayıp kullanımımıza sunan Prof. Dr. Cahit DEMETGÜL’ e (HMKÜ Kimya Bölümü) teşekkürlerimi sunarım.
Kaynakça
- Adhikari B., Majumdar S. Polymers in sensor application. Progress in Polymer Science 2004; 29(7): 699-766.
- Amiri M., Pakdel Z., Bezaatpour A., Shahrokhian S. Electrocatalytic determination of sumatriptan on thesurface of carbon-paste electrode modified with a composite of cobalt/Schiff-base complex and carbon nanotube. Bioelectrochemistry 2011; 81(2): 81-85.
- Azak H., Yildiz HB., Carbas BB. Synthesis and characterization of a new poly (dithieno (3, 2-b: 2′, 3′-d) pyrrole) derivative conjugated polymer: Its electrochromic and biosensing applications. Polymer 2018; 134: 44-52.
- Baghayeri M., Zare EN., Hasanzadeh R. Facile synyhesis of PSMA-g-3 ABA/MWCNTs nanocomposite as a substrate for hemoglabin immobilization: Application to catalysis of H2O2. Materials Science and Engineering 2014; 39: 213-220.
- Balint R., Cassidy NJ., Cartmell SH. Conductive polymers: towards a smart biomaterial fort issue engineering. Actabiomaterialia 2014; 10(6): 2341-2353.
- Beaujuge PM., Reynolds JR. Color control in π-conjugated organic polymers for use in electrochromic devices. Chemical Reviews 2010; 110(1): 268-320.
- Cansu-Ergun EG. Covering the more visible region by electrochemical copolymerization of carbazole and benzothiadiazole based donor-acceptor type monomers. Chinese Journal of Polymer Science 2019; 37: 28-35.
- Carbas BB., Ergun EGC. A classified and comparative review of Poly (2, 5-dithienyl-N-substituted-pyrrole) derivatives for electrochromic applications. European Polymer Journal 2022; 175: 111363.
- Chen C., Sun C., Gao Y. Application of electrosynthesized poly(aniline-co-p-aminophenol) as a catecol sensor. Electrochemica Acta 2009; 54(9): 2575-2580.
- Çakal D., Cihaner A., Önal AM. Synthesis and electropolymerization of donor-acceptor-donor type monomers based on azobenzene-substituted thieno [3, 4-c] pyrrole-4, 6-dione acceptors. Electrochimica Acta 2021; 398: 139325.
- Cevik E., Carbas BB., Senel M., Yildiz HB. Construction of conducting polymer/cytochrome C/thylakoid membrane based photo-bioelectrochemical fuel cells generating high photocurrent via photosynthesis. Biosensors and Bioelectronics 2018a; 113: 25-31.
- Cevik E., Cerit A., Gazel N., Yildiz HB. Construction of an amperometric cholesterol biosensor based on DTP (aryl) aniline conducting polymer bound cholesterol oxidase. Electroanalysis 2018b; 30 (10): 2445-2453.
- Dervisevic M., Dervisevic E., Azak H., Çevik E., Şenel M., Yildiz HB. Novel amperometric xanthine biosensor based on xanthine oxidase immobilized on electrochemically polymerized 10-[4H-dithieno (3, 2-b: 2′, 3′-d) pyrrole-4-yl] decane-1-amine film. Sensors and Actuators B: Chemical 2016; 225: 181-187.
- Ekanayeke Mala EMI., Preethichandra DMG., Kaneto K. Bi-functional amperometric biosensor for low concentration hydrojen peroxide measurements using polypyrrole immobilizing matrix. Sensors and Actuators 2008; 132(1): 166-171.
- Hu DD., Sh QZ., Tang ZX., Fang Y., Kennedy JF. Co Salen immobilized on chitosan and its electrochemical behavior. Carbonhydrate Polymers 2001; 45(4): 385-393.
- Karthikeyan M., Satheesh Kumar KK., Elango KP. Batch sorption studies on theremoval of fluoride ions from water using eco-friendly conducting polymer/bio-polymer composites. Desalination 2011; 267(1): 49-56.
- Komathi S., Gopalan AI., Kim SK., Anand GS. Fabrication of horse radish peroxidase immobilized poly(N-[3-(trimethoxysilyl)propyl]aniline) gold nano rods film modified electrode and electrochemical hydrojen peroxide sensing. Electrochemica Acta 2013; 92(1): 71-78.
- Rong Li X., Liu J., Kong F., Liu X., Xu J. Chen H. Potassium-doped graphene for simultaneus determination of nitrite and sülfite in pulluted water. Electrochemistry Communications 2012; 20(1): 109-112.
Immobilization of CuII-(N,N'-bis(salicylidene)-2-aminobenzylamine) complex on the surface of Poly (pyrrole-co-o-anisidine) composite films and hydrogen peroxide determination
Öz
In this study, the immobilization of Cu II (N,N'-bis(salicylidene)-2-aminobenzylamine) (CuL) on the surface of poly(pyrrole-co-o-anisidine)/chitosan composite (Cs) films was carried out in a 0.15 M acetonitrile-LiClO4 solution between 0.2-2.0 V by cyclic voltammetry technique. It was determined by SEM images that the Schiff base metal complex was immobilized on the surface of the composite films coated on the platinum electrode in solutions with different monomer mole ratios. The presence of flower and rod-shaped structures, which are the characteristic shapes of Schiff base metal complexes, revealed in SEM images that Schiff base metal complexes are attached to the surface of composite films. In Addition, electrochemical stability studies have shown that composite films have not any degradation after immobilization and are quite electroactive. As a result of the electroanalytical studies, it was determined that the best electrode for the determination of peroxide was the modified electrode with a ratio of 9:1 attached to the Schiff base metal complex, and this electrode could be an alternative in application.
