EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER)

Büşra Nur Seven; Elif Utlu; Gizem Ceylan Türkoğlu; Gökhan Erkan; Gülşah Ekin Kartal

doi:10.17780/ksujes.1791729

EN TR

EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER)

Öz

This study examines the application of Rubia tinctorum L. (madder) as a natural dye in wool fabric printing, focusing on dyeing optimization and the effects of pre- and post-mordanting using various mordants. Wool fabrics were treated with iron(II) sulfate, alum, tannic acid, and tartaric acid before or after printing. For the printing process, the same mordants were used, with locust bean flour and gum arabic as thickeners. The impact of mordanting sequence (pre- vs. post-mordanting) on color yield and color fastness properties was analyzed to determine the optimal conditions for enhanced dye fixation and print quality. The results indicated that mordanting significantly enhanced color depth, with the highest color strength achieved through pre-mordanting with iron(II) sulfate. Natural mordants such as tannic and tartaric acids showed potential as effective alternatives to alum. Additionally, the color fastness to washing showed considerably high performance in terms of color change, although staining levels could be improved.

Anahtar Kelimeler

RUBIA TINCTORUM L. (KÖKBOYA) KULLANILARAK YAPILAN YÜNLÜ KUMAŞLARIN BASKISINDA FARKLI MORDANLARLA ÖN VE SON MORDANLAMANIN ETKİLERİ

Öz

Bu çalışmada, yünlü kumaş baskısında doğal boya olarak Rubia tinctorum L. (kök boya) uygulamasının, boyama optimizasyonunun ve çeşitli mordanlar kullanılarak yapılan ön ve son mordanlamanın etkileri üzerinde durulmuştur. Yünlü kumaşlar, baskıdan önce veya sonra demir(II) sülfat, şap, tannik asit ve tartarik asit ile işlem görmüştür. Baskı işlemi için, belirtilen mordanlar kıvamlaştırıcı olarak keçiboynuzu çekirdeği unu ve arap zamkı ile birlikte kullanılmıştır. Mordanlama sırasının (ön ve son mordanlama) renk verimi ve haslık özellikleri üzerindeki etkisi, geliştirilmiş boya fiksajı ve baskı kalitesi için en uygun koşulları belirlemek amacıyla analiz edilmiştir. Sonuçlar, mordanlamanın renk verimini önemli ölçüde artırdığını ve en yüksek renk veriminin demir(II) sülfat ile ön mordanlama yoluyla elde edildiğini göstermiştir. Tannik ve tartarik asitler gibi doğal mordanlar, şapa alternatif olabilecek potansiyele sahiptir. Ayrıca, yıkamaya karşı renk haslığı, renk değişimi açısından oldukça yüksek performans göstermiştir, ancak lekelenme konusunda geliştirmeye gerek duyulmaktadır.

Anahtar Kelimeler

Teşekkür

The authors gratefully acknowledge the Turkish Cultural Foundation Cultural Heritage Preservation and Natural Dyes Project Laboratory for supplying the ground Rubia tinctorum L. used in this study.

