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Adsorption of Copper (II) from Aqueous Solution by Using Carbonized Peanut Hull: Determination of the Equilibrium, Kinetic and Thermodynamic Parameters

Yıl 2020, Cilt: 5 Sayı: 2, 131 - 137, 30.06.2020

Gülşad Uslu Şenel

https://doi.org/10.35229/jaes.672951
Cited By: 1

Öz

In this study, the effect of temperature, pH, initial metal concentration and adsorbent dosage on Cu(II) adsorption onto carbonized peanut hull (PHC) was investigated. Activated carbon was prepared from peanut hull. It was produced by carbonization in carbon diokside atmosphere at 500 °C for 1.0 h. The maximum Cu (II) adsorption capacity was obtained as 168.16 mg/g for 500 mg/L initial Cu (II) at pH = 4.0 and 60 °C. The Freundlich and Langmuir adsorption models were used for the mathematical description of the adsorption equilibrium. The best interpretation for the experimental data was given by the Freundlich isotherm and the maximum adsorption capacity was obtained. Batch adsorption models, based on the assumption of the pseudo-first and pseudo-second order mechanism, were applied to examine the kinetics of the adsorption. Kinetic data fitted the pseudo-second kinetic order model. Thermodynamic functions, the change of free energy (Go), enthalpy (Ho) and entropy (So) of copper adsorption on PHC were calculated as -23.21 kjmol-1 (at 60 oC), 15.94 kjmol-1 and 117.59 kjmol-1 K-1, respectively, indicating the spontaneous, endothermic and the increased randomness nature of Cu2+ adsorption. The results show that adsorption of Cu (II) on PHC is an.

Anahtar Kelimeler

Adsorption Carbonization Peanut hull carbon (PHC) Equilibrium Kinetic

Kaynakça

  • Argun, M. E., Dursun, S. (2008). A new approach to modification of natural adsorbent for heavy metal adsorption. Bioresearch Technology, 99, 2516–2527.
  • Bansode, R.R., Losso, J.N., Marshall, W.E., Rao, R.M., Portier, R.J. (2004). Pecan shell-based granular activated carbon for treatment of chemical oxygen demand (COD) in municipal wastewater. Bioresour. Technol. 94, 129–135.
  • Bayat, B. (2002). Comparative study of adsorption properties of Turkish fly ashes. I. The case of nickel(II), copper(II) and zinc(II). J. Hazard. Mater. 3897, 1–23.
  • Cetin, S., Pehlivan, E. (2007). The use of fly ash as a low cost, environmentally friendly alternative to activated carbon for the removal of heavy metals from aqueous solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 298(1-2), 83-87.
  • Demirbaş, E., Dizge, N., Kobya, M. (2009). Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon. Chemical Eng. J, 148, 480-487.
  • Dursun, A. Y. (2006). A comparative study on determination of the equilibrium, kinetic and Thermodynamic parameters of adsorption of copper (II) and lead (II) ions onto pretreated Aspergillus niger. Biochem. Eng. J, 28, 187–195.
  • Dursun, G., Çiçek, H., Dursun, A.Y. (2005). Adsorption of phenol from aqueous solution by using carbonised beet pulp. Journal of Hazardous Materials, 125 (1-3, 17), 175- 182.
