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Preparation and characterization of potato crust-based polyurethane foam-I

Year 2023, Volume: 7 Issue: 2, 204 - 214, 31.12.2023

Tülay Gürsoy M. Alma Ertuğrul Altuntaş Eyyüp Karaoğul

https://doi.org/10.32571/ijct.1368742

Abstract

Polyurethanes (PUs) are polymers obtained by reacting diisocyanates with a group of polyols. The first synthesized PU compounds were prepared using petroleum subproduct compounds. In this research study, biomass-containing polyols, which have been studied by other scientists, were prepared using potato crust and polymerized with diisocyanates to produce PU foam. Polyol reactions were carried out using the microwave heating method. Synthesis reactions and structural properties of polyols have been studied in many aspects. The most available polyol was used for PU synthesis. Different formulations were tried for PU synthesis and as a result, PU foam containing nearly 25% starch-polyol was synthesized. The chemical structure of PU polymer was identified by ATR-FTIR spectroscopy and crystallographic properties by WA-XRD analysis. The physical and mechanical properties of PU foam, which is used as a large number of building and construction materials, including thermal insulation materials, were evaluated by comparing them with a commercial PU foam.
According to the results of our research, it was detected that the incorporation of biomass into the structure of PU polymer improved its density, heat conduction coefficient, pressure based mechanical properties. PU foam derived from potato waste has a WA XRD-ray diffraction peak between 13.1-28.5o. This data is between 12.5-23o in synthetic commercial foam and has been positively improved in the product we synthesized as a result of combining biomass into the structure. The synthesized biomass-based PU foam can be used as thermal insulation material. Biomass-based PU foam has been synthesized with features that can be used as a thermal insulation material.

Keywords

Biomass polyol polyurethane foam characterization

Ethical Statement

I declare that there is no a conflict of interest with any person, institute, company etc.

Supporting Institution

Van Yüzüncü Yıl University Scientific Search Project Department

Project Number

2013- FBE-D060

Thanks

We are grateful for the financial support provided for this research by Van Yüzüncü Yıl University Scientific Search Project Department (2013- FBE-D060).

