ATIK YUMURTA KABUKLARINDAN SENTEZLENEN HİDROKSİAPATİTLER İLE SULARDAN MALAHİT YEŞİL GİDERİMİ

Yağmur Uysal; Pınar Belibağlı

doi:10.17780/ksujes.753116

ATIK YUMURTA KABUKLARINDAN SENTEZLENEN HİDROKSİAPATİTLER İLE SULARDAN MALAHİT YEŞİL GİDERİMİ

Öz

Bu çalışmada atık yumurta kabuklarından hidroksiapatit (YKHAp) partikülleri adsorbent olarak sentezlenmiş ve Malahit Yeşili (MY) üzerine etkileri araştırılmıştır. Adsorpsiyon deneyleri Tepki Yüzey Yöntemi (RSM) kullanılarak tasarlanmış ve pH, YKHAp dozu, MY konsantrasyonu, temas süresi için optimum şartlar belirlenmiştir. YKHAp partiküllerinin karakterizasyonu için SEM-EDX ve FTIR analizleri yapılmıştır. Adsorpsiyonun hangi mekanizmaya uyumlu olduğunu belirlemek için izoterm ve kinetik hesaplamaları yapılmış ve elde edilen sonuçlarda YKHAp’ın MY adsorpsiyonunun Freundlich, Tempkin ve Scatchard izotermine ve adsorpsiyon kinetiğinin partikül içi difüzyon kinetik modeline uyduğu tespit edilmiştir. YKHAp ile MY gideriminde renk ölçümleri Pt-Co ve RES (436, 525, 620) değerlerine göre yapılmış ve değerlendirilmiştir Optimum koşullar altında (pH;6.0, YKHAp dozu; 0,75g/50 mL, 50 ppm MY konsantrasyonu) %93 oranında MY giderim verimi elde edilmiştir.

Anahtar Kelimeler

Adsorpsiyon,Hidroksiapatit,Malahit Yeşili,Renk,Yumurta Kabuğu

References

Abukhadra, M. R., Dardir, F. M., Shaban, M., Ahmed, E. A., & Soliman, M. F. (2018). Superior removal of Co2+, Cu2+ and Zn2+ contaminants from water utilizing spongy Ni/Fe carbonate–fluorapatite; preparation, application and mechanism. Ecotoxicology and environmental safety, 157, 358-368.
Apalangya, V., Rangari, V., Jeelani, S., Dankyi, E., Yaya, A., & Darko, S. (2018). Rapid microwave synthesis of needle-liked hydroxyapatite nanoparticles via template directing ball-milled spindle-shaped eggshell particles. Ceramics International, 44(6), 7165-7171.
Baglar, S., Erdem, U., Dogan, M., & Turkoz, M. (2018). Dentinal tubule occluding capability of nano‐hydroxyapatite; The in‐vitro evaluation. Microscopy research and technique, 81(8), 843-854.
Crini, G., Peindy, H. N., Gimbert, F., & Robert, C. (2007). Removal of CI Basic Green 4 (Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: Kinetic and equilibrium studies. Separation and Purification Technology, 53(1), 97-110.
Dawood, S., & Sen, T. (2014). Review on dye removal from its aqueous solution into alternative cost effective and non-conventional adsorbents. Journal of Chemical and Process Engineering, 1(104), 1-11.
Deng, J., Li, M., & Wang, Y. (2016). Biomass-derived carbon: synthesis and applications in energy storage and conversion. Green Chemistry, 18(18), 4824-4854.
Ecer, Ü. and Sahan, T. (2018). A response surface approach for optimization of Pb(II) biosorption conditions from aqueous environment with Polyporussquamosus fungi as a new biosorbent and kinetic, equilibrium and thermodynamic studies. Desalin. Water Treat.,102, 229-240.
El-Subruiti, G. M., Eltaweil, A. S., & Sallam, S. A. (2019). Synthesis of Active MFe2O4/γ-Fe2O3 Nanocomposites (Metal= Ni or Co) for Reduction of Nitro-Containing Pollutants and Methyl Orange Degradation. Nano, 14(10), 1950125.