  • El-Ashtoukhy, E.-S Z., Amin, N.K., Abdelwahab, O. (2008). Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent. Desalination, 223, (1-3): 162-173.
  • Freundlich, H.M.F. (1906). Uberdie adsorption in lasungen. J. Phys. Chem.; 57, 385-470.
  • Giwa, O.S., Bello, I.A. (2007). Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon. Biochem. Engin. J., 36(2), 174-181.
  • Gong, R., Li, M., Yang, C., Sun, Y., Chen, J. (2005). Removal of cationic dyes from aqueous solution by adsorption on peanut hull. Journal of Hazardous Materials. 121 (1-3), 247-250.
  • Gong, R., Sun, Y., Chen, J., Liu, H., Yang, C. (2005). Effect of chemical modification on dye adsorption capacity of peanut hull. Dyes and Pigments. 67 (3), 175-181.
  • Ho, Y.S., Mckay, G. (1999). Pseudo-second order model for sorption processes, Process Biochem. 34, 451–465.
  • Jiang, Y., Pang, H., Bing, L. (2009). Removal ofg copper (II) ions from aqueous solution by modified bagasse. J of Hazardous, 164, 1-9.
  • Kara, M., Yüzer, H., Sabah, E., Çelik, M. (2003). Adsorption of cobalt from aqueous solution onto seplolite, Water Research. 37, 224-232.
  • Lagergren, S. (1998). Zur theorie der sogenannten adsorption geloster stoffe, Kungliga Svenska Vetenkapsakademiens, handlingar. 24, 1–39.
  • Langmuir, I. (1916). The constitution and fundamental properties of solids and liquids, J Am Chem Soc. 38 (11), 2221-95. Özçimen, D., Ersoy-Meriçboyu, A. (2009). Removal of copper from aqueoussolutions by adsorption onto chestnut shell and garpeseed activated carbons.J. of Hazardous. 168, 1118–1125
  • Özer, D., Dursun, G., Özer, A. (2007). Methylene blue adsorption from aqueous solution by dehydrated peanut hull. J. of Hazard. Mater, 144, 171-179.
  • Parrish, D. (1998). The use of peanut hulls as a low cost adsorbent for the treatment of metal bearing waste streams. Thesis. University of Alabama, Tuscaloosa, AL.
  • Perisamy, K., Namasivayam, C. (1995). Removal of nickel(II) from aqueous solution and nickel plating industry wastewater using an agricultural waste: peanut hulls. Waste Mgmt.15, 63–68.
  • Periasamy, K., Namasivayam, C. (1996). Removal of copper (II) by adsorption onto peanut hull carbon from water and copper plating industry wastewater. Chemosphere. 32 (4), 769-789.
  • Sölener, M., Tunali, S., Özcan, A.S., Özcan, A., Gedikbey, T. (2008). Adsorption characteristics of lead(II) ions onto the clay/poly(methoxyethyl)acrylamide (PMEA) composite from aqueous solutions. Desalination, 223, 308–322.
  • Tewari, N., Vasudevan, P., Guha, B.K. (2005). Study on biosorption of Cr (VI) by Mucor hiemalis, Biochemical Eng. J. 23, 185-192.
  • Wang, H.J., Zhou, A.L., Peng, F., Yu, H., Chen, L.F. (2007). Adsorption characteristic of acidified carbon nanotubes for heavy metal Pb (II) in aqueous solution. Materials Science and Engineering: A. 466 (1-2), 201-206.
  • WHO. (2006). Guidelines for Drinking-Water Quality: Incorporating First Addendum, 1,. Recommendations, third ed., World Health Organization, Geneva.

