FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS

Cihan Geçgel

doi:10.17780/ksujes.1458311

EN TR

FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS

Abstract

Recently, water-stable ZIF MOFs, a new material class with a very large surface area, have attracted attention for the removal of organic pollutants. This type of MOF's excellent adsorption capacities, large pore volumes, and recyclability performances stand out compared to many other adsorbents. In this work, the ZIF-67 structure, a cobalt-containing ZIF, was synthesized using the ultrasound-assisted solvothermal method, and its phenol adsorption performance was investigated. The characterization of the ZIF-67 structure was carried out by SEM-EDS, XRD, FTIR, and nitrogen adsorption analyses. Nitrogen adsorption data showed that ZIF-67 had microporosity, and the surface area calculated from the BET model was 1656 m2/g. To synthesize ZIF-67, optimization of phenol adsorption, one of the important pollutants in water, was investigated by response surface method (RSM) for initial phenol concentration, adsorbent concentration, pH, and temperature variables. At the operating levels determined by RSM, the most effective removal of 92.2% was obtained at 30°C, 1 g/L adsorbent concentration, 20 mg/L initial phenol concentration, and pH 6.5. The adsorption isotherm of phenol onto ZIF-67 was fit to the Langmuir model, which is a monolayer interaction. According to the Langmuir isotherm model, the maximum phenol adsorption capacity of ZIF-67 was determined as 303.0 mg/g.

Keywords

Supporting Institution

Mersin University

Project Number

BAP proje No. 2023-1-AP4-4878

Thanks

Thanks to the Mersin University Scientific Research Projects Unit for financial support (BAP project No. 2023-1-AP4-4878) and the Mersin University Advanced Technology, Education, Research, and Application Center (MEITAM), from whose infrastructure we benefited.

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Details

Primary Language

English

Subjects

Environmental Pollution and Prevention , Separation Processes

Journal Section

Research Article

Authors

Cihan Geçgel ^*
0000-0001-7998-0811
Türkiye

Publication Date

September 3, 2024

Submission Date

March 25, 2024

Acceptance Date

April 25, 2024

Published in Issue

Year 1970 Volume: 27 Number: 3

DOI

https://doi.org/10.17780/ksujes.1458311

IZ

https://izlik.org/JA96KZ84TS

Cite

RIS / Bibtex

APA

Geçgel, C. (2024). FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 27(3), 1057-1068. https://doi.org/10.17780/ksujes.1458311

FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS

FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS

Abstract

Keywords

BASIT ULTRASONIK-DESTEKLI ZIF-67 SENTEZI VE SULU ÇÖZELTILERDEN FENOLÜN UZAKLAŞTIRILMASINDA KULLANIMI

Öz

Anahtar Kelimeler

Supporting Institution

Project Number

Thanks

References

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Acceptance Date

Published in Issue

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