Kaynakça

Ali, M., Sarkar, A., Pandey, M. D., & Pandey, S. (2006). Efficient precipitation of dyes from dilute aqueous solutions of ionic liquids. Analytical Sciences, 22(8), 1051-1053. https://doi.org/10.2116/analsci.22.1051
Andriamanantena, M., Danthu, P., Cardon, D., Fawbush, F. R., Raonizafinimanana, B., Razafintsalama, V. E., ... & Caro, Y. (2019). Malagasy dye plant species: A promising source of novel natural colorants with potential applications–A review. Chemistry & Biodiversity, 16(12), e1900442. https://doi.org/10.1002/cbdv.201900442
Başaran, F. N., & Sarıkaya, H. (2015). Investigation of nutgall and some natural dyes with mordants cotton dyeing and fastness level in the context of the ecological textile production. International E-Journal of Advances in Social Sciences, 1(3), 452-459. https://doi.org/10.18769/ijasos.00057
Deveoglu, O., Sahinbaskan, B. Y., Torgan, E., & Karadag, R. (2012). Investigation on colour, fastness properties and HPLC‐DAD analysis of silk fibres dyed with Rubia tinctorium L. and Quercus ithaburensis Decaisne. Coloration Technology, 128(5), 364-370. https://doi.org/10.1111/j.1478-4408.2012.00389.x
Feiz, M., & Norouzi, H. (2014). Dyeing studies of wool fibers with madder (Rubia tinctorum) and effect of different mordants and mordanting procedures on color characteristics of dyed samples. Fibers and Polymers, 15(12), 2504-2514. https://doi.org/10.1007/s12221-014-2504-x
Ford, L., Rayner, C. M., & Blackburn, R. S. (2018). Comparative sorption isotherms for colorants present in Dyers’ madder (Rubia tinctorum L.) provide new insights into historical dyeing. Coloration Technology, 134(1), 3-12. https://doi.org/10.1111/cote.12327
Gandhi, P. D., & Shaikh, S. A. (2021). Biodegradation of Textile Dye Reactive Black GDN by Free Cells Isolated from Soil and Textile Effluents. International Journal of Current Microbiology and Applied Sciences, 10(04): 103–115. doi: https://doi.org/10.20546/ijcmas.2021.1004.010
Ghandehari, S., Tabrizi, M. H., Ardalan, P., Neamati, A., & Shali, R. (2019). Green synthesis of silver nanoparticles using Rubia tinctorum extract and evaluation the anti‐cancer properties in vitro. IET Nanobiotechnology, 13(3), 269-274. https://doi.org/10.1049/iet-nbt.2018.5190

