Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde

Cilt: 19 Sayı: 1 10 Mayıs 2016
PDF İndir
EN TR

Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde

Öz

The Schiff base ligand containing N,N donor atoms, (E)-4-(((pyridin-2-ylmethylene)amino)methyl)phenol (L1H) (Fig. 1), and its Ru(II) complex have been prepared. The ligand and its complex have been characterized by elemental analyses, IR spectra, UV-Visible spectroscopy, 1H and 13C NMR spectra and magnetic susceptibility measurements.  The analytical data show that the metal to ligand ratio in the L1H complexes is 1:1.

Anahtar Kelimeler

Kaynakça

  1. Ispir E. The synthesis, characterization, electrochemical character, catalytic and antimicrobial activity of novel, azo-containing Schiff bases and their metal complexes. Dyes Pigments. 2009; 82(1):13-9.
  2. Atabey, H., Findik, E., Sari, H., Ceylan, M., “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 2014, 38(1), 109.
  3. Huang, D. X., Wang, C. X., Song, Y. B., “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 2013, 83(12), 2361.
  4. Khandar. A. A.; Nejati, K. Synthesis And Characterization of a Series of Copper(II) Complexes With Azo-linked Salicylaldimine Schiff Base Ligands. Crystal Structure of Cu5PHAZOSALTN.
  5. CHCl3. Polyhedron. 2000, 19, 607-613.
  6. Tümer, M.; Çelik, C.; Köksal, H.; and Serin, S. Transition Metal Complexes of Bidentate Schiff Base Ligands. Trans. Met. Chem. 1999, 24, 525.
  7. J.L. Pratihar, S. Bhaduri, P. Pattanayak, D. Patra, S. Chattopadhyay, Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates, J Organomet Chem, 2009, 694,3401- 3408.
  8. R.N. Prabhu, R. Ramesh, Synthesis, structural characterization, electrochemistry and catalytic transfer hydrogenation of ruthenium(II) carbonyl complexes containing tridentate benzoylhydrazone ligands, J Organomet Chem, 2012, 718, 43-51.

Ayrıntılar

Birincil Dil

İngilizce

Konular

-

Bölüm

-

Yazarlar

Arif Aktaş

Yayımlanma Tarihi

10 Mayıs 2016

Gönderilme Tarihi

13 Nisan 2016

Kabul Tarihi

-

Yayımlandığı Sayı

Yıl 2016 Cilt: 19 Sayı: 1

Kaynak Göster

APA
İspir, E., & Aktaş, A. (2016). Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 19(1), 37-40. https://doi.org/10.17780/ksujes.73633
AMA
1.İspir E, Aktaş A. Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi. 2016;19(1):37-40. doi:10.17780/ksujes.73633
Chicago
İspir, Esin, ve Arif Aktaş. 2016. “Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde”. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi 19 (1): 37-40. https://doi.org/10.17780/ksujes.73633.
EndNote
İspir E, Aktaş A (01 Mayıs 2016) Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi 19 1 37–40.
IEEE
[1]E. İspir ve A. Aktaş, “Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde”, Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, c. 19, sy 1, ss. 37–40, May. 2016, doi: 10.17780/ksujes.73633.
ISNAD
İspir, Esin - Aktaş, Arif. “Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde”. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi 19/1 (01 Mayıs 2016): 37-40. https://doi.org/10.17780/ksujes.73633.
JAMA
1.İspir E, Aktaş A. Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi. 2016;19:37–40.
MLA
İspir, Esin, ve Arif Aktaş. “Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde”. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, c. 19, sy 1, Mayıs 2016, ss. 37-40, doi:10.17780/ksujes.73633.
Vancouver
1.Esin İspir, Arif Aktaş. Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi. 01 Mayıs 2016;19(1):37-40. doi:10.17780/ksujes.73633

DİZİNLENME ve ARŞİVLEME

download?token=eyJhdXRoX3JvbGVzIjpbXSwiZW5kcG9pbnQiOiJqb3VybmFsIiwib3JpZ2luYWxuYW1lIjoiaW1hZ2UucG5nIiwicGF0aCI6IjAzNTkvYmZjYS81YjQyLzY5ZjFkM2E4NWY2YWY3Ljg1NjQ2NDgxLnBuZyIsImV4cCI6MTc3NzQ1OTY0MCwibm9uY2UiOiI1NTUzYmJiN2U5NGNkMjdkYWNhMTRlMDZiYjc1OTY4NCJ9.nCVoSJClEIC9bWK5gGCmjHyTNRz2N0DhYKVJzJZR9Bs

 

download?token=eyJhdXRoX3JvbGVzIjpbXSwiZW5kcG9pbnQiOiJqb3VybmFsIiwib3JpZ2luYWxuYW1lIjoiaW1hZ2UucG5nIiwicGF0aCI6Ijg5YmUvODZlOC8wYzY0LzY5ZjFkNWE4MWJmYzY0LjM0OTM2NzM1LnBuZyIsImV4cCI6MTc3NzQ2MDE1Miwibm9uY2UiOiI3OWE1Mzk0OWRhMTk0Mjg0OGYzZTUxOWQyNTU5MjdjMSJ9.XxqhJ36woCZcO1DV_I9Mogpgg86-bwM454jQiOcqpS0 

Bu eser, Creative Commons Atıf 4.0 Uluslararası Lisansı ile lisanslanmıştır.