SİNTERLEME SICAKLIKLARI VE MAGNEZYUM OKSİT İLAVESİNİN HİDROKSİAPATİTİN ÖZELLİKLERİNE ETKİSİ

Süleyman Serdar Pazarlıoğlu

doi:10.17780/ksujes.774314

SİNTERLEME SICAKLIKLARI VE MAGNEZYUM OKSİT İLAVESİNİN HİDROKSİAPATİTİN ÖZELLİKLERİNE ETKİSİ

Öz

Bu çalışmada farklı sinterleme sıcaklıkları (900-1300oC) ve farklı oranlardaki magnezyum oksit (MgO; ağırlıkça %0.5, %1 ve %2) ilavelerinin ticari saflıktaki bir hidroksiapatit (HA)’ in mikroyapısal, fiziksel ve mekanik özelliklerine etkileri incelendi. MgO ilavesiz HA’ in basma dayanımı ve kırılma tokluğu özelliklerinin üç ana nedenden dolayı (dekompoze olma, aşırı tane büyümesi ve mikro çatlak oluşumu) 1100oC' nin üzerindeki sıcaklıklarda azaldığı belirlendi. Tüm numunelerde ana faz olarak HA, eser faz olarak ise beta/alfa-trikalsiyum fosfat ve kalsiyum oksit (MgO ilavesiz HA’ te) ile whitlockite (MgO ilaveli HA’ te) tespit edildi. MgO ilavesi ile saf HA’ te meydana gelen tane büyümesinin engellendiği görüldü. Ağırlıkça %1 oranında MgO ilaveli HA’ te ait mikroyapıların, diğerlerine kıyasla daha homojen ve düzgün tanelerden oluştuğu tespit edildi. HA’ e ağırlıkça %0.5 ve %1 oranlarında MgO ilavesinin tüm sıcaklıklarda saf HA’ e ait özelliklerin artmasına katkı sağladığı belirlendi. Poroziteli yapısı nedeniyle, %2 MgO ilaveli HA tüm sinterleme sıcaklıklarında diğerlerinden daha düşük sinterlenebilirliğe ve özelliklere sahip olduğu belirlendi. %1 MgO ilaveli HA’ nin, saf HA’ e oranla %38 oranında daha fazla basma dayanımı (183.25±25.09 MPa) ve %53 oranında daha fazla kırılma tokluğuna (1.472±0.041 MPam1/2) sahip olduğu, ancak düşük kırılma tokluğu nedeniyle insan vücudunda kullanıma uygun olmadığı belirlendi.

Anahtar Kelimeler

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Mühendislik , Giyilebilir Malzemeler

Bölüm

Araştırma Makalesi

Yazarlar

Süleyman Serdar Pazarlıoğlu ^*
0000-0002-7870-8418
Türkiye

Yayımlanma Tarihi

3 Mart 2021

Gönderilme Tarihi

27 Temmuz 2020

Kabul Tarihi

17 Şubat 2021

Yayımlandığı Sayı

Yıl 2021 Cilt: 24 Sayı: 1

DOI

https://doi.org/10.17780/ksujes.774314

IZ

https://izlik.org/JA94SG34NK

Kaynak Göster

RIS / Bibtex

APA

Pazarlıoğlu, S. S. (2021). SİNTERLEME SICAKLIKLARI VE MAGNEZYUM OKSİT İLAVESİNİN HİDROKSİAPATİTİN ÖZELLİKLERİNE ETKİSİ. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 24(1), 1-14. https://doi.org/10.17780/ksujes.774314