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Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde

Year 2016, Volume: 19 Issue: 1, 37 - 40, 10.05.2016

Abstract

The Schiff base ligand containing N,N donor atoms, (E)-4-(((pyridin-2-ylmethylene)amino)methyl)phenol (L1H) (Fig. 1), and its Ru(II) complex have been prepared. The ligand and its complex have been characterized by elemental analyses, IR spectra, UV-Visible spectroscopy, 1H and 13C NMR spectra and magnetic susceptibility measurements.  The analytical data show that the metal to ligand ratio in the L1H complexes is 1:1.

References

  • Ispir E. The synthesis, characterization, electrochemical character, catalytic and antimicrobial activity of novel, azo-containing Schiff bases and their metal complexes. Dyes Pigments. 2009; 82(1):13-9.
  • Atabey, H., Findik, E., Sari, H., Ceylan, M., “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 2014, 38(1), 109.
  • Huang, D. X., Wang, C. X., Song, Y. B., “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 2013, 83(12), 2361.
  • Khandar. A. A.; Nejati, K. Synthesis And Characterization of a Series of Copper(II) Complexes With Azo-linked Salicylaldimine Schiff Base Ligands. Crystal Structure of Cu5PHAZOSALTN.
  • CHCl3. Polyhedron. 2000, 19, 607-613.
  • Tümer, M.; Çelik, C.; Köksal, H.; and Serin, S. Transition Metal Complexes of Bidentate Schiff Base Ligands. Trans. Met. Chem. 1999, 24, 525.
  • J.L. Pratihar, S. Bhaduri, P. Pattanayak, D. Patra, S. Chattopadhyay, Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates, J Organomet Chem, 2009, 694,3401- 3408.
  • R.N. Prabhu, R. Ramesh, Synthesis, structural characterization, electrochemistry and catalytic transfer hydrogenation of ruthenium(II) carbonyl complexes containing tridentate benzoylhydrazone ligands, J Organomet Chem, 2012, 718, 43-51.
  • R.K. Rath, M. Nethaji, A.R. Chakravarty, Synthesis, crystal structure and catalytic properties of (p-cymene)ruthenium(II) azophenol complexes: azophenyl to azophenol conversion by oxygen insertion to a ruthenium carbon bond, J Organomet Chem, 2001, 633, 79-84.
  • R.K. Rath, M. Nethaji, A.R. Chakravarty, Transfer hydrogenation of acetophenone promoted by (arene)ruthenium(II) reduced Schiff base complexes: an X-ray structure of [(η6-p- cymene)RuCl(OC6H4-2-CH2NHC6H4-p-Me)], Polyhedron, 2001, 20, 2735-2739.
  • Sanmartin, J.; Bermejo,M. R.; Gariç-Deibe, A. M.; Maneiro, M.; Large, C.; Costa-Filho, A. J. Mono- and Polynuclear Complexes of Fe(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with N,N-Bis(3- hydroxysalicylidene)-1,3-diamino-2-propanol. Polyhedron, 2000, 19, 185-192.
  • Jaworska, J. K. New Platinum(II) Complexes With Schiff Base Ligands. Trans. Met. Chem., 1994, 19, 296-298.
  • Tümer, M.; Köksal, H.; Serin, S. Synthesis, Characterization and Thermal Investigation of some Metal Complexes Derived from New Schiff Base Ligands. Synth. React. Inorg. Met.-Org. Chem., 1998, 28 (8), 1393-1404.
  • Zolezzi, S.; Decinti, A.; Spodine, E. Sythesis and Characterization of Copper(II) Complexes with Schiff Base Ligands Derived from Ethylenediamine, Diphenylethylenediamine and Nitro, Bromo and Methox Saliclaldehyde. Polyhedron. 1999, 18, 897-904.
Year 2016, Volume: 19 Issue: 1, 37 - 40, 10.05.2016

