Araştırma Makalesi

Farklı İşletim Koşulları Altında Tiyosülfat Bazlı Ototrofik ve Miksotrofik Denitrifikasyon Performansının Araştırılması

Cilt: 20 Sayı: 4 27 Aralık 2017
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Evaluation of Thiosulfate-Based Autotrophic and Mixotrophic Denitrification Performances under Different Operational Conditions

Abstract

The aim of this study was to investigate the factors affecting the autotrophic and mixotrophic denitrification performances in sequencing batch reactor (SBR). Findings obtained from this study shed light on the full-scale applicability of the autotrophic and mixotrophic denitrification processes in carbon deficient wastewaters. In this study, the effect of cycle time, varying concentrations of electron donor source and the addition of external organic carbon source was evaluated by sulfate, nitrate, nitrite, ORP and inorganic carbon parameters. Firstly, SBR was operated with thiosulfate (S2O32-) based autotrophic denitrification process at different cycle times (8h-4h-2h). Further, autotrophic denitrification process was optimized the under varying S2O32-/NO3- ratios (1.5-1.25-1.0) at the optimum cycle time of 2h. The maximum nitrate removal efficiency of 84% was accomplished at operational conditions containing 2h cycle time and 1.5 S2O32-/NO3- ratio. In the rest of the study,the impact of increasing C/N ratio by methanol supplementation (0.35-0.7-1.05)was evaluated on mixotrophic denitrification performance. It was observed that nitrate was completely consumed at the C/N ratio of 1.05 and nitrate removal rate improved with increasing methanol supplementation as organic carbon source.

Keywords

Kaynakça

  1. Beller, H.R. (2005) “Anaerobic, nitrate-dependent oxidation of U(IV) oxide minerals by the chemolitotrophic bacterium Thiobacillusdenitrificans”, Appl. Environ. Microb., 71, 2170-2174.
  2. Campos, J. L.,Carvalho, S., Portela, R., Mosquera-Corral, A., &Méndez, R. (2008). Kinetics of denitrificationusingsulphurcompounds: effects of S/N ratio, endogenousandexogenouscompounds. Bioresourcetechnology, 99(5), 1293-1299.
  3. Guo, Y.,Guo, L., Sun, M., Zhao, Y., Gao, M., &She, Z. (2017). Effects of hydraulicretention time (HRT) on denitrificationusingwasteactivatedsludgethermalhydrolysisliquidandacidogenicliquid as carbonsources. Bioresourcetechnology, 224, 147-156.
  4. Liu, H., Jiang, W., Wan, D., Qu, J. (2009) “Study of a combined heterotrophicand sulfur autotrophic denitrification technology for removal of nitrate in water”, Journal of Haz Mat, 169, 23-28.
  5. Manconi, I., Carucci, A., Lens, P. (2007) “Combined removal of sulfur compound sand nitrate by autotrophic denitrification in bioaugmented activated sludge system”, Biotechnology and Bioengineering, 98 (3), 551-560.
  6. Moon, H.S., Shin, D.Y., Nam, K., Kim, J.Y. (2008) “A long-term performance test on an autotrophic denitrification column for application as a permeable reactive barrier”, Chemosphere, 73, 723-728.
  7. Oh, S.E., Yoo, Y.B., Young, J.C., Kim, I.S. (2001) “Effect of organics on sulfur-utilizing autotrophic denitrification under mixotrophic conditions”, J Biotechnol, 92,1-8.
  8. Sahinkaya, E.,&Kilic, A. (2014). Heterotrophicandelemental-sulfur-basedautotrophicdenitrificationprocessesforsimultaneousnitrateand Cr (VI) reduction. waterresearch, 50, 278-286.

Ayrıntılar

Birincil Dil

Türkçe

Konular

Çevre Mühendisliği

Bölüm

Araştırma Makalesi

Yazarlar

Vildan Akgul
Department of Bioengineering and Sciences, KahramanmarasSutcu Imam University, Kahramanmaras 46100, Turkey
Türkiye

Dilek Akman
Department of Environmental Engineering, KahramanmarasSutcu Imam University, Kahramanmaras 46100, Turkey
Türkiye

Yakup Cuci
Department of Environmental Engineering, KahramanmarasSutcu Imam University, Kahramanmaras 46100, Turkey
Türkiye

Kevser Cirik
Department of Environmental Engineering, KahramanmarasSutcu Imam University, Kahramanmaras 46100, Turkey
Türkiye

Yayımlanma Tarihi

27 Aralık 2017

Gönderilme Tarihi

24 Ağustos 2017

Kabul Tarihi

22 Kasım 2017

Yayımlandığı Sayı

Yıl 2017 Cilt: 20 Sayı: 4

Kaynak Göster

APA
Akgul, V., Akman, D., Cuci, Y., & Cirik, K. (2017). Farklı İşletim Koşulları Altında Tiyosülfat Bazlı Ototrofik ve Miksotrofik Denitrifikasyon Performansının Araştırılması. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 20(4), 81-89. https://doi.org/10.17780/ksujes.335996