Fihri, A., Len, C., Varma, R. S., & Solhy, A. (2017). Hydroxyapatite: A review of syntheses, structure and applications in heterogeneous catalysis. Coordination Chemistry Reviews, 347, 48-76.
Geng, J., Wu, H., Al-Enizi, A. M., Elzatahry, A. A., & Zheng, G. (2015). Freestanding eggshell membrane-based electrodes for high-performance supercapacitors and oxygen evolution reaction. Nanoscale, 7(34), 14378-14384.
Ibrahim, M., Labaki, M., Giraudon, J. M., & Lamonier, J. F. (2020). Hydroxyapatite, a multifunctional material for air, water and soil pollution control: A review. Journal of hazardous materials, 383, 121139.
Jalil, A. A., Triwahyono, S., Yaakob, M. R., Azmi, Z. Z. A., Sapawe, N., Kamarudin, N. H. N., ... & Hameed, B. H. (2012). Utilization of bivalve shell-treated Zea mays L.(maize) husk leaf as a low-cost biosorbent for enhanced adsorption of malachite green. Bioresource Technology, 120, 218-224.
Lee, Y. C., Kim, J. Y., & Shin, H. J. (2013). Removal of malachite green (MG) from aqueous solutions by adsorption, precipitation, and alkaline fading using talc. Separation Science and Technology, 48(7), 1093-1101.
Luo, J.Y., Feng, L.Y., Zhang, W., Li, H. Chen, X., Wang, D.B., Chen, Y.G. (2014). Improved production of short-chain fatty acids from waste activated sludge driven by carbohydrate addition in continuous-flow reactors: Influence of SRT and temperature, Appl. Energy, 113, 51–58.
Luo, J., Wu, L., Zhang, Q., Fang, F., Feng, Q., Xue, Z., ... & Cao, J. (2018). How do biocides that occur in waste activated sludge affect the resource recovery for short-chain fatty acids production. ACS Sustainable Chemistry & Engineering, 7(1), 1648-1657.
Martins, R. C., Domingues, E., Bosio, M., Quina, M. J., Gmurek, M., Quinta-Ferreira, R. M., & Gomes, J. (2019). Effect of Different Radiation Sources and Noble Metal Doped onto TiO2 for Contaminants of Emerging Concern Removal. Water, 11(5), 894.
Mehariya, S., Patel, A. K., Obulisamy, P. K., Punniyakotti, E., & Wong, J. W. (2018). Co-digestion of food waste and sewage sludge for methane production: Current status and perspective. Bioresource technology, 265, 519-531.
Pandi, K., & Viswanathan, N. (2014). Synthesis of alginate bioencapsulated nano-hydroxyapatite composite for selective fluoride sorption. Carbohydrate polymers, 112, 662-667.
Pandi, K., & Viswanathan, N. (2015). Enhanced defluoridation and facile separation of magnetic nano-hydroxyapatite/alginate composite. International journal of biological macromolecules, 80, 341-349.
Parra-Orobio, B. A., Donoso-Bravo, A., Ruiz-Sánchez, J. C., Valencia-Molina, K. J., & Torres-Lozada, P. (2018). Effect of inoculum on the anaerobic digestion of food waste accounting for the concentration of trace elements. Waste Management, 71, 342-349.
Pourjavadi, A., Doulabi, M., & Doroudian, M. (2014). Adsorption characteristics of malachite green dye onto novel kappa-carrageenan-g-polyacrylic acid/TiO2–NH2 hydrogel nanocomposite. Journal of the Iranian Chemical Society, 11(4), 1057-1065.
Rao, K. V. K. (1995). Inhibition of DNA synthesis in primary rat hepatocyte cultures by malachite green: a new liver tumor promoter. Toxicology letters, 81(2-3), 107-113.
Saha, P., Chowdhury, S., Gupta, S., & Kumar, I. (2010). Insight into adsorption equilibrium, kinetics and thermodynamics of Malachite Green onto clayey soil of Indian origin. Chemical Engineering Journal, 165(3), 874-882.