References

  • 1. http://pagev.org/poliuretanlar/ (accessed September 12, 2023)
  • 2.http://emagen.gov.tr/poliuretan-nedir/ (accessed September 12, 2023)
  • 3.Hu, S.; Li, Y.; Industrial Crops and Products. 2014, 57, 188-194.
  • 4.Philips, L. N., and Parker, D. B. V. (1965). Polyurethanes Chemistry, Technology and Properties. Ilife Books Ltd., London.
  • 5.Ferrigno, T.H. Rigid Plastics Foams. Second Edition. Reinhold Publishing Corp./ Chapman-Reinhold. Newyork, NY, 1967; p.146.
  • 6.Zheng, Z.; Pan, H.; Huang, Y.; Chung, Y. H.; Zhang, X.; Feng, H. The Open Materials Science Journal 2011, 5, 1-8.
  • 7.Guelcher, S. A.; Patel, V.; Gallagher, K. M.; Connolly, S.; Didier, J. E.; Doctor, J. S. 2006. Tissue Eng. 2006, 12(5): 1247-1259.
  • 8.Rai, M.; Yadav, A.; Gade, A. Biotechnol. Adv. 2009, 27(1):76-83.
  • 9.Lemos, V.A.; Santos, M.S.; Santos, E.S.; Santos, M.J.S.; dos Santos, W.N.L. Spectrochimica Acta Part B, 2007, 62, 4-12.
  • 10.http://kimpur.com/tr/poliuretan-nedir/ (accessed September 12, 2023)
  • 11.Luo, X.; Hu, S.; Zhang, X.; Li, Y. Bioresource Technology. 2013, 139(2013): 323-329.
  • 12.Serrano, L.; Rincon, E.; Rodriguez, J.; Briones, R. Polymers. 2020, 12, 1-13.
  • 13.Zhang, Q.; Lin, X.; Chen, W.; Zhang, H.; Han, D. Polymers. 2020, 12(107):1-10.
  • 14. Furtwengler, P.; Averous, L. Polymer Chemistry. 2018, 32, 4253-4318.
  • 15.Ma, Y.; Xiao, Y.; Zhao, Y.; Bei, Y.; Hu, L.; Zhou, Y.; Jia, P. Reactive and Functional Polymers, 2022, 175, 105285.
  • 16.Briones, R.; Serrano, L.; Labidi, J. J. Chem. Technol. Biotechnol. 2012, 87, 244-249.
  • 17.Lee, S.H.; Yoshioka, M.; Shiraishi, N. J.Appl. Polym. Sci. 2000, 78, 319-325.
  • 18.Ge, J.; Zhang, W.; Li, W.; Sakai, K. Journal of Applied Polymer Science, 2000, 77, 2575-2580.
  • 19.Zlatic, A.; Lava, C.; Zhang, W.; Petrovic, Z.S. J.Polym. Sci. Polym. Phys. 2004, 42, 809-819.
  • 20.Walfson, A.; Litvak, G.; Dlugy, C.; Shotland, Y.; Tavor, D. Int. Crop. Prod. 2009, 30, 80-81
  • 21.http://www.ozcankimya.com/detay.phd?id=71 (accessed September 12, 2023)
  • 22.Alma, M. H.; Baştürk M. A.; Dıgrak, M. Journal of Materials Letters. 2003, 22, 1225-1228.
  • 23.Yamada, T. Mokuzai Gakkaishi, 1996, 42: 1098-1104.
  • 24.Ugarte, L.; Saralegi, A.; Fernandez, R.; Martin, L.; Corcuera, M.A.; Eceiza, A. Industrial Crops and Products, 2014, 62: 545-551.
  • 25.Goheen, M.S.; Wool, R.P. J. Appl. Polym. Sci. 1991, 42(10): 2691-2701.
  • 26.Pan, H.; Zheng, Z.; Chung, Y. H. Eur. J. Wood and Wood Prod. 2011, 70(4), 461-470.
  • 27. Pu, S.; Shiraishi N. Journal -Japan Wood Research Society, 1993, 39, 446-452.
  • 28.Fidan, M.S., and Ertaş, M., Bioresorces, 2020, 15(3), 6061-6079.
  • 29.Pu, S., and Shiraishi N. Journal of the Japan Wood Research Society, 1994, 40.8: 824-829.
  • 30.Yao, Y.; Yoshioka, M.; Shiraishi, N. J. Appl Polym Sci 1996, 60(11), 1939-1949.
  • 31.Pu, S., and Shiraishi N. Journal of the Japan Wood Research Society, 1994, 40.8: 824-829.
  • 32.Wang, M.; Zhang, X.; Zhang W.; Tian, D.; Lu, C. Journal of applied polymer science, 2013, 128.6: 3555-3563.
  • 33.Chen, Fangeng, and Zhuomin Lu. Journal of Applied Polymer Science, 2009, 111.1: 508-516.
  • 34. Xie, J.; Zhai, X.; Hse, C. Y.; Shupe, T. F.; Pan, H. Materials, 2015, 8.12: 8496-8509. 35. Hakim A.A.A., Nassar M., Emam A., Sultan M. Material Chemistry and Physics, 2011, 129.1-1: 301-307.
  • 36.Huang, X. Y.; Qi, J. Q.; Hoop, C. F.; Xie, J. L.; Chen, Y. Z. Bioresources, 2017a, 12(4): 8160-8179.
  • 37.Huang, X. Y.; Li, F.; Xie, J. L.; Hoop, C. F.; Hse, C. Y.; Qi, J. Q.; Xiao, H. Bioresources, 2017b, 12(1), 1968-1981.
  • 38.Wang,T.P.; Pang, H.; Zhang, L.; Chen, X.D.; Mao, Z.H. Chemical Engineering Research and Design, 2008, 86.4: 416-421.
  • 39.Wang, Y.; Tian H.; Zhang, L. Carbohydrate Polymers, 2010, 80.3: 665-671.
  • 40.Trovati, G.; Sanches, E.A.; Neto, S.C. Journal of Applied Polymer Science, 2010, 115.1: 263-268.
  • 41.Zou, J.; Zhang, F.; Huang, J.; Chang, P.R.; Su, Z.; Yu, J. Carbohydrate Polymers, 2011, 85.4: 824-831.
  • 42.Savelyev, Y.; Veselov, V.; Markovskaya, L.; Savelyeva, O.; Akhranovich, E.; Galatenko, N.; Robota, L.; Travinskaya, T. Materials Science and Engineering: C, 2014, 45: 127-135.
  • 43.Zhang, Y.; Leng, Y.; Zhu, M.; Fan, B.; Yan, R.; Wu, Q. Carbohydrate polymers, 2012, 88.4: 1208-1213.2012.
  • 44.Gürsoy, T., WA-XRD Analyzes of Different Kinds of Composite Filling Materials. in Fundamental Aspects of Engineering Sciences; Unal F., Akan A.E., Eds., Chapter 4, Iksad Publishing House: Ankara, 2019 pp. 79-101.

