EN
TR
INVESTIGATION OF THE EFFECT OF LIGNIN ADITION ON THE PROPERTIES OF GLASS FIBER REINFORCED POLYAMIDE 6/POLYAMIDE 610 COMPOSITES
Abstract
In this study, PA6 and PA610 were blended and glass fiber (GF) and lignin (LL) were added to improve the properties. Composites were prepared by extrusion and injection molding and morphological, thermal (differential scanning calorimetry-DSC, thermogravimetric analysis-TGA) and flame retardancy (limiting oxygen index-LOI, vertical burning test-UL-94, cone calorimetry) properties were examined. While a good interfacial interaction and homogeneous dispersion were observed in the GF reinforced composite, the interaction of LL with the matrix was found to be weak. GF, improved the thermal stability of the matrix and increased the char residue. In GF/LL composites, although LL decreased the thermal resistance, it slowed down the mass loss and increased the char residue. While there was no significant change in the melting point of the matrix with the addition of GF and LL, LL reduced the crystallization temperature and therefore greatly reduced the crystallinity of the matrix. LOI and UL94 classification of the matrix did not change by adding GF. But LL significantly shortened the burning time. GF and LL improved the flame retardancy of the matrix by significantly reducing the total heat release and peak heat release rate values. In conclusion, this study showed that lignin is a promising flame retardant for GF reinforced PA composites.
Keywords
Project Number
FYL-2021-2659
References
- Arboleda-Clemente, L., Ares-Pernas, A., García-Fonte, X. X., & Abad, M. J. (2016). Water sorption of PA12/PA6/MWCNT composites with a segregated conductive network: structure–property relationships. Journal of Materials Science, 51(18), 8674–8686. https://doi.org/10.1007/s10853-016-0127-x
- Artykbaeva, E., Ucpinar Durmaz, B., Aksoy, P., & Aytac, A. (2022). Investigation of the properties of PA6/PA610 blends and glass fiber reinforced PA6/PA610 composites. Polymer Composites, 43(10), 7514–7525. https://doi.org/10.1002/pc.26840
- Cayla, A., Rault, F., Giraud, S., Salaün, F., Sonnier, R., & Dumazert, L. (2019). Influence of ammonium polyphosphate/lignin ratio on thermal and fire behavior of biobased thermoplastic: The case of Polyamide 11. Materials, 12(7). https://doi.org/10.3390/ma12071146
- Chen, Y., Wang, Q., Yan, W., & Tang, H. (2006). Preparation of flame retardant polyamide 6 composite with melamine cyanurate nanoparticles in situ formed in extrusion process. Polymer Degradation and Stability, 91(11), 2632–2643. https://doi.org/10.1016/j.polymdegradstab.2006.05.002
- Fabbri, F., Bischof, S., Mayr, S., Gritsch, S., Jimenez Bartolome, M., Schwaiger, N., Guebitz, G.M., & Weiss, R. (2023). The Biomodified Lignin Platform: A Review. Polymers, 15(7). https://doi.org/10.3390/polym15071694
- Koruyucu, A., & Balaban, F. Ç. (2021). Muz kabuğu ekstraktının pamuk ve pamuk-poliester karışımlı kumaşlarda güç tutuşurluğa etkisinin incelenmesi. Kahramanmaras Sutcu Imam University Journal of Engineering Sciences, 24(2), 66–82.
- Mandlekar, N., Cayla, A., Rault, F., Giraud, S., Salaün, F., Malucelli, G., & Guan, J. (2017). Thermal Stability and Fire Retardant Properties of Polyamide 11 Microcomposites Containing Different Lignins. Industrial and Engineering Chemistry Research, 56(46), 13704–13714. https://doi.org/10.1021/acs.iecr.7b03085
- Marset, D., Dolza, C., Fages, E., Gonga, E., Gutiérrez, O., Gomez-Caturla, J., Ivorra-Martinez, J., Sanchez-Nacher, L., & Quiles-Carrillo, L. (2020). The effect of halloysite nanotubes on the fire retardancy properties of partially biobased polyamide 610. Polymers, 12(12), 1–21. https://doi.org/10.3390/polym12123050
Details
Primary Language
Turkish
Subjects
Polymer Science and Technologies , Composite and Hybrid Materials
Journal Section
Research Article
Publication Date
March 3, 2024
Submission Date
October 10, 2023
Acceptance Date
November 21, 2023
Published in Issue
Year 1970 Volume: 27 Number: 1
APA
Üçpınar Durmaz, B., Artykbaeva, E., & Aytac, A. (2024). LİGNİN İLAVESİNİN CAM ELYAF TAKVİYELİ POLİAMİD 6/POLİAMİD 610 KOMPOZİTLERİNİN ÖZELLİKLERİNE ETKİSİNİN İNCELENMESİ. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 27(1), 213-221. https://doi.org/10.17780/ksujes.1373989