Yıl 2020, Cilt: 5 Sayı: 2, 131 - 137, 30.06.2020

Gülşad Uslu Şenel

https://doi.org/10.35229/jaes.672951
Cited By: 1

Öz

Kaynakça

  • Argun, M. E., Dursun, S. (2008). A new approach to modification of natural adsorbent for heavy metal adsorption. Bioresearch Technology, 99, 2516–2527.
  • Bansode, R.R., Losso, J.N., Marshall, W.E., Rao, R.M., Portier, R.J. (2004). Pecan shell-based granular activated carbon for treatment of chemical oxygen demand (COD) in municipal wastewater. Bioresour. Technol. 94, 129–135.
  • Bayat, B. (2002). Comparative study of adsorption properties of Turkish fly ashes. I. The case of nickel(II), copper(II) and zinc(II). J. Hazard. Mater. 3897, 1–23.
  • Cetin, S., Pehlivan, E. (2007). The use of fly ash as a low cost, environmentally friendly alternative to activated carbon for the removal of heavy metals from aqueous solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 298(1-2), 83-87.
  • Demirbaş, E., Dizge, N., Kobya, M. (2009). Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon. Chemical Eng. J, 148, 480-487.
  • Dursun, A. Y. (2006). A comparative study on determination of the equilibrium, kinetic and Thermodynamic parameters of adsorption of copper (II) and lead (II) ions onto pretreated Aspergillus niger. Biochem. Eng. J, 28, 187–195.
  • Dursun, G., Çiçek, H., Dursun, A.Y. (2005). Adsorption of phenol from aqueous solution by using carbonised beet pulp. Journal of Hazardous Materials, 125 (1-3, 17), 175- 182.
  • El-Ashtoukhy, E.-S Z., Amin, N.K., Abdelwahab, O. (2008). Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent. Desalination, 223, (1-3): 162-173.
  • Freundlich, H.M.F. (1906). Uberdie adsorption in lasungen. J. Phys. Chem.; 57, 385-470.
  • Giwa, O.S., Bello, I.A. (2007). Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon. Biochem. Engin. J., 36(2), 174-181.
  • Gong, R., Li, M., Yang, C., Sun, Y., Chen, J. (2005). Removal of cationic dyes from aqueous solution by adsorption on peanut hull. Journal of Hazardous Materials. 121 (1-3), 247-250.
  • Gong, R., Sun, Y., Chen, J., Liu, H., Yang, C. (2005). Effect of chemical modification on dye adsorption capacity of peanut hull. Dyes and Pigments. 67 (3), 175-181.
  • Ho, Y.S., Mckay, G. (1999). Pseudo-second order model for sorption processes, Process Biochem. 34, 451–465.
  • Jiang, Y., Pang, H., Bing, L. (2009). Removal ofg copper (II) ions from aqueous solution by modified bagasse. J of Hazardous, 164, 1-9.
  • Kara, M., Yüzer, H., Sabah, E., Çelik, M. (2003). Adsorption of cobalt from aqueous solution onto seplolite, Water Research. 37, 224-232.
  • Lagergren, S. (1998). Zur theorie der sogenannten adsorption geloster stoffe, Kungliga Svenska Vetenkapsakademiens, handlingar. 24, 1–39.
  • Langmuir, I. (1916). The constitution and fundamental properties of solids and liquids, J Am Chem Soc. 38 (11), 2221-95. Özçimen, D., Ersoy-Meriçboyu, A. (2009). Removal of copper from aqueoussolutions by adsorption onto chestnut shell and garpeseed activated carbons.J. of Hazardous. 168, 1118–1125
  • Özer, D., Dursun, G., Özer, A. (2007). Methylene blue adsorption from aqueous solution by dehydrated peanut hull. J. of Hazard. Mater, 144, 171-179.
  • Parrish, D. (1998). The use of peanut hulls as a low cost adsorbent for the treatment of metal bearing waste streams. Thesis. University of Alabama, Tuscaloosa, AL.
  • Perisamy, K., Namasivayam, C. (1995). Removal of nickel(II) from aqueous solution and nickel plating industry wastewater using an agricultural waste: peanut hulls. Waste Mgmt.15, 63–68.
  • Periasamy, K., Namasivayam, C. (1996). Removal of copper (II) by adsorption onto peanut hull carbon from water and copper plating industry wastewater. Chemosphere. 32 (4), 769-789.
  • Sölener, M., Tunali, S., Özcan, A.S., Özcan, A., Gedikbey, T. (2008). Adsorption characteristics of lead(II) ions onto the clay/poly(methoxyethyl)acrylamide (PMEA) composite from aqueous solutions. Desalination, 223, 308–322.
  • Tewari, N., Vasudevan, P., Guha, B.K. (2005). Study on biosorption of Cr (VI) by Mucor hiemalis, Biochemical Eng. J. 23, 185-192.
  • Wang, H.J., Zhou, A.L., Peng, F., Yu, H., Chen, L.F. (2007). Adsorption characteristic of acidified carbon nanotubes for heavy metal Pb (II) in aqueous solution. Materials Science and Engineering: A. 466 (1-2), 201-206.
  • WHO. (2006). Guidelines for Drinking-Water Quality: Incorporating First Addendum, 1,. Recommendations, third ed., World Health Organization, Geneva.
Toplam 25 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Makaleler
Yazarlar

Gülşad Uslu Şenel 0000-0002-5304-9436

Yayımlanma Tarihi 30 Haziran 2020
Gönderilme Tarihi 10 Ocak 2020
Kabul Tarihi 17 Nisan 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 5 Sayı: 2

Kaynak Göster

APA Uslu Şenel, G. (2020). Adsorption of Copper (II) from Aqueous Solution by Using Carbonized Peanut Hull: Determination of the Equilibrium, Kinetic and Thermodynamic Parameters. Journal of Anatolian Environmental and Animal Sciences, 5(2), 131-137. https://doi.org/10.35229/jaes.672951

Cited By

Şartlandırılmış Zeolit - Klinoptilolit Minerali ile Bakır Gideriminin Araştırılması
Karadeniz Fen Bilimleri Dergisi
https://doi.org/10.31466/kfbd.1179342
 Kapak Resmi İndir


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