Year 2023, Volume: 7 Issue: 2, 204 - 214, 31.12.2023

Tülay Gürsoy M. Alma Ertuğrul Altuntaş Eyyüp Karaoğul

https://doi.org/10.32571/ijct.1368742

Abstract

Project Number

2013- FBE-D060

References

  • 1. http://pagev.org/poliuretanlar/ (accessed September 12, 2023)
  • 2.http://emagen.gov.tr/poliuretan-nedir/ (accessed September 12, 2023)
  • 3.Hu, S.; Li, Y.; Industrial Crops and Products. 2014, 57, 188-194.
  • 4.Philips, L. N., and Parker, D. B. V. (1965). Polyurethanes Chemistry, Technology and Properties. Ilife Books Ltd., London.
  • 5.Ferrigno, T.H. Rigid Plastics Foams. Second Edition. Reinhold Publishing Corp./ Chapman-Reinhold. Newyork, NY, 1967; p.146.
  • 6.Zheng, Z.; Pan, H.; Huang, Y.; Chung, Y. H.; Zhang, X.; Feng, H. The Open Materials Science Journal 2011, 5, 1-8.
  • 7.Guelcher, S. A.; Patel, V.; Gallagher, K. M.; Connolly, S.; Didier, J. E.; Doctor, J. S. 2006. Tissue Eng. 2006, 12(5): 1247-1259.
  • 8.Rai, M.; Yadav, A.; Gade, A. Biotechnol. Adv. 2009, 27(1):76-83.
  • 9.Lemos, V.A.; Santos, M.S.; Santos, E.S.; Santos, M.J.S.; dos Santos, W.N.L. Spectrochimica Acta Part B, 2007, 62, 4-12.
  • 10.http://kimpur.com/tr/poliuretan-nedir/ (accessed September 12, 2023)
  • 11.Luo, X.; Hu, S.; Zhang, X.; Li, Y. Bioresource Technology. 2013, 139(2013): 323-329.
  • 12.Serrano, L.; Rincon, E.; Rodriguez, J.; Briones, R. Polymers. 2020, 12, 1-13.
  • 13.Zhang, Q.; Lin, X.; Chen, W.; Zhang, H.; Han, D. Polymers. 2020, 12(107):1-10.
  • 14. Furtwengler, P.; Averous, L. Polymer Chemistry. 2018, 32, 4253-4318.
  • 15.Ma, Y.; Xiao, Y.; Zhao, Y.; Bei, Y.; Hu, L.; Zhou, Y.; Jia, P. Reactive and Functional Polymers, 2022, 175, 105285.
  • 16.Briones, R.; Serrano, L.; Labidi, J. J. Chem. Technol. Biotechnol. 2012, 87, 244-249.
  • 17.Lee, S.H.; Yoshioka, M.; Shiraishi, N. J.Appl. Polym. Sci. 2000, 78, 319-325.
  • 18.Ge, J.; Zhang, W.; Li, W.; Sakai, K. Journal of Applied Polymer Science, 2000, 77, 2575-2580.
  • 19.Zlatic, A.; Lava, C.; Zhang, W.; Petrovic, Z.S. J.Polym. Sci. Polym. Phys. 2004, 42, 809-819.
  • 20.Walfson, A.; Litvak, G.; Dlugy, C.; Shotland, Y.; Tavor, D. Int. Crop. Prod. 2009, 30, 80-81
  • 21.http://www.ozcankimya.com/detay.phd?id=71 (accessed September 12, 2023)
  • 22.Alma, M. H.; Baştürk M. A.; Dıgrak, M. Journal of Materials Letters. 2003, 22, 1225-1228.
  • 23.Yamada, T. Mokuzai Gakkaishi, 1996, 42: 1098-1104.
