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ORGANİK ATIKLARDAN ÜRETİLEN KOMPOZİT BİR MODİFİYE BİYOKÖMÜR KULLANILARAK SULU ÇÖZELTİDEN SAFRANİN T GİDERİMİ

Year 2022, Volume: 25 Issue: 3, 237 - 248, 03.09.2022

Dilek Gümüş

https://doi.org/10.17780/ksujes.1097965

Abstract

Modern yaşamın ilgi çekici unsurlarından biri de renktir. Başta tekstil endüstrileri olmak üzere bir çok endüstri, farklı konsantrasyonlarda çeşitli boyalar içeren yüksek miktarda renkli atık su üretmektedir. Sağlık ve ekolojik kaygılara yol açan sentetik boyaların alıcı ortama verilmeden önce atıksulardan uzaklaştırılması gerekmektedir. Düşük maliyetli adsorbanlar elde edebilmek için atık malzemelerin kullanımı, atıksu arıtma maliyetlerinin azaltılmasına ve çevrenin korunmasına katkıda bulunduğu için araştırmalara konu olmaktadır. Bu çalışmada, kolayca temin edilebilen ve toksik olmayan organik üretilen aktive edilmiş kompozit bir biyokömür hazırlanarak Safranin T boyasının gideriminde adsorbent olarak kullanılmıştır. Kesikli sistemde gerçekleştirilen deneylerde adsorban miktarı (0,1-1 g/L), boya konsantrasyonu (10-50 mg/L), pH (5-9) ve temas süresi (0-360 dk) gibi en temel parametreler incelenmiştir. Dört farklı İzoterm ve dört farklı kinetik tartışılmıştır. Elde edilen verilerle Langmuir izoterm modeli ve sözde ikinci derece kinetik model daha iyi uyum sağlamıştır.

