Research Article

DEVELOPMENT OF ZIF-8 LOADED PVA HYBRID MEMBRANES FOR THE DESALINATION OF SEAWATER BY PERVAPORATION

Volume: 25 Number: 4 December 3, 2022
  • Zeynep Sığın
  • Gözdenur Güvenç
  • Nagihan Çakmakçı
  • Derya Ünlü *
EN TR

DEVELOPMENT OF ZIF-8 LOADED PVA HYBRID MEMBRANES FOR THE DESALINATION OF SEAWATER BY PERVAPORATION

Abstract

In this study, ZIF-8 zeolitic imidazolate framework was synthesized and added to the polyvinyl alcohol (PVA) membrane for the manufacture of hybrid membranes to use in pervaporative desalination. The hybrid membranes were characterized by using FTIR, SEM and contact angle. The effects of ZIF-8 loading ratio, feed NaCl concentration, and operation temperature on separation perfomance were investigated. The addition of ZIF-8 to the improved the hydrophilicity and purification performance of membrane. The optimal loading ratios ZIF-8 were specified as 0.25 wt%. Optimum operation parameters were found as 60oC of temperature and a 2 wt% of feed NaCl concentration. Pervaporative desalination tests of seawater were carried out under the optimum operation conditions and rejection performance of >99.99% were achieved. The obtained data are observed under the drinking water standart values of World Health Organization. Hybrid membranes which are exhibited rather successful separation performance, are candidate structure for the usage of desalination process.

Keywords

Supporting Institution

Bursa Teknik Üniversitesi Bilimsel Araştırma Projeleri Birimi

Project Number

220Y022

Thanks

Bu çalışma Bursa Teknik Üniversitesi Bilimsel Araştırma Projeleri birimi tarafından 220Y022 numaralı proje kapsamında desteklenmiştir.

References

  1. Ahmad, A. L., Abdulkarim, A. A., Ismail, S., & Ooi, B. S. (2014). Preparation and characterisation of PES-ZnO mixed matrix membranes for humic acid removal. Desalination and Water Treatment, 54(12), 3257–3268.
  2. Basile, A., Figoli, A., & Khayet, M. (2015). Pervaporation, Vapour Permeation and Membrane Distillation: Principles and Applications (1st ed.). UK:Woodhead Publishing.
  3. Binaeian, E., Maleki, S., Motaghedi, N., & Arjmandi, M. (2019). Study on the performance of Cd2+ sorption using dimethylethylenediamine-modified zinc-based MOF (ZIF-8-mmen): optimization of the process by RSM technique. Separation Science and Technology, 55(15), 2713–2728.
  4. Dehkordi, F.S., Pakizeh, M., & Namvar-Mahboub, M. (2015). Properties and ultrafiltration efficiency of cellulose acetate/organically modified Mt (CA/OMMt) nanocomposite membrane for humic acid removal. Applied Clay Science, 105-106, 178-185.
  5. Drioli, E., Stankiewicz, A.I., & Macedonio, F. (2011). Membrane engineering in process intensification an overview. Journal of Membrane Science, 380, 1-8.
  6. Duke, M. C., Zhu, B., Doherty, C. M., Hill, M. R., Hill, A. J., & Carreon, M. A. (2016). Structural effects on SAPO-34 and ZIF-8 materials exposed to seawater solutions, and their potential as desalination membranes. Desalination, 377, 128–137.
  7. Gündağ Ö. (2017). İçme Sularında Humik Asit Giderim Verimlerinin İncelenmesi.Yüksek Lisans Tezi. Namik Kemal Üniversitesi Fen Bilimleri Enstitüsü Çevre Mühendisliği Anabilim Dalı, Tekirdağ 80s.
  8. He, X., Wang, T., Huang, J., Chen, J., & Li, J. (2020). Fabrication and characterization of superhydrophobic PDMS composite membranes for efficient ethanol recovery via pervaporation. Separation and Purification Technology, 241, 116675.

Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Zeynep Sığın
0000-0001-7943-1919
Türkiye

Gözdenur Güvenç
0000-0002-1793-2029
Türkiye

Nagihan Çakmakçı
0000-0002-2464-9184
Türkiye

Publication Date

December 3, 2022

Submission Date

August 16, 2022

Acceptance Date

September 6, 2022

Published in Issue

Year 1970 Volume: 25 Number: 4

APA
Sığın, Z., Güvenç, G., Çakmakçı, N., & Ünlü, D. (2022). DENİZ SUYUNUN PERVAPORASYON İLE DESALİNASYONU İÇİN ZIF-8 YÜKLÜ PVA HİBRİT MEMBRANLARIN GELİŞTİRİLMESİ. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 25(4), 733-745. https://doi.org/10.17780/ksujes.1163098