Abstract

N,N donor atomlu Schiff bazı ligandı ve onun rutenyum (II) kompleksi sentezlenmiştir. Ligand ve kompleksin yapıları IR, UV-Visible spektroskopisi, 1H ve 13C NMR spektroskopisi, elementel analiz magnetik süssebtibilite yöntemleri ile karakterize edilmiştir. Analitik veriler kompleks yapısında metal ligand oranının 1:1 olduğunu göstermiştir

References

  • Ispir E. The synthesis, characterization, electrochemical character, catalytic and antimicrobial activity of novel, azo-containing Schiff bases and their metal complexes. Dyes Pigments. 2009; 82(1):13-9.
  • Atabey, H., Findik, E., Sari, H., Ceylan, M., “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 2014, 38(1), 109.
  • Huang, D. X., Wang, C. X., Song, Y. B., “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 2013, 83(12), 2361.
  • Khandar. A. A.; Nejati, K. Synthesis And Characterization of a Series of Copper(II) Complexes With Azo-linked Salicylaldimine Schiff Base Ligands. Crystal Structure of Cu5PHAZOSALTN.
  • CHCl3. Polyhedron. 2000, 19, 607-613.
  • Tümer, M.; Çelik, C.; Köksal, H.; and Serin, S. Transition Metal Complexes of Bidentate Schiff Base Ligands. Trans. Met. Chem. 1999, 24, 525.
  • J.L. Pratihar, S. Bhaduri, P. Pattanayak, D. Patra, S. Chattopadhyay, Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates, J Organomet Chem, 2009, 694,3401- 3408.
  • R.N. Prabhu, R. Ramesh, Synthesis, structural characterization, electrochemistry and catalytic transfer hydrogenation of ruthenium(II) carbonyl complexes containing tridentate benzoylhydrazone ligands, J Organomet Chem, 2012, 718, 43-51.
  • R.K. Rath, M. Nethaji, A.R. Chakravarty, Synthesis, crystal structure and catalytic properties of (p-cymene)ruthenium(II) azophenol complexes: azophenyl to azophenol conversion by oxygen insertion to a ruthenium carbon bond, J Organomet Chem, 2001, 633, 79-84.
  • R.K. Rath, M. Nethaji, A.R. Chakravarty, Transfer hydrogenation of acetophenone promoted by (arene)ruthenium(II) reduced Schiff base complexes: an X-ray structure of [(η6-p- cymene)RuCl(OC6H4-2-CH2NHC6H4-p-Me)], Polyhedron, 2001, 20, 2735-2739.
  • Sanmartin, J.; Bermejo,M. R.; Gariç-Deibe, A. M.; Maneiro, M.; Large, C.; Costa-Filho, A. J. Mono- and Polynuclear Complexes of Fe(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with N,N-Bis(3- hydroxysalicylidene)-1,3-diamino-2-propanol. Polyhedron, 2000, 19, 185-192.
  • Jaworska, J. K. New Platinum(II) Complexes With Schiff Base Ligands. Trans. Met. Chem., 1994, 19, 296-298.
  • Tümer, M.; Köksal, H.; Serin, S. Synthesis, Characterization and Thermal Investigation of some Metal Complexes Derived from New Schiff Base Ligands. Synth. React. Inorg. Met.-Org. Chem., 1998, 28 (8), 1393-1404.
  • Zolezzi, S.; Decinti, A.; Spodine, E. Sythesis and Characterization of Copper(II) Complexes with Schiff Base Ligands Derived from Ethylenediamine, Diphenylethylenediamine and Nitro, Bromo and Methox Saliclaldehyde. Polyhedron. 1999, 18, 897-904.
There are 14 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Esin İspir

Arif Aktaş

Publication Date May 10, 2016
Submission Date April 13, 2016
Published in Issue Year 2016Volume: 19 Issue: 1

Cite

APA İspir, E., & Aktaş, A. (2016). Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 19(1), 37-40. https://doi.org/10.17780/ksujes.73633