Keywords

adsorpsiyon biyokömür, asetik asit modifikasyon Safranin T

References

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  • Azimvand, J., Didehban, K., & Mirshokraie, S. A. (2018). Safranin-O removal from aqueous solutions using lignin nanoparticle-g-polyacrylic acid adsorbent: Synthesis, properties, and application. Adsorption Science & Technology, 36(7-8), 1422-1440. https://doi.org/10.1177/0263617418777836
  • Chien, S. H., & Clayton, W. R. (1980). Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Science Society of America Journal, 44(2), 265-268. https://doi.org/10.2136/sssaj1980.03615995004400020013x
  • Crini, G., Lichtfouse, E., Wilson, L. D., & Morin-Crini, N. (2019). Conventional and non-conventional adsorbents for wastewater treatment. Environmental Chemistry Letters, 17(1), 195-213. https://doi.org/10.1007/s10311-018-0786-8
  • Dubinin, M. M., Zaverina, E. D., & Radushkevich, L. V. (1947). Sorption and structure of active carbons. I. Adsorption of organic vapors. Zhurnal Fizicheskoi Khimii, 21(3), 151-162.
  • Freundlich HMF (1906) Over the adsorption in solution. J Phys chem 57: 385-471.
  • Gümüş, D. (2021, Şubat). Kav Mantarı (Fomes fomentarius L. ex Fr.) Kullanılarak Sulu Çözeltilerden Bazik Kırmızı 2 Boyasının Giderimi. Black Sea Summit 5th International Applied Science Congress, 27-35.
  • Hamzenejad Taghlidabad, R., Sepehr, E., Khodaverdiloo, H., Samadi, A., & Rasouli-Sadaghiani, M. H. (2020). Characterization of cadmium adsorption on two cost-effective biochars for water treatment. Arabian Journal of Geosciences, 13(12), 1-10. https://doi.org/10.1007/s12517-020-05477-6
  • Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochemistry 34(5): 451-465. https://doi.org/10.1016/S0032-9592(98)00112-5
  • Hu, H., Lin, C., Zhang, Y., Cai, X., Huang, Z., Chen, C., ... & Liang, J. (2019). Preparation of a Stable Nanoscale Manganese Residue-Derived FeS@ Starch-Derived Carbon Composite for the Adsorption of Safranine T. Nanomaterials, 9(6), 839. https://doi.org/10.3390/nano9060839
  • Hu, X., Xue, Y., Long, L., & Zhang, K. (2018). Characteristics and batch experiments of acid-and alkali-modified corncob biomass for nitrate removal from aqueous solution. Environmental Science and Pollution Research, 25(20), 19932-19940. https://doi.org/10.1007/s11356-018-2198-5
  • Lagergren SK (1898) About the theory of so-called adsorption of soluble substances. Sven. Vetenskapsakad. Handingarl 24: 1-39.
  • Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society 1918 40 (9), 1361-1403. https://doi.org/10.1021/ja02242a004
  • Li, R., Wang, J. J., Gaston, L. A., Zhou, B., Li, M., Xiao, R., ... & Zhang, X. (2018). An overview of carbothermal synthesis of metal–biochar composites for the removal of oxyanion contaminants from aqueous solution. Carbon, 129, 674-687. https://doi.org/10.1016/j.carbon.2017.12.070
  • Li, W., Xie, Z., Xue, S., Ye, H., Liu, M., Shi, W., & Liu, Y. (2021). Studies on the adsorption of dyes, Methylene blue, Safranin T, and Malachite green onto Polystyrene foam. Separation and Purification Technology, 276, 119435. https://doi.org/10.1016/j.seppur.2021.119435
  • Mašek, O., Budarin, V., Gronnow, M., Crombie, K., Brownsort, P., Fitzpatrick, E., & Hurst, P. (2013). Microwave and slow pyrolysis biochar—Comparison of physical and functional properties. Journal of Analytical and Applied Pyrolysis, 100, 41-48. https://doi.org/10.1016/j.jaap.2012.11.015
  • Mohammed, N. A., Abu-Zurayk, R. A., Hamadneh, I., & Al-Dujaili, A. H. (2018). Phenol adsorption on biochar prepared from the pine fruit shells: Equilibrium, kinetic and thermodynamics studies. Journal of environmental management, 226, 377-385. https://doi.org/10.1016/j.jenvman.2018.08.033
  • Novais, R. M., Caetano, A. P., Seabra, M. P., Labrincha, J. A., & Pullar, R. C. (2018). Extremely fast and efficient methylene blue adsorption using eco-friendly cork and paper waste-based activated carbon adsorbents. Journal of cleaner production, 197, 1137-1147. https://doi.org/10.1016/j.jclepro.2018.06.278
  • Samsami, S., Mohamadizaniani, M., Sarrafzadeh, M. H., Rene, E. R., & Firoozbahr, M. (2020). Recent advances in the treatment of dye-containing wastewater from textile industries: Overview and perspectives. Process safety and environmental protection, 143, 138-163. https://doi.org/10.1016/j.psep.2020.05.034
  • Sharafinia, S., Farrokhnia, A., & Ghasemian, E. (2021). Comparative Study of Adsorption of Safranin o by TiO2/Activated Carbon and Chitosan/TiO2/Activated Carbon Adsorbents. Physical Chemistry Research, 9(4), 605-621. https://doi.org/10.22036/PCR.2021.274568.1889
  • Shirvanimoghaddam, K., Czech, B., Abdikheibari, S., Brodie, G., Kończak, M., Krzyszczak, A., ... & Naebe, M. (2021). Microwave synthesis of biochar for environmental applications. Journal of Analytical and Applied Pyrolysis, 105415. https://doi.org/10.1016/j.jaap.2021.105415
  • Suleman, M., Zafar, M., Ahmed, A., Rashid, M. U., Hussain, S., Razzaq, A., ... & Park, Y. K. (2021). Castor Leaves-Based Biochar for Adsorption of Safranin from Textile Wastewater. Sustainability, 13(12), 6926. https://doi.org/10.3390/su13126926
  • Temkin MI (1941) Adsorption equilibrium and the kinetics of processes on nonhomogeneous surfaces and in the interaction between adsorbed molecules. Zhurnal Fiziche- skoi Khimii 15: 296-332.
  • Ugraskan, V., Isik, B., Yazici, O., & Cakar, F. (2022). Removal of Safranine T by a highly efficient adsorbent (Cotinus Coggygria leaves): Isotherms, kinetics, thermodynamics, and surface properties. Surfaces and Interfaces, 28, 101615. https://doi.org/10.1016/j.surfin.2021.101615
  • Wang, B., Gao, B., & Fang, J. (2017). Recent advances in engineered biochar productions and applications. Critical reviews in environmental science and technology, 47(22), 2158-2207. https://doi.org/10.1080/10643389.2017.1418580
  • Weber Jr, W. J., & Morris, J. C. (1963). Kinetics of adsorption on carbon from solution. Journal of the sanitary engineering division, 89(2), 31-59.
  • Zhou, Y., Lu, J., Zhou, Y., & Liu, Y. (2019). Recent advances for dyes removal using novel adsorbents: a review. Environmental pollution, 252, 352-365. https://doi.org/10.1016/j.envpol.2019.05.072

