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Photoluminescence properties of azo-containing Schiff Bases metal complexes

Year 2015, Volume: 18 Issue: 2, 49 - 53, 24.12.2015

Abstract

The Schiff base ligand containing -N=N- group, 4-((E)-(4-bromophenyl)diazenyl)-2-((E)-(phenylimino)methyl)phenol (L1H) (Fig. 1), and its CoII, CuII, NiII, ZnII and FeIII complexes have been prepared and characterized in previous study. According to analytical, UV-visible and IR data, the metal complexes are formed by coordination of the N, O atoms of the ligands and metal:ligand ratio was found to 1:2 for all the complexes. In this study, photoluminescence properties of L1H and its metal complexes were investigated.

References

  • Shaghaghi, Z., (2014), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Spectrochim Acta A, 131, 67.
  • Atabey, H., Findik, E., Sari, H., Ceylan, M., (2014), “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 38(1), 109.
  • Huang, D. X., Wang, C. X., Song, Y. B., (2013), “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 83(12), 2361.
  • Farhadi. S., Sepahvand, S., (2010), “Na4W10O32/ZrO2 nanocomposite prepared via a sol-gel route: A novel, green and recoverable photocatalyst for reductive cleavage of azobenzenes to amines with 2-propanol”, J Mol Catal A-Chem., 318(1-2), 75.
  • Govindaswamy. P., Sinha. C., Kollipara. M. R., (2005), “Syntheses and characterization of eta(5)cyclopentadienyl and eta(5)-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(eta(5)C5H5)Ru(PPh3)(C6H5-N=N-C3H3N2)]”, J Organomet Chem., 690(14), 3465.
  • Shinar, J., (Ed.), Organic Light-Emitting Devices: A Survey, Springer-Verlag, NY, 2004.
  • Hens, A., Mondal, P., Rajak, K. K., (2015), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Polyhedron, 85, 255.
  • Wang, J., Ha, C.-S., (2010), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Tetrahedron, 66, 1846.
  • Cheng, Y.-F., Zhao, D.-T., Zhang, M., Liu, Z.-Q., Zhou, Y.-F., Shu, T.-M., Li, F.-Y., Yi, T., Huang, C.-H., (2006), “Azo 8-hydroxyquinoline benzoate as selective chromogenic chemosensor for Hg2+ and Cu2+”, Tetrahedron Lett., 47, 6413.
  • A. Misra, M. Shahid, J. Phys. Chem., (2010), “Molecular Dynamics of Phycocyanobilin Binding Bacteriophytochromes: A Detailed Study of Structural and Dynamic Properties”, 114, 16726.
  • M. Kumar, J. Nagendra Babu, V. Bhalla, A. Dhir, (2009), Inorg. Chem. Commun., “Chromogenic sensing of Cu(II) by imino linked thiacalix[4]arene in mixed aqueous environment”, 12, 332.
  • Lou, X., Qin, J., Li, Z., (2009), “Colorimetric cyanide detection using an azobenzene acid in aqueous solutions”, Analyst, 134, 2071.
  • Arabahmadi, R., Orojloo, M., Amani, S., (2014), “Qualitative discrimination between organic and biodynamic Sangiovese red wines for authenticity”, Anal. Methods, 6, 7384.
  • Gunnlaugsson, T., Leonard, J. P., (2002), “Synthesis and evaluation of colorimetric chemosensors for monitoring sodium and potassium ions in the intracellular concentration range”, J. Chem. Soc., Perkin Trans., 2,1980.
  • Arabahmadi, R., Amani, S., (2013), “Synthesis and studies of selective chemosensors for anions and cations by azo-containing salicylaldiminebased receptors”, J. Coord. Chem. 66 218.
  • İkiz, M., İspir, E., Aytar, E., Karabuğa, Ş., Aslantaş, M., Çelik, Ö., Ulusoy, M., (2015), “Chemical fixation of CO2 into Cyclic Carbonates by azo-containing Schiff Bases metal complexes”, New Journal of Chemistry, 39(10), 7786.
  • Odabasoglu M, Albayrak C, Ozkanca R, Aykan FZ, Lonecke P. Some polyhydroxy azoazomethine derivatives of salicylaldehyde: Synthesis, characterization, spectroscopic, molecular structure and antimicrobial activity studies. J Mol Struct. 2007;840(1-3):71-89.
  • Ceyhan, G., Köse, M., Tümer, M., McKee, V., (2012), “Novel polymeric potassium complex: Its synthesis, structural characterization, photoluminescence and electrochemical properties”, J of Lumin, 132(3), 850.