  • 24.Ugarte, L.; Saralegi, A.; Fernandez, R.; Martin, L.; Corcuera, M.A.; Eceiza, A. Industrial Crops and Products, 2014, 62: 545-551.
  • 25.Goheen, M.S.; Wool, R.P. J. Appl. Polym. Sci. 1991, 42(10): 2691-2701.
  • 26.Pan, H.; Zheng, Z.; Chung, Y. H. Eur. J. Wood and Wood Prod. 2011, 70(4), 461-470.
  • 27. Pu, S.; Shiraishi N. Journal -Japan Wood Research Society, 1993, 39, 446-452.
  • 28.Fidan, M.S., and Ertaş, M., Bioresorces, 2020, 15(3), 6061-6079.
  • 29.Pu, S., and Shiraishi N. Journal of the Japan Wood Research Society, 1994, 40.8: 824-829.
  • 30.Yao, Y.; Yoshioka, M.; Shiraishi, N. J. Appl Polym Sci 1996, 60(11), 1939-1949.
  • 31.Pu, S., and Shiraishi N. Journal of the Japan Wood Research Society, 1994, 40.8: 824-829.
  • 32.Wang, M.; Zhang, X.; Zhang W.; Tian, D.; Lu, C. Journal of applied polymer science, 2013, 128.6: 3555-3563.
  • 33.Chen, Fangeng, and Zhuomin Lu. Journal of Applied Polymer Science, 2009, 111.1: 508-516.
  • 34. Xie, J.; Zhai, X.; Hse, C. Y.; Shupe, T. F.; Pan, H. Materials, 2015, 8.12: 8496-8509. 35. Hakim A.A.A., Nassar M., Emam A., Sultan M. Material Chemistry and Physics, 2011, 129.1-1: 301-307.
  • 36.Huang, X. Y.; Qi, J. Q.; Hoop, C. F.; Xie, J. L.; Chen, Y. Z. Bioresources, 2017a, 12(4): 8160-8179.
  • 37.Huang, X. Y.; Li, F.; Xie, J. L.; Hoop, C. F.; Hse, C. Y.; Qi, J. Q.; Xiao, H. Bioresources, 2017b, 12(1), 1968-1981.
  • 38.Wang,T.P.; Pang, H.; Zhang, L.; Chen, X.D.; Mao, Z.H. Chemical Engineering Research and Design, 2008, 86.4: 416-421.
  • 39.Wang, Y.; Tian H.; Zhang, L. Carbohydrate Polymers, 2010, 80.3: 665-671.
  • 40.Trovati, G.; Sanches, E.A.; Neto, S.C. Journal of Applied Polymer Science, 2010, 115.1: 263-268.
  • 41.Zou, J.; Zhang, F.; Huang, J.; Chang, P.R.; Su, Z.; Yu, J. Carbohydrate Polymers, 2011, 85.4: 824-831.
  • 42.Savelyev, Y.; Veselov, V.; Markovskaya, L.; Savelyeva, O.; Akhranovich, E.; Galatenko, N.; Robota, L.; Travinskaya, T. Materials Science and Engineering: C, 2014, 45: 127-135.
  • 43.Zhang, Y.; Leng, Y.; Zhu, M.; Fan, B.; Yan, R.; Wu, Q. Carbohydrate polymers, 2012, 88.4: 1208-1213.2012.
  • 44.Gürsoy, T., WA-XRD Analyzes of Different Kinds of Composite Filling Materials. in Fundamental Aspects of Engineering Sciences; Unal F., Akan A.E., Eds., Chapter 4, Iksad Publishing House: Ankara, 2019 pp. 79-101.
There are 43 citations in total.

