ORGANİK ATIKLARDAN ÜRETİLEN KOMPOZİT BİR MODİFİYE BİYOKÖMÜR KULLANILARAK SULU ÇÖZELTİDEN SAFRANİN T GİDERİMİ

Dilek Gümüş

doi:10.17780/ksujes.1097965

ORGANİK ATIKLARDAN ÜRETİLEN KOMPOZİT BİR MODİFİYE BİYOKÖMÜR KULLANILARAK SULU ÇÖZELTİDEN SAFRANİN T GİDERİMİ

Öz

Modern yaşamın ilgi çekici unsurlarından biri de renktir. Başta tekstil endüstrileri olmak üzere bir çok endüstri, farklı konsantrasyonlarda çeşitli boyalar içeren yüksek miktarda renkli atık su üretmektedir. Sağlık ve ekolojik kaygılara yol açan sentetik boyaların alıcı ortama verilmeden önce atıksulardan uzaklaştırılması gerekmektedir. Düşük maliyetli adsorbanlar elde edebilmek için atık malzemelerin kullanımı, atıksu arıtma maliyetlerinin azaltılmasına ve çevrenin korunmasına katkıda bulunduğu için araştırmalara konu olmaktadır. Bu çalışmada, kolayca temin edilebilen ve toksik olmayan organik üretilen aktive edilmiş kompozit bir biyokömür hazırlanarak Safranin T boyasının gideriminde adsorbent olarak kullanılmıştır. Kesikli sistemde gerçekleştirilen deneylerde adsorban miktarı (0,1-1 g/L), boya konsantrasyonu (10-50 mg/L), pH (5-9) ve temas süresi (0-360 dk) gibi en temel parametreler incelenmiştir. Dört farklı İzoterm ve dört farklı kinetik tartışılmıştır. Elde edilen verilerle Langmuir izoterm modeli ve sözde ikinci derece kinetik model daha iyi uyum sağlamıştır.

Anahtar Kelimeler

Kaynakça

Almarri, A. H. (2021). Chitosan composites for thionine dye adsorption. International Journal of Environmental Analytical Chemistry, 1-12.
Azimvand, J., Didehban, K., & Mirshokraie, S. A. (2018). Safranin-O removal from aqueous solutions using lignin nanoparticle-g-polyacrylic acid adsorbent: Synthesis, properties, and application. Adsorption Science & Technology, 36(7-8), 1422-1440. https://doi.org/10.1177/0263617418777836
Chien, S. H., & Clayton, W. R. (1980). Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Science Society of America Journal, 44(2), 265-268. https://doi.org/10.2136/sssaj1980.03615995004400020013x
Crini, G., Lichtfouse, E., Wilson, L. D., & Morin-Crini, N. (2019). Conventional and non-conventional adsorbents for wastewater treatment. Environmental Chemistry Letters, 17(1), 195-213. https://doi.org/10.1007/s10311-018-0786-8
Dubinin, M. M., Zaverina, E. D., & Radushkevich, L. V. (1947). Sorption and structure of active carbons. I. Adsorption of organic vapors. Zhurnal Fizicheskoi Khimii, 21(3), 151-162.
Freundlich HMF (1906) Over the adsorption in solution. J Phys chem 57: 385-471.
Gümüş, D. (2021, Şubat). Kav Mantarı (Fomes fomentarius L. ex Fr.) Kullanılarak Sulu Çözeltilerden Bazik Kırmızı 2 Boyasının Giderimi. Black Sea Summit 5th International Applied Science Congress, 27-35.
Hamzenejad Taghlidabad, R., Sepehr, E., Khodaverdiloo, H., Samadi, A., & Rasouli-Sadaghiani, M. H. (2020). Characterization of cadmium adsorption on two cost-effective biochars for water treatment. Arabian Journal of Geosciences, 13(12), 1-10. https://doi.org/10.1007/s12517-020-05477-6

Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochemistry 34(5): 451-465. https://doi.org/10.1016/S0032-9592(98)00112-5
Hu, H., Lin, C., Zhang, Y., Cai, X., Huang, Z., Chen, C., ... & Liang, J. (2019). Preparation of a Stable Nanoscale Manganese Residue-Derived FeS@ Starch-Derived Carbon Composite for the Adsorption of Safranine T. Nanomaterials, 9(6), 839. https://doi.org/10.3390/nano9060839
Hu, X., Xue, Y., Long, L., & Zhang, K. (2018). Characteristics and batch experiments of acid-and alkali-modified corncob biomass for nitrate removal from aqueous solution. Environmental Science and Pollution Research, 25(20), 19932-19940. https://doi.org/10.1007/s11356-018-2198-5
Lagergren SK (1898) About the theory of so-called adsorption of soluble substances. Sven. Vetenskapsakad. Handingarl 24: 1-39.
Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society 1918 40 (9), 1361-1403. https://doi.org/10.1021/ja02242a004
Li, R., Wang, J. J., Gaston, L. A., Zhou, B., Li, M., Xiao, R., ... & Zhang, X. (2018). An overview of carbothermal synthesis of metal–biochar composites for the removal of oxyanion contaminants from aqueous solution. Carbon, 129, 674-687. https://doi.org/10.1016/j.carbon.2017.12.070
Li, W., Xie, Z., Xue, S., Ye, H., Liu, M., Shi, W., & Liu, Y. (2021). Studies on the adsorption of dyes, Methylene blue, Safranin T, and Malachite green onto Polystyrene foam. Separation and Purification Technology, 276, 119435. https://doi.org/10.1016/j.seppur.2021.119435
Mašek, O., Budarin, V., Gronnow, M., Crombie, K., Brownsort, P., Fitzpatrick, E., & Hurst, P. (2013). Microwave and slow pyrolysis biochar—Comparison of physical and functional properties. Journal of Analytical and Applied Pyrolysis, 100, 41-48. https://doi.org/10.1016/j.jaap.2012.11.015
Mohammed, N. A., Abu-Zurayk, R. A., Hamadneh, I., & Al-Dujaili, A. H. (2018). Phenol adsorption on biochar prepared from the pine fruit shells: Equilibrium, kinetic and thermodynamics studies. Journal of environmental management, 226, 377-385. https://doi.org/10.1016/j.jenvman.2018.08.033
Novais, R. M., Caetano, A. P., Seabra, M. P., Labrincha, J. A., & Pullar, R. C. (2018). Extremely fast and efficient methylene blue adsorption using eco-friendly cork and paper waste-based activated carbon adsorbents. Journal of cleaner production, 197, 1137-1147. https://doi.org/10.1016/j.jclepro.2018.06.278
Samsami, S., Mohamadizaniani, M., Sarrafzadeh, M. H., Rene, E. R., & Firoozbahr, M. (2020). Recent advances in the treatment of dye-containing wastewater from textile industries: Overview and perspectives. Process safety and environmental protection, 143, 138-163. https://doi.org/10.1016/j.psep.2020.05.034
Sharafinia, S., Farrokhnia, A., & Ghasemian, E. (2021). Comparative Study of Adsorption of Safranin o by TiO2/Activated Carbon and Chitosan/TiO2/Activated Carbon Adsorbents. Physical Chemistry Research, 9(4), 605-621. https://doi.org/10.22036/PCR.2021.274568.1889
Shirvanimoghaddam, K., Czech, B., Abdikheibari, S., Brodie, G., Kończak, M., Krzyszczak, A., ... & Naebe, M. (2021). Microwave synthesis of biochar for environmental applications. Journal of Analytical and Applied Pyrolysis, 105415. https://doi.org/10.1016/j.jaap.2021.105415
Suleman, M., Zafar, M., Ahmed, A., Rashid, M. U., Hussain, S., Razzaq, A., ... & Park, Y. K. (2021). Castor Leaves-Based Biochar for Adsorption of Safranin from Textile Wastewater. Sustainability, 13(12), 6926. https://doi.org/10.3390/su13126926
Temkin MI (1941) Adsorption equilibrium and the kinetics of processes on nonhomogeneous surfaces and in the interaction between adsorbed molecules. Zhurnal Fiziche- skoi Khimii 15: 296-332.
Ugraskan, V., Isik, B., Yazici, O., & Cakar, F. (2022). Removal of Safranine T by a highly efficient adsorbent (Cotinus Coggygria leaves): Isotherms, kinetics, thermodynamics, and surface properties. Surfaces and Interfaces, 28, 101615. https://doi.org/10.1016/j.surfin.2021.101615
Wang, B., Gao, B., & Fang, J. (2017). Recent advances in engineered biochar productions and applications. Critical reviews in environmental science and technology, 47(22), 2158-2207. https://doi.org/10.1080/10643389.2017.1418580
Weber Jr, W. J., & Morris, J. C. (1963). Kinetics of adsorption on carbon from solution. Journal of the sanitary engineering division, 89(2), 31-59.
Zhou, Y., Lu, J., Zhou, Y., & Liu, Y. (2019). Recent advances for dyes removal using novel adsorbents: a review. Environmental pollution, 252, 352-365. https://doi.org/10.1016/j.envpol.2019.05.072

Ayrıntılar

Birincil Dil

Türkçe

Konular

Çevre Mühendisliği

Bölüm

Araştırma Makalesi

Yazarlar

Dilek Gümüş ^*
0000-0001-7665-3057
Türkiye

Yayımlanma Tarihi

3 Eylül 2022

Gönderilme Tarihi

3 Nisan 2022

Kabul Tarihi

8 Haziran 2022

Yayımlandığı Sayı

Yıl 2022 Cilt: 25 Sayı: 3

DOI

https://doi.org/10.17780/ksujes.1097965

IZ

https://izlik.org/JA37PE99RW

Kaynak Göster

RIS / Bibtex

APA

Gümüş, D. (2022). ORGANİK ATIKLARDAN ÜRETİLEN KOMPOZİT BİR MODİFİYE BİYOKÖMÜR KULLANILARAK SULU ÇÖZELTİDEN SAFRANİN T GİDERİMİ. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 25(3), 237-248. https://doi.org/10.17780/ksujes.1097965

Cited By

Typha latifolia ile Sulu Çözeltiden Kristal Viyole Boyasının Adsorpsiyonu; Doğrusal ve Doğrusal Olmayan İzoterm, Kinetik ve Dizayn

Karadeniz Fen Bilimleri Dergisi

https://doi.org/10.31466/kfbd.1548851