Azo Grubu İçeren Schiff Baz Metal Komplekslerinin Fotolüminesans Özellikleri

Year 2015, Volume: 18 Issue: 2, 49 - 53, 24.12.2015

Abstract

Daha önceki çalışmada 4-((E)-(4-bromophenyl)diazenyl)-2-((E)-(phenylimino)methyl)phenol (L1H) ligandı ve bu ligamndın CoII, CuII, NiII, ZnII ve FeIII komplekslerinin sentezi ve karakterizasyonu yapılmış olup komplekslerin metal:ligand oranı 1:2 olacak şekilde oluştuğu gözlenmiştir. Bu çalışmada sentezi ve karakterizasyonu yapılan ligand ve komplekslerinin fotolüminesans özellikleri incelenmiştir

References

  • Shaghaghi, Z., (2014), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Spectrochim Acta A, 131, 67.
  • Atabey, H., Findik, E., Sari, H., Ceylan, M., (2014), “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 38(1), 109.
  • Huang, D. X., Wang, C. X., Song, Y. B., (2013), “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 83(12), 2361.
  • Farhadi. S., Sepahvand, S., (2010), “Na4W10O32/ZrO2 nanocomposite prepared via a sol-gel route: A novel, green and recoverable photocatalyst for reductive cleavage of azobenzenes to amines with 2-propanol”, J Mol Catal A-Chem., 318(1-2), 75.
  • Govindaswamy. P., Sinha. C., Kollipara. M. R., (2005), “Syntheses and characterization of eta(5)cyclopentadienyl and eta(5)-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(eta(5)C5H5)Ru(PPh3)(C6H5-N=N-C3H3N2)]”, J Organomet Chem., 690(14), 3465.
  • Shinar, J., (Ed.), Organic Light-Emitting Devices: A Survey, Springer-Verlag, NY, 2004.
  • Hens, A., Mondal, P., Rajak, K. K., (2015), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Polyhedron, 85, 255.
  • Wang, J., Ha, C.-S., (2010), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Tetrahedron, 66, 1846.
  • Cheng, Y.-F., Zhao, D.-T., Zhang, M., Liu, Z.-Q., Zhou, Y.-F., Shu, T.-M., Li, F.-Y., Yi, T., Huang, C.-H., (2006), “Azo 8-hydroxyquinoline benzoate as selective chromogenic chemosensor for Hg2+ and Cu2+”, Tetrahedron Lett., 47, 6413.
  • A. Misra, M. Shahid, J. Phys. Chem., (2010), “Molecular Dynamics of Phycocyanobilin Binding Bacteriophytochromes: A Detailed Study of Structural and Dynamic Properties”, 114, 16726.
  • M. Kumar, J. Nagendra Babu, V. Bhalla, A. Dhir, (2009), Inorg. Chem. Commun., “Chromogenic sensing of Cu(II) by imino linked thiacalix[4]arene in mixed aqueous environment”, 12, 332.
  • Lou, X., Qin, J., Li, Z., (2009), “Colorimetric cyanide detection using an azobenzene acid in aqueous solutions”, Analyst, 134, 2071.
  • Arabahmadi, R., Orojloo, M., Amani, S., (2014), “Qualitative discrimination between organic and biodynamic Sangiovese red wines for authenticity”, Anal. Methods, 6, 7384.
  • Gunnlaugsson, T., Leonard, J. P., (2002), “Synthesis and evaluation of colorimetric chemosensors for monitoring sodium and potassium ions in the intracellular concentration range”, J. Chem. Soc., Perkin Trans., 2,1980.
  • Arabahmadi, R., Amani, S., (2013), “Synthesis and studies of selective chemosensors for anions and cations by azo-containing salicylaldiminebased receptors”, J. Coord. Chem. 66 218.
  • İkiz, M., İspir, E., Aytar, E., Karabuğa, Ş., Aslantaş, M., Çelik, Ö., Ulusoy, M., (2015), “Chemical fixation of CO2 into Cyclic Carbonates by azo-containing Schiff Bases metal complexes”, New Journal of Chemistry, 39(10), 7786.
  • Odabasoglu M, Albayrak C, Ozkanca R, Aykan FZ, Lonecke P. Some polyhydroxy azoazomethine derivatives of salicylaldehyde: Synthesis, characterization, spectroscopic, molecular structure and antimicrobial activity studies. J Mol Struct. 2007;840(1-3):71-89.
  • Ceyhan, G., Köse, M., Tümer, M., McKee, V., (2012), “Novel polymeric potassium complex: Its synthesis, structural characterization, photoluminescence and electrochemical properties”, J of Lumin, 132(3), 850.
There are 18 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Mesut İkiz

Gökhan Ceyhan

Esin İspir

Publication Date December 24, 2015
Submission Date December 23, 2015
Published in Issue Year 2015Volume: 18 Issue: 2

Cite

APA İkiz, M., Ceyhan, G., & İspir, E. (2015). Photoluminescence properties of azo-containing Schiff Bases metal complexes. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 18(2), 49-53. https://doi.org/10.17780/ksujes.08941