Year 2022, Volume: 25 Issue: 3, 237 - 248, 03.09.2022

Dilek Gümüş

https://doi.org/10.17780/ksujes.1097965

Abstract

References

  • Almarri, A. H. (2021). Chitosan composites for thionine dye adsorption. International Journal of Environmental Analytical Chemistry, 1-12.
  • Azimvand, J., Didehban, K., & Mirshokraie, S. A. (2018). Safranin-O removal from aqueous solutions using lignin nanoparticle-g-polyacrylic acid adsorbent: Synthesis, properties, and application. Adsorption Science & Technology, 36(7-8), 1422-1440. https://doi.org/10.1177/0263617418777836
  • Chien, S. H., & Clayton, W. R. (1980). Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Science Society of America Journal, 44(2), 265-268. https://doi.org/10.2136/sssaj1980.03615995004400020013x
  • Crini, G., Lichtfouse, E., Wilson, L. D., & Morin-Crini, N. (2019). Conventional and non-conventional adsorbents for wastewater treatment. Environmental Chemistry Letters, 17(1), 195-213. https://doi.org/10.1007/s10311-018-0786-8
  • Dubinin, M. M., Zaverina, E. D., & Radushkevich, L. V. (1947). Sorption and structure of active carbons. I. Adsorption of organic vapors. Zhurnal Fizicheskoi Khimii, 21(3), 151-162.
  • Freundlich HMF (1906) Over the adsorption in solution. J Phys chem 57: 385-471.
  • Gümüş, D. (2021, Şubat). Kav Mantarı (Fomes fomentarius L. ex Fr.) Kullanılarak Sulu Çözeltilerden Bazik Kırmızı 2 Boyasının Giderimi. Black Sea Summit 5th International Applied Science Congress, 27-35.
  • Hamzenejad Taghlidabad, R., Sepehr, E., Khodaverdiloo, H., Samadi, A., & Rasouli-Sadaghiani, M. H. (2020). Characterization of cadmium adsorption on two cost-effective biochars for water treatment. Arabian Journal of Geosciences, 13(12), 1-10. https://doi.org/10.1007/s12517-020-05477-6
  • Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochemistry 34(5): 451-465. https://doi.org/10.1016/S0032-9592(98)00112-5
  • Hu, H., Lin, C., Zhang, Y., Cai, X., Huang, Z., Chen, C., ... & Liang, J. (2019). Preparation of a Stable Nanoscale Manganese Residue-Derived FeS@ Starch-Derived Carbon Composite for the Adsorption of Safranine T. Nanomaterials, 9(6), 839. https://doi.org/10.3390/nano9060839
  • Hu, X., Xue, Y., Long, L., & Zhang, K. (2018). Characteristics and batch experiments of acid-and alkali-modified corncob biomass for nitrate removal from aqueous solution. Environmental Science and Pollution Research, 25(20), 19932-19940. https://doi.org/10.1007/s11356-018-2198-5
  • Lagergren SK (1898) About the theory of so-called adsorption of soluble substances. Sven. Vetenskapsakad. Handingarl 24: 1-39.
  • Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society 1918 40 (9), 1361-1403. https://doi.org/10.1021/ja02242a004
  • Li, R., Wang, J. J., Gaston, L. A., Zhou, B., Li, M., Xiao, R., ... & Zhang, X. (2018). An overview of carbothermal synthesis of metal–biochar composites for the removal of oxyanion contaminants from aqueous solution. Carbon, 129, 674-687. https://doi.org/10.1016/j.carbon.2017.12.070
  • Li, W., Xie, Z., Xue, S., Ye, H., Liu, M., Shi, W., & Liu, Y. (2021). Studies on the adsorption of dyes, Methylene blue, Safranin T, and Malachite green onto Polystyrene foam. Separation and Purification Technology, 276, 119435. https://doi.org/10.1016/j.seppur.2021.119435
  • Mašek, O., Budarin, V., Gronnow, M., Crombie, K., Brownsort, P., Fitzpatrick, E., & Hurst, P. (2013). Microwave and slow pyrolysis biochar—Comparison of physical and functional properties. Journal of Analytical and Applied Pyrolysis, 100, 41-48. https://doi.org/10.1016/j.jaap.2012.11.015