Details

Primary Language English
Subjects Chemical Engineering (Other)
Journal Section Research Articles
Authors

Tülay Gürsoy 0000-0001-6166-6875

M. Alma 0000-0001-6323-7230

Ertuğrul Altuntaş 0000-0003-2840-0703

Eyyüp Karaoğul 0000-0001-8162-6838

Project Number 2013- FBE-D060
Early Pub Date November 28, 2023
Publication Date December 31, 2023
Published in Issue Year 2023 Volume: 7 Issue: 2

Cite

APA Gürsoy, T., Alma, M., Altuntaş, E., Karaoğul, E. (2023). Preparation and characterization of potato crust-based polyurethane foam-I. International Journal of Chemistry and Technology, 7(2), 204-214. https://doi.org/10.32571/ijct.1368742
AMA Gürsoy T, Alma M, Altuntaş E, Karaoğul E. Preparation and characterization of potato crust-based polyurethane foam-I. Int. J. Chem. Technol. December 2023;7(2):204-214. doi:10.32571/ijct.1368742
Chicago Gürsoy, Tülay, M. Alma, Ertuğrul Altuntaş, and Eyyüp Karaoğul. “Preparation and Characterization of Potato Crust-Based Polyurethane Foam-I”. International Journal of Chemistry and Technology 7, no. 2 (December 2023): 204-14. https://doi.org/10.32571/ijct.1368742.
EndNote Gürsoy T, Alma M, Altuntaş E, Karaoğul E (December 1, 2023) Preparation and characterization of potato crust-based polyurethane foam-I. International Journal of Chemistry and Technology 7 2 204–214.
IEEE T. Gürsoy, M. Alma, E. Altuntaş, and E. Karaoğul, “Preparation and characterization of potato crust-based polyurethane foam-I”, Int. J. Chem. Technol., vol. 7, no. 2, pp. 204–214, 2023, doi: 10.32571/ijct.1368742.
ISNAD Gürsoy, Tülay et al. “Preparation and Characterization of Potato Crust-Based Polyurethane Foam-I”. International Journal of Chemistry and Technology 7/2 (December 2023), 204-214. https://doi.org/10.32571/ijct.1368742.
JAMA Gürsoy T, Alma M, Altuntaş E, Karaoğul E. Preparation and characterization of potato crust-based polyurethane foam-I. Int. J. Chem. Technol. 2023;7:204–214.
MLA Gürsoy, Tülay et al. “Preparation and Characterization of Potato Crust-Based Polyurethane Foam-I”. International Journal of Chemistry and Technology, vol. 7, no. 2, 2023, pp. 204-1, doi:10.32571/ijct.1368742.
Vancouver Gürsoy T, Alma M, Altuntaş E, Karaoğul E. Preparation and characterization of potato crust-based polyurethane foam-I. Int. J. Chem. Technol. 2023;7(2):204-1.

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