Sallam, S. A., El-Subruiti, G. M., & Eltaweil, A. S. (2018). Facile Synthesis of Ag–γ-Fe2O3 Superior Nanocomposite for Catalytic Reduction of Nitroaromatic Compounds and Catalytic Degradation of Methyl Orange. Catalysis Letters, 148(12), 3701-3714.
Shaban, M., Abukhadra, M. R., Rabia, M., Elkader, Y. A., & El-Halim, M. R. A. (2018). Investigation the adsorption properties of graphene oxide and polyaniline nano/micro structures for efficient removal of toxic Cr (VI) contaminants from aqueous solutions; kinetic and equilibrium studies. Rendiconti Lincei. Scienze Fisiche e Naturali, 29(1), 141-154.
Srivastava, S., Sinha, R., & Roy, D. (2004). Toxicological effects of malachite green. Aquatic toxicology, 66(3), 319-329.
Taheri, M., Moghaddam, M.R.A. and Arami, M. (2012). Optimization of acid black 172 decolorization by electrocoagulation using response surface methodology. Iranian J.Environ.Health Sci.Eng. pp. 923-31.
Waheed, M., Butt, M. S., Shehzad, A., Adzahan, N. M., Shabbir, M. A., Suleria, H. A. R., & Aadil, R. M. (2019). Eggshell calcium: A cheap alternative to expensive supplements. Trends in Food Science & Technology, 91, 219-230.
Wang, Y. Y., Liu, Y. X., Lu, H. H., Yang, R. Q., & Yang, S. M. (2018). Competitive adsorption of Pb (II), Cu (II), and Zn (II) ions onto hydroxyapatite-biochar nanocomposite in aqueous solutions. Journal of Solid State Chemistry, 261, 53-61.
Wan Ngah, W. S., Ariff, N. F. M., Hashim, A., & Hanafiah, M. A. K. M. (2010). Malachite green adsorption onto chitosan coated bentonite beads: isotherms, kinetics and mechanism. Clean–Soil, Air, Water, 38(4), 394-400.
Wei, A., Liu, B., Zhao, H., Chen, Y., Wang, W., Ma, Y., ... & Liu, S. (2014). Synthesis and formation mechanism of flowerlike architectures assembled from ultrathin NiO nanoflakes and their adsorption to malachite green and acid red in water. Chemical Engineering Journal, 239, 141-148.
Yang, F., Zhang, S., Sun, Y., Cheng, K., Li, J., & Tsang, D. C. (2018). Fabrication and characterization of hydrophilic corn stalk biochar-supported nanoscale zero-valent iron composites for efficient metal removal. Bioresource technology, 265, 490-497.
Zhang, F., Yin, X., Lan, J., & Zhang, W. (2016). Application of Ba3(PO4)2/Fe3O4 as a novel magnetic adsorbent to remove methyl blue from aqueous solution. Journal of materials science, 51(7), 3525-3535.
Zhang, F., Wei, Z., Zhang, W., & Cui, H. (2017). Effective adsorption of malachite green using magnetic barium phosphate composite from aqueous solution. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 182, 116-122.

Details

Primary Language

Turkish

Subjects

Environmental Engineering

Journal Section

Research Article

Authors

Yağmur Uysal ^*
0000-0002-7217-8217
Türkiye

Pınar Belibağlı
0000-0001-6643-9620
Türkiye

Publication Date

September 1, 2020

Submission Date

June 15, 2020

Acceptance Date

July 9, 2020

Published in Issue

Year 2020 Volume: 23 Number: 3

DOI

https://doi.org/10.17780/ksujes.753116

IZ

https://izlik.org/JA88AC26ZF

Cite

RIS / Bibtex

APA

Uysal, Y., & Belibağlı, P. (2020). ATIK YUMURTA KABUKLARINDAN SENTEZLENEN HİDROKSİAPATİTLER İLE SULARDAN MALAHİT YEŞİL GİDERİMİ. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 23(3), 141-152. https://doi.org/10.17780/ksujes.753116

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