Piezoelektrik Malzemelerin Lityum İyon Batarya Anotlarında Katkı Olarak Kullanılması

M. Taha Demirkan; Mehbare Doğrusöz

doi:10.17780/ksujes.672828

Research Article

Piezoelektrik Malzemelerin Lityum İyon Batarya Anotlarında Katkı Olarak Kullanılması

Year 2021, , 258 - 270, 03.12.2021

M. Taha Demirkan , Mehbare Doğrusöz

https://doi.org/10.17780/ksujes.672828

Abstract

Özet
Lityum iyon bataryalarında son günlerdeki en popüler malzeme olarak gösterilen silisyum (Si) içerikli malzemelerle ilgili önemli sorunlar, bunların ticari olarak yaygınlaşmasını engellemektedir. Si anot malzemelerinin şarj/deşarj esnasında yüksek hacim değişikliğine uğraması ve mekanik olarak dayanıksızlığı bu sorunların başında gelmektedir. Bu çalışmada PZT tabanlı piezoelektrik malzemelerin kullanılmasıyla bu sorunların çözümündeki katkısı üzerinde durulmuştur. Si ve karbon (C) karışımı anot malzemelerinde katkı olarak PZT parçacıkları kullanıldığında bu malzemelerin kapasite performansında artış olduğu görülmüştür. Bu artışın nedenleri tartışılmakla birlikte farklı türlerde PZT malzemeleri ile farklı oranlarda Si-C karışımları üzerine test yapılmış ve aralarındaki performans farkları incelenmiştir. PZT kullanımı olmadığı durumlarda ilk 50 çevrimde 50 mAh/g’in altında spesifik kapasite değerleri vererek bozulmaya uğrayan anot malzemelerinin, PZT katkısı kullanılmasıyla 100. çevrimde dahi 400 mAh/g üzerinde değerleri verdiği gözlemlenmiştir.

Keywords

Silisyum Anot, Lityum İyon Batarya, Piezoelektrik

Supporting Institution

TÜBİTAK

Project Number

118M340

Thanks

Yazar bu çalışmadaki desteklerinden ve yardımlarından dolayı Doç. Dr. Rezan Demir-Çakan’a ve Prof. Dr. Hüseyin Yılmaz’a teşekkürlerini sunar

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