Piezoelektrik Malzemelerin Lityum İyon Batarya Anotlarında Katkı Olarak Kullanılması

M. Taha Demirkan; Mehbare Doğrusöz

doi:10.17780/ksujes.672828

Piezoelektrik Malzemelerin Lityum İyon Batarya Anotlarında Katkı Olarak Kullanılması

Öz

Özet Lityum iyon bataryalarında son günlerdeki en popüler malzeme olarak gösterilen silisyum (Si) içerikli malzemelerle ilgili önemli sorunlar, bunların ticari olarak yaygınlaşmasını engellemektedir. Si anot malzemelerinin şarj/deşarj esnasında yüksek hacim değişikliğine uğraması ve mekanik olarak dayanıksızlığı bu sorunların başında gelmektedir. Bu çalışmada PZT tabanlı piezoelektrik malzemelerin kullanılmasıyla bu sorunların çözümündeki katkısı üzerinde durulmuştur. Si ve karbon (C) karışımı anot malzemelerinde katkı olarak PZT parçacıkları kullanıldığında bu malzemelerin kapasite performansında artış olduğu görülmüştür. Bu artışın nedenleri tartışılmakla birlikte farklı türlerde PZT malzemeleri ile farklı oranlarda Si-C karışımları üzerine test yapılmış ve aralarındaki performans farkları incelenmiştir. PZT kullanımı olmadığı durumlarda ilk 50 çevrimde 50 mAh/g’in altında spesifik kapasite değerleri vererek bozulmaya uğrayan anot malzemelerinin, PZT katkısı kullanılmasıyla 100. çevrimde dahi 400 mAh/g üzerinde değerleri verdiği gözlemlenmiştir.

Anahtar Kelimeler

Silisyum Anot,Lityum İyon Batarya,Piezoelektrik

Supporting Institution

TÜBİTAK

Project Number

118M340

Thanks

Yazar bu çalışmadaki desteklerinden ve yardımlarından dolayı Doç. Dr. Rezan Demir-Çakan’a ve Prof. Dr. Hüseyin Yılmaz’a teşekkürlerini sunar

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

M. Taha Demirkan
0000-0002-5041-5680
Türkiye

Mehbare Doğrusöz ^*
0000-0002-3064-8081
Türkiye

Publication Date

December 3, 2021

Submission Date

January 9, 2020

Acceptance Date

October 12, 2021

Published in Issue

Year 2021 Volume: 24 Number: 4

DOI

https://doi.org/10.17780/ksujes.672828

IZ

https://izlik.org/JA75YH82ML

Cite

RIS / Bibtex

APA

Demirkan, M. T., & Doğrusöz, M. (2021). Piezoelektrik Malzemelerin Lityum İyon Batarya Anotlarında Katkı Olarak Kullanılması. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 24(4), 258-270. https://doi.org/10.17780/ksujes.672828