Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde

Cilt: 19 Sayı: 1 10 Mayıs 2016
Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi Kapak
Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi
PDF İndir
EN TR

Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde

Abstract

The Schiff base ligand containing N,N donor atoms, (E)-4-(((pyridin-2-ylmethylene)amino)methyl)phenol (L1H) (Fig. 1), and its Ru(II) complex have been prepared. The ligand and its complex have been characterized by elemental analyses, IR spectra, UV-Visible spectroscopy, 1H and 13C NMR spectra and magnetic susceptibility measurements.  The analytical data show that the metal to ligand ratio in the L1H complexes is 1:1.

Keywords

Kaynakça

  1. Ispir E. The synthesis, characterization, electrochemical character, catalytic and antimicrobial activity of novel, azo-containing Schiff bases and their metal complexes. Dyes Pigments. 2009; 82(1):13-9.
  2. Atabey, H., Findik, E., Sari, H., Ceylan, M., “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 2014, 38(1), 109.
  3. Huang, D. X., Wang, C. X., Song, Y. B., “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 2013, 83(12), 2361.
  4. Khandar. A. A.; Nejati, K. Synthesis And Characterization of a Series of Copper(II) Complexes With Azo-linked Salicylaldimine Schiff Base Ligands. Crystal Structure of Cu5PHAZOSALTN.
  5. CHCl3. Polyhedron. 2000, 19, 607-613.
  6. Tümer, M.; Çelik, C.; Köksal, H.; and Serin, S. Transition Metal Complexes of Bidentate Schiff Base Ligands. Trans. Met. Chem. 1999, 24, 525.
  7. J.L. Pratihar, S. Bhaduri, P. Pattanayak, D. Patra, S. Chattopadhyay, Reactions of 2-(arylazo)aniline with ruthenium substrates: Isolation, characterizations and reactivities of delocalized diazoketiminato and orthometallated Ru(II) chelates, J Organomet Chem, 2009, 694,3401- 3408.
  8. R.N. Prabhu, R. Ramesh, Synthesis, structural characterization, electrochemistry and catalytic transfer hydrogenation of ruthenium(II) carbonyl complexes containing tridentate benzoylhydrazone ligands, J Organomet Chem, 2012, 718, 43-51.

Ayrıntılar

Birincil Dil

İngilizce

Konular

-

Bölüm

-

Yazarlar

Arif Aktaş

Yayımlanma Tarihi

10 Mayıs 2016

Gönderilme Tarihi

13 Nisan 2016

Kabul Tarihi

-

Yayımlandığı Sayı

Yıl 2016 Cilt: 19 Sayı: 1

DOI

https://doi.org/10.17780/ksujes.73633

IZ

https://izlik.org/JA49FG59HW

Kaynak Göster

RIS / Bibtex
APA
İspir, E., & Aktaş, A. (2016). Synthesis and characterization of ruthenium (II) complexes with new Schiff base ligand from the reaction of 4-(aminomethyl)phenol with picolinaldehyde. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 19(1), 37-40. https://doi.org/10.17780/ksujes.73633