Anahtar Kelimeler
Pyrrole o-anisidine chitosan composite electrochemical synthesis
Proje Numarası
112T523
Kaynakça
- Adhikari B., Majumdar S. Polymers in sensor application. Progress in Polymer Science 2004; 29(7): 699-766.
- Amiri M., Pakdel Z., Bezaatpour A., Shahrokhian S. Electrocatalytic determination of sumatriptan on thesurface of carbon-paste electrode modified with a composite of cobalt/Schiff-base complex and carbon nanotube. Bioelectrochemistry 2011; 81(2): 81-85.
- Azak H., Yildiz HB., Carbas BB. Synthesis and characterization of a new poly (dithieno (3, 2-b: 2′, 3′-d) pyrrole) derivative conjugated polymer: Its electrochromic and biosensing applications. Polymer 2018; 134: 44-52.
- Baghayeri M., Zare EN., Hasanzadeh R. Facile synyhesis of PSMA-g-3 ABA/MWCNTs nanocomposite as a substrate for hemoglabin immobilization: Application to catalysis of H2O2. Materials Science and Engineering 2014; 39: 213-220.
- Balint R., Cassidy NJ., Cartmell SH. Conductive polymers: towards a smart biomaterial fort issue engineering. Actabiomaterialia 2014; 10(6): 2341-2353.
- Beaujuge PM., Reynolds JR. Color control in π-conjugated organic polymers for use in electrochromic devices. Chemical Reviews 2010; 110(1): 268-320.
- Cansu-Ergun EG. Covering the more visible region by electrochemical copolymerization of carbazole and benzothiadiazole based donor-acceptor type monomers. Chinese Journal of Polymer Science 2019; 37: 28-35.
- Carbas BB., Ergun EGC. A classified and comparative review of Poly (2, 5-dithienyl-N-substituted-pyrrole) derivatives for electrochromic applications. European Polymer Journal 2022; 175: 111363.
- Chen C., Sun C., Gao Y. Application of electrosynthesized poly(aniline-co-p-aminophenol) as a catecol sensor. Electrochemica Acta 2009; 54(9): 2575-2580.
- Çakal D., Cihaner A., Önal AM. Synthesis and electropolymerization of donor-acceptor-donor type monomers based on azobenzene-substituted thieno [3, 4-c] pyrrole-4, 6-dione acceptors. Electrochimica Acta 2021; 398: 139325.
- Cevik E., Carbas BB., Senel M., Yildiz HB. Construction of conducting polymer/cytochrome C/thylakoid membrane based photo-bioelectrochemical fuel cells generating high photocurrent via photosynthesis. Biosensors and Bioelectronics 2018a; 113: 25-31.
- Cevik E., Cerit A., Gazel N., Yildiz HB. Construction of an amperometric cholesterol biosensor based on DTP (aryl) aniline conducting polymer bound cholesterol oxidase. Electroanalysis 2018b; 30 (10): 2445-2453.
- Dervisevic M., Dervisevic E., Azak H., Çevik E., Şenel M., Yildiz HB. Novel amperometric xanthine biosensor based on xanthine oxidase immobilized on electrochemically polymerized 10-[4H-dithieno (3, 2-b: 2′, 3′-d) pyrrole-4-yl] decane-1-amine film. Sensors and Actuators B: Chemical 2016; 225: 181-187.
- Ekanayeke Mala EMI., Preethichandra DMG., Kaneto K. Bi-functional amperometric biosensor for low concentration hydrojen peroxide measurements using polypyrrole immobilizing matrix. Sensors and Actuators 2008; 132(1): 166-171.
- Hu DD., Sh QZ., Tang ZX., Fang Y., Kennedy JF. Co Salen immobilized on chitosan and its electrochemical behavior. Carbonhydrate Polymers 2001; 45(4): 385-393.
- Karthikeyan M., Satheesh Kumar KK., Elango KP. Batch sorption studies on theremoval of fluoride ions from water using eco-friendly conducting polymer/bio-polymer composites. Desalination 2011; 267(1): 49-56.
- Komathi S., Gopalan AI., Kim SK., Anand GS. Fabrication of horse radish peroxidase immobilized poly(N-[3-(trimethoxysilyl)propyl]aniline) gold nano rods film modified electrode and electrochemical hydrojen peroxide sensing. Electrochemica Acta 2013; 92(1): 71-78.
- Rong Li X., Liu J., Kong F., Liu X., Xu J. Chen H. Potassium-doped graphene for simultaneus determination of nitrite and sülfite in pulluted water. Electrochemistry Communications 2012; 20(1): 109-112.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Konular | Elektroanalitik Kimya |
| Bölüm | Araştırma Makaleleri (RESEARCH ARTICLES) |
| Yazarlar | |
| Proje Numarası | 112T523 |
| Yayımlanma Tarihi | 20 Aralık 2023 |
| Gönderilme Tarihi | 10 Haziran 2023 |
| Kabul Tarihi | 15 Eylül 2023 |
| Yayımlandığı Sayı | Yıl 2023 Cilt: 6 Sayı: Ek Sayı |
Kaynak Göster
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