  • Mohammed, N. A., Abu-Zurayk, R. A., Hamadneh, I., & Al-Dujaili, A. H. (2018). Phenol adsorption on biochar prepared from the pine fruit shells: Equilibrium, kinetic and thermodynamics studies. Journal of environmental management, 226, 377-385. https://doi.org/10.1016/j.jenvman.2018.08.033
  • Novais, R. M., Caetano, A. P., Seabra, M. P., Labrincha, J. A., & Pullar, R. C. (2018). Extremely fast and efficient methylene blue adsorption using eco-friendly cork and paper waste-based activated carbon adsorbents. Journal of cleaner production, 197, 1137-1147. https://doi.org/10.1016/j.jclepro.2018.06.278
  • Samsami, S., Mohamadizaniani, M., Sarrafzadeh, M. H., Rene, E. R., & Firoozbahr, M. (2020). Recent advances in the treatment of dye-containing wastewater from textile industries: Overview and perspectives. Process safety and environmental protection, 143, 138-163. https://doi.org/10.1016/j.psep.2020.05.034
  • Sharafinia, S., Farrokhnia, A., & Ghasemian, E. (2021). Comparative Study of Adsorption of Safranin o by TiO2/Activated Carbon and Chitosan/TiO2/Activated Carbon Adsorbents. Physical Chemistry Research, 9(4), 605-621. https://doi.org/10.22036/PCR.2021.274568.1889
  • Shirvanimoghaddam, K., Czech, B., Abdikheibari, S., Brodie, G., Kończak, M., Krzyszczak, A., ... & Naebe, M. (2021). Microwave synthesis of biochar for environmental applications. Journal of Analytical and Applied Pyrolysis, 105415. https://doi.org/10.1016/j.jaap.2021.105415
  • Suleman, M., Zafar, M., Ahmed, A., Rashid, M. U., Hussain, S., Razzaq, A., ... & Park, Y. K. (2021). Castor Leaves-Based Biochar for Adsorption of Safranin from Textile Wastewater. Sustainability, 13(12), 6926. https://doi.org/10.3390/su13126926
  • Temkin MI (1941) Adsorption equilibrium and the kinetics of processes on nonhomogeneous surfaces and in the interaction between adsorbed molecules. Zhurnal Fiziche- skoi Khimii 15: 296-332.
  • Ugraskan, V., Isik, B., Yazici, O., & Cakar, F. (2022). Removal of Safranine T by a highly efficient adsorbent (Cotinus Coggygria leaves): Isotherms, kinetics, thermodynamics, and surface properties. Surfaces and Interfaces, 28, 101615. https://doi.org/10.1016/j.surfin.2021.101615
  • Wang, B., Gao, B., & Fang, J. (2017). Recent advances in engineered biochar productions and applications. Critical reviews in environmental science and technology, 47(22), 2158-2207. https://doi.org/10.1080/10643389.2017.1418580
  • Weber Jr, W. J., & Morris, J. C. (1963). Kinetics of adsorption on carbon from solution. Journal of the sanitary engineering division, 89(2), 31-59.
  • Zhou, Y., Lu, J., Zhou, Y., & Liu, Y. (2019). Recent advances for dyes removal using novel adsorbents: a review. Environmental pollution, 252, 352-365. https://doi.org/10.1016/j.envpol.2019.05.072
There are 27 citations in total.

Details

Primary Language Turkish
Subjects Environmental Engineering
Journal Section Environmental Engineering
Authors

Dilek Gümüş 0000-0001-7665-3057

Publication Date September 3, 2022
Submission Date April 3, 2022
Published in Issue Year 2022Volume: 25 Issue: 3

Cite

APA Gümüş, D. (2022). ORGANİK ATIKLARDAN ÜRETİLEN KOMPOZİT BİR MODİFİYE BİYOKÖMÜR KULLANILARAK SULU ÇÖZELTİDEN SAFRANİN T GİDERİMİ. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 25(3), 237-248. https://doi.org/10.17780/ksujes.1097965
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