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SİNTERLEME SICAKLIKLARI VE MAGNEZYUM OKSİT İLAVESİNİN HİDROKSİAPATİTİN ÖZELLİKLERİNE ETKİSİ

Yıl 2021, Cilt 24, Sayı 1, 1 - 14, 03.03.2021
https://doi.org/10.17780/ksujes.774314

Öz

Bu çalışmada farklı sinterleme sıcaklıkları (900-1300oC) ve farklı oranlardaki magnezyum oksit (MgO; ağırlıkça %0.5, %1 ve %2) ilavelerinin ticari saflıktaki bir hidroksiapatit (HA)’ in mikroyapısal, fiziksel ve mekanik özelliklerine etkileri incelendi. MgO ilavesiz HA’ in basma dayanımı ve kırılma tokluğu özelliklerinin üç ana nedenden dolayı (dekompoze olma, aşırı tane büyümesi ve mikro çatlak oluşumu) 1100oC' nin üzerindeki sıcaklıklarda azaldığı belirlendi. Tüm numunelerde ana faz olarak HA, eser faz olarak ise beta/alfa-trikalsiyum fosfat ve kalsiyum oksit (MgO ilavesiz HA’ te) ile whitlockite (MgO ilaveli HA’ te) tespit edildi. MgO ilavesi ile saf HA’ te meydana gelen tane büyümesinin engellendiği görüldü. Ağırlıkça %1 oranında MgO ilaveli HA’ te ait mikroyapıların, diğerlerine kıyasla daha homojen ve düzgün tanelerden oluştuğu tespit edildi. HA’ e ağırlıkça %0.5 ve %1 oranlarında MgO ilavesinin tüm sıcaklıklarda saf HA’ e ait özelliklerin artmasına katkı sağladığı belirlendi. Poroziteli yapısı nedeniyle, %2 MgO ilaveli HA tüm sinterleme sıcaklıklarında diğerlerinden daha düşük sinterlenebilirliğe ve özelliklere sahip olduğu belirlendi. %1 MgO ilaveli HA’ nin, saf HA’ e oranla %38 oranında daha fazla basma dayanımı (183.25±25.09 MPa) ve %53 oranında daha fazla kırılma tokluğuna (1.472±0.041 MPam1/2) sahip olduğu, ancak düşük kırılma tokluğu nedeniyle insan vücudunda kullanıma uygun olmadığı belirlendi.

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Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik, Malzeme Bilimleri, Tekstil
Bölüm Tekstil Mühendisliği
Yazarlar

Süleyman Serdar PAZARLIOĞLU (Sorumlu Yazar)
MARMARA ÜNİVERSİTESİ, TEKNOLOJİ FAKÜLTESİ
0000-0002-7870-8418
Türkiye

Yayımlanma Tarihi 3 Mart 2021
Başvuru Tarihi 27 Temmuz 2020
Kabul Tarihi 17 Şubat 2021
Yayınlandığı Sayı Yıl 2021, Cilt 24, Sayı 1

Kaynak Göster

APA Pazarlıoğlu, S. S. (2021). SİNTERLEME SICAKLIKLARI VE MAGNEZYUM OKSİT İLAVESİNİN HİDROKSİAPATİTİN ÖZELLİKLERİNE ETKİSİ . Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi , 24 (1) , 1-14 . DOI: 10.17780/ksujes.774314