SENTEZLENEN METAL OKSİT NANOKOMPOZİT YARDIMIYLA SUCUL ÇÖZELTİLERDEN REAKTİF AZO BOYA GİDERİMİ

İlknur Şentürk

doi:10.17780/ksujes.1403697

EN TR

REACTIVE AZO DYE REMOVAL FROM AQUATIC SOLUTIONS USING SYNTHESIZED METAL OXIDE NANOCOMPOSITE

Abstract

This work investigates the possibility of utilizing Fe3O4@ZnO@TiO2 as magnetic nanocomposite materials for the adsorption of reactive orange 16 dye (RO 16) through batch adsorption processing. A batch system was used to investigate the effects of adsorbent dosage, contact time, dye initial concentration, and temperature on the removal performance of RO 16. SEM and EDS analyses were performed for surface properties and elemental analysis of the synthesized Fe3O4@ZnO@TiO2 nanocomposite. The equilibrium isotherm data were best correlated using the Langmuir model with a maximum adsorption capacity of 38.61 mg/g at 40◦C. The pseudo-second-order model well represented the adsorption kinetics and followed chemisorption. The prepared Fe3O4@ZnO@TiO2 is an effective adsorbent candidate for the removal of reactive dyes from wastewater.

Keywords

SENTEZLENEN METAL OKSİT NANOKOMPOZİT YARDIMIYLA SUCUL ÇÖZELTİLERDEN REAKTİF AZO BOYA GİDERİMİ

Öz

Bu çalışma, kesikli adsorpsiyon prosesi ile Reaktif Orange 16 boyasının (RO 16) adsorpsiyonu için manyetik nanokompozit materyal olarak Fe3O4@ZnO@TiO2'nin kullanılma olasılığını araştırmaktadır. Adsorban dozajının, temas süresinin, boya başlangıç konsantrasyonunun ve sıcaklığın RO 16 giderim performansı üzerindeki etkilerini araştırmak için kesikli adsorpsiyon sistemi kullanılmıştır. Sentezlenen Fe3O4@ZnO@TiO2 nanokompozitin yüzey özellikleri ve elementel analizi için SEM ve EDS analizleri yapılmıştır. Denge izoterm verileri, 40◦C'de 38,61 mg/g maksimum adsorpsiyon kapasitesi ile Langmuir modeli kullanılarak en iyi şekilde ilişkilendirilmiştir. Sözde ikinci dereceden model adsorpsiyon kinetiğini iyi bir şekilde temsil etmiş ve kemisorpsiyonu takip etmiştir. Hazırlanan Fe3O4@ZnO@TiO2, reaktif boyaların atık sulardan uzaklaştırılmasında kullanılabilecek etkili bir adsorbent adayıdır.

Anahtar Kelimeler

Ethical Statement

Çalışma için etik beyan iznine gerek yoktur.

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Details

Primary Language

Turkish

Subjects

Environmental Pollution and Prevention , Environmental Engineering (Other)

Journal Section

Research Article

Authors

İlknur Şentürk ^*
0000-0002-8217-2281
Türkiye

Publication Date

June 3, 2024

Submission Date

December 12, 2023

Acceptance Date

January 10, 2024

Published in Issue

Year 2024 Volume: 27 Number: 2

DOI

https://doi.org/10.17780/ksujes.1403697

IZ

https://izlik.org/JA34SP72LL

Cite

RIS / Bibtex

APA

Şentürk, İ. (2024). SENTEZLENEN METAL OKSİT NANOKOMPOZİT YARDIMIYLA SUCUL ÇÖZELTİLERDEN REAKTİF AZO BOYA GİDERİMİ. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 27(2), 523-538. https://doi.org/10.17780/ksujes.1403697

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