EN
TR
Photoluminescence properties of azo-containing Schiff Bases metal complexes
Abstract
The Schiff base ligand containing -N=N- group, 4-((E)-(4-bromophenyl)diazenyl)-2-((E)-(phenylimino)methyl)phenol (L1H) (Fig. 1), and its CoII, CuII, NiII, ZnII and FeIII complexes have been prepared and characterized in previous study. According to analytical, UV-visible and IR data, the metal complexes are formed by coordination of the N, O atoms of the ligands and metal:ligand ratio was found to 1:2 for all the complexes. In this study, photoluminescence properties of L1H and its metal complexes were investigated.
Keywords
References
- Shaghaghi, Z., (2014), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Spectrochim Acta A, 131, 67.
- Atabey, H., Findik, E., Sari, H., Ceylan, M., (2014), “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 38(1), 109.
- Huang, D. X., Wang, C. X., Song, Y. B., (2013), “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 83(12), 2361.
- Farhadi. S., Sepahvand, S., (2010), “Na4W10O32/ZrO2 nanocomposite prepared via a sol-gel route: A novel, green and recoverable photocatalyst for reductive cleavage of azobenzenes to amines with 2-propanol”, J Mol Catal A-Chem., 318(1-2), 75.
- Govindaswamy. P., Sinha. C., Kollipara. M. R., (2005), “Syntheses and characterization of eta(5)cyclopentadienyl and eta(5)-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(eta(5)C5H5)Ru(PPh3)(C6H5-N=N-C3H3N2)]”, J Organomet Chem., 690(14), 3465.
- Shinar, J., (Ed.), Organic Light-Emitting Devices: A Survey, Springer-Verlag, NY, 2004.
- Hens, A., Mondal, P., Rajak, K. K., (2015), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Polyhedron, 85, 255.
- Wang, J., Ha, C.-S., (2010), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Tetrahedron, 66, 1846.
Details
Primary Language
English
Subjects
-
Journal Section
-
Publication Date
December 24, 2015
Submission Date
December 23, 2015
Acceptance Date
-
Published in Issue
Year 1970 Volume: 18 Number: 2