FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS

Cihan Geçgel

doi:10.17780/ksujes.1458311

EN TR

FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS

Abstract

Recently, water-stable ZIF MOFs, a new material class with a very large surface area, have attracted attention for the removal of organic pollutants. This type of MOF's excellent adsorption capacities, large pore volumes, and recyclability performances stand out compared to many other adsorbents. In this work, the ZIF-67 structure, a cobalt-containing ZIF, was synthesized using the ultrasound-assisted solvothermal method, and its phenol adsorption performance was investigated. The characterization of the ZIF-67 structure was carried out by SEM-EDS, XRD, FTIR, and nitrogen adsorption analyses. Nitrogen adsorption data showed that ZIF-67 had microporosity, and the surface area calculated from the BET model was 1656 m2/g. To synthesize ZIF-67, optimization of phenol adsorption, one of the important pollutants in water, was investigated by response surface method (RSM) for initial phenol concentration, adsorbent concentration, pH, and temperature variables. At the operating levels determined by RSM, the most effective removal of 92.2% was obtained at 30°C, 1 g/L adsorbent concentration, 20 mg/L initial phenol concentration, and pH 6.5. The adsorption isotherm of phenol onto ZIF-67 was fit to the Langmuir model, which is a monolayer interaction. According to the Langmuir isotherm model, the maximum phenol adsorption capacity of ZIF-67 was determined as 303.0 mg/g.

Keywords

BASIT ULTRASONIK-DESTEKLI ZIF-67 SENTEZI VE SULU ÇÖZELTILERDEN FENOLÜN UZAKLAŞTIRILMASINDA KULLANIMI

Öz

Oldukça geniş yüzey alanına sahip yeni bir malzeme sınıfı olan suya dayanıklı ZIF MOF'lar, organik kirleticilerin uzaklaştırılması konusunda son yıllarda dikkat çekmektedir. Bu tip MOF'ların mükemmel adsorpsiyon kapasiteleri, geniş gözenek hacimleri ve geri dönüştürülebilirlik performansları diğer birçok adsorbanla karşılaştırıldığında öne çıkmaktadır. Bu çalışmada da kobalt içerikli bir ZIF yapısı (ZIF-67) ultrasonik destekli solvotermal yöntem kullanılarak sentezlendi ve fenol adsorpsiyon performansı araştırıldı. Sentezlenen ZIF yapısının karakterizasyonu SEM-EDS, XRD, FTIR ve nitrojen adsorpsiyon analizleri ile gerçekleştirildi. Azot adsorpsiyon verileri, ZIF-67'nin mikro gözenekliliğe sahip olduğunu ve Brauner Emmet Teller (BET) modelinden hesaplanan yüzey alanının 1656 m2/g olduğunu gösterdi. ZIF-67'yi sentezlemek için sudaki önemli kirleticilerden biri olan fenol adsorpsiyonunun optimizasyonu, başlangıç fenol derişimi, adsorbent derişimi, pH ve sıcaklık değişkenleri için yanıt yüzey yöntemi (RSM) ile araştırıldı. RSM ile belirlenen çalışma seviyelerinde %92,2'lik en etkili giderim 30°C'de, 1 g/L adsorban derişiminde, 20 mg/L başlangıç fenol derişiminde ve pH 6,5'te elde edildi. Fenolün ZIF-67 üzerine adsorpsiyon izotermi, tek katmanlı bir etkileşim olan Langmuir modeline uyuyordu. Langmuir izoterm modeline göre ZIF-67'nin maksimum fenol adsorpsiyon kapasitesi 303,0 mg/g olarak belirlendi.

Anahtar Kelimeler

Destekleyen Kurum

Mersin University

Proje Numarası

BAP proje No. 2023-1-AP4-4878

Teşekkür

Thanks to the Mersin University Scientific Research Projects Unit for financial support (BAP project No. 2023-1-AP4-4878) and the Mersin University Advanced Technology, Education, Research, and Application Center (MEITAM), from whose infrastructure we benefited.

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Çevre Kirliliği ve Önlenmesi , Ayırma İşlemleri

Bölüm

Araştırma Makalesi

Yazarlar

Cihan Geçgel ^*
0000-0001-7998-0811
Türkiye

Yayımlanma Tarihi

3 Eylül 2024

Gönderilme Tarihi

25 Mart 2024

Kabul Tarihi

25 Nisan 2024

Yayımlandığı Sayı

Yıl 2024 Cilt: 27 Sayı: 3

DOI

https://doi.org/10.17780/ksujes.1458311

IZ

https://izlik.org/JA96KZ84TS

Kaynak Göster

RIS / Bibtex

APA

Geçgel, C. (2024). FACILE ULTRASONIC-ASSISTED ZIF-67 SYNTHESIS AND USE IN PHENOL REMOVAL FROM AQUEOUS SOLUTIONS. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 27(3), 1057-1068. https://doi.org/10.17780/ksujes.1458311