Azo Grubu İçeren Schiff Baz Metal Komplekslerinin Fotolüminesans Özellikleri

Cilt: 18 Sayı: 2 24 Aralık 2015
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Photoluminescence properties of azo-containing Schiff Bases metal complexes

Abstract

The Schiff base ligand containing -N=N- group, 4-((E)-(4-bromophenyl)diazenyl)-2-((E)-(phenylimino)methyl)phenol (L1H) (Fig. 1), and its CoII, CuII, NiII, ZnII and FeIII complexes have been prepared and characterized in previous study. According to analytical, UV-visible and IR data, the metal complexes are formed by coordination of the N, O atoms of the ligands and metal:ligand ratio was found to 1:2 for all the complexes. In this study, photoluminescence properties of L1H and its metal complexes were investigated.

Keywords

Kaynakça

  1. Shaghaghi, Z., (2014), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Spectrochim Acta A, 131, 67.
  2. Atabey, H., Findik, E., Sari, H., Ceylan, M., (2014), “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 38(1), 109.
  3. Huang, D. X., Wang, C. X., Song, Y. B., (2013), “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 83(12), 2361.
  4. Farhadi. S., Sepahvand, S., (2010), “Na4W10O32/ZrO2 nanocomposite prepared via a sol-gel route: A novel, green and recoverable photocatalyst for reductive cleavage of azobenzenes to amines with 2-propanol”, J Mol Catal A-Chem., 318(1-2), 75.
  5. Govindaswamy. P., Sinha. C., Kollipara. M. R., (2005), “Syntheses and characterization of eta(5)cyclopentadienyl and eta(5)-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(eta(5)C5H5)Ru(PPh3)(C6H5-N=N-C3H3N2)]”, J Organomet Chem., 690(14), 3465.
  6. Shinar, J., (Ed.), Organic Light-Emitting Devices: A Survey, Springer-Verlag, NY, 2004.
  7. Hens, A., Mondal, P., Rajak, K. K., (2015), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Polyhedron, 85, 255.
  8. Wang, J., Ha, C.-S., (2010), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Tetrahedron, 66, 1846.

Ayrıntılar

Birincil Dil

İngilizce

Konular

-

Bölüm

-

Yazarlar

Mesut İkiz

Gökhan Ceyhan

Yayımlanma Tarihi

24 Aralık 2015

Gönderilme Tarihi

23 Aralık 2015

Kabul Tarihi

-

Yayımlandığı Sayı

Yıl 1970 Cilt: 18 Sayı: 2

Kaynak Göster

APA
İkiz, M., Ceyhan, G., & İspir, E. (2015). Photoluminescence properties of azo-containing Schiff Bases metal complexes. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 18(2), 49-53. https://doi.org/10.17780/ksujes.08941