Harmon, J. (2020, December). Investigating the Dyeing Potential of Bacterial Cellulose: Colorfastness to Crocking and Artificial Light. In International Textile and Apparel Association Annual Conference Proceedings (Vol. 77, No. 1). https://doi.org/10.31274/itaa.12165
Henderson, R. L., Rayner, C. M., & Blackburn, R. S. (2013). Isolation and extraction of lucidin primeveroside from Rubia tinctorum L. and crystal structure elucidation. Phytochemistry, 95, 105-108. https://doi.org /10.1016/j.phytochem.2013.07.001
Hosseinnezhad, M., Gharanjig, K., Rouhani, S., Razani, N., & Imani, H. (2022). Environmentally friendly dyeing of wool yarns using of combination of bio‐mordants and natural dyes. Environmental Progress & Sustainable Energy, 41(5), e13868. https://doi.org/10.1002/ep.13868
İşmal, Ö. E., & Yıldırım, L. (2019). Metal mordants and biomordants. In The impact and prospects of green chemistry for textile technology (pp. 57-82). Woodhead Publishing. https://doi.org/10.1016/B978-0-08-102491-1.00003-4
Khattab, T. A., & Rehan, M. (2018). A review on synthesis of nitrogen-containing heterocyclic dyes for textile fibers-Part 1: five and six-membered heterocycles. Egyptian Journal of Chemistry, 61(5), 897-937.18. https://doi.org/10.21608/ejchem.2018.4130.1362
Kramell, A. E., García-Altares, M., Pötsch, M., Kluge, R., Rother, A., Hause, G., ... & Csuk, R. (2019). Mapping natural dyes in archeological textiles by imaging mass spectrometry. Scientific Reports, 9(1), 2331. https://doi.org/10.1038/s41598-019-38706-4
Lech, K., Wilicka, E., Witowska‐Jarosz, J., & Jarosz, M. (2013). Early synthetic dyes–a challenge for tandem mass spectrometry. Journal of Mass Spectrometry, 48(2), 141-147. https://doi.org/10.1002/jms.3090
Manhita, A., Ferreira, V., Vargas, H., Ribeiro, I., Candeias, A., Teixeira, D., ... & Dias, C. B. (2011). Enlightening the influence of mordant, dyeing technique and photodegradation on the colour hue of textiles dyed with madder–A chromatographic and spectrometric approach. Microchemical Journal, 98(1), 82–90. https://doi.org/10.1007/s00216-011-4858-x
Mathur, N., Bhatnagar, P., & Bakre, P. (2006). Assessing mutagenicity of textile dyes from Pali(Rajasthan) using Ames bioassay. Applied Ecology and Environmental Research, 4(1), 111-118
Mehrparvar, L., Safapour, S., Sadeghi-Kiakhani, M., & Gharanjig, K. (2016). A cleaner and eco-benign process for wool dyeing with madder, Rubia tinctorum L., root natural dye. International Journal of Environmental Science and Technology, 13(11), 2569–2578. https://doi.org/10.1007/s13762-016-1060-x
Pickering, A. (2005). Decentering sociology: Synthetic dyes and social theory. Perspectives on Science, 13(3), 352–405.
Rather, L. J., Shabbir, M., Bukhari, M. N., Shahid, M., Khan, M. A., & Mohammad, F. (2016). Ecological dyeing of woolen yarn with Adhatoda vasica natural dye in the presence of biomordants as an alternative copartner to metal mordants. Journal of Environmental Chemical Engineering, 4(3), 3041–3049. https://doi.org/10.1016/j.jece.2016.06.019
Recep, K., Emine, T., & Gökhan, E. (2014). Dyeing properties and analysis by RP-HPLC-DAD of silk fabrics dyed with madder (Rubia tinctorum L.). Journal of Textile Science and Engineering, 4(154), 2. https://doi.org/10.4172/2165-8064.1000154
Repon, M. R., Dev, B., Rahman, M. A., Jurkonienė, S., Haji, A., Alim, M. A., & Kumpikaitė, E. (2024). Textile dyeing using natural mordants and dyes: a review. Environmental Chemistry Letters, 22(3), 1473-1520. https://doi.org/10.1007/s10311-024-01716-4
Saad, F., Hassabo, A., Othman, H., Mosaad, M. M., & Mohamed, A. L. (2022). A valuable observation on thickeners for valuable utilisation in the printing of different textile fabrics. Egyptian Journal of Chemistry, 65(4), 431–448. https://doi.org/10.21608/ejchem.2021.96612.4521
Samanta, A. K., & Agarwal, P. (2009). Application of natural dyes on textiles. Indian Journal of Fibre & Textile Research, 34(4), 384–399.
Saxena, S., & Raja, A. S. M. (2014). Natural dyes: sources, chemistry, application and sustainability issues. In Roadmap to sustainable textiles and clothing: eco-friendly raw materials, technologies, and processing methods (pp. 37-80). Singapore: Springer Singapore. https://doi.org/10.1007/978-981-287-065-0_2
Shams Nateri, A., & Dehnavi, E. (2022). The effect of mordanting method on the absorption behavior of natural dyes. Pigment & Resin Technology, 51(5), 489–498. https://doi.org/10.1108/PRT-05-2021-0050.
Sukenik, N., Iluz, D., Amar, Z., Varvak, A., Workman, V., Shamir, O., & Ben-Yosef, E. (2017). Early evidence (late 2nd millennium BCE) of plant-based dyeing of textiles from Timna, Israel. PLoS One, 12(6), e0179014. https://doi.org/10.1371/journal.pone.0179014.
Yurdakul, A., & Atav, R. (2016). Boya-baskı esasları [Fundamentals of dye printing]. Ege Üniversitesi Tekstil ve Konfeksiyon Araştırma-Uygulama Merkezi Yayını.
Yusuf, M., Mohammad, F., Shabbir, M., & Khan, M. A. (2016). Eco-dyeing of wool with Rubia cordifolia root extract: Assessment of the effect of Acacia catechu as biomordant on color and fastness properties. Textiles and Clothing Sustainability, 2(1), 10. https://doi.org/10.1186/s40689-016-0021-6
Varjani, S., Rakholiya, P., Ng, H. Y., You, S., & Teixeira, J. A. (2020). Microbial degradation of dyes: An overview. Bioresource Technology, 314, 123728. https://doi.org/10.1016/j.biortech.2020.123728
Zarkogianni, M., Mikropoulou, E., Varella, E., & Tsatsaroni, E. (2011). Colour and fastness of natural dyes: revival of traditional dyeing techniques. Coloration Technology, 127(1), 18-27. https://doi.org/10.1111/j.1478-4408.2010.00273.x
Zhao, Y., & Liu, J. (2021). Extraction of tea natural dye and its dyeing properties on cotton fabrics. AATCC Journal of Research, 8(2_suppl), 86–90. https://doi.org/10.14504/ajr.8.S2.17

Ayrıntılar

Birincil Dil

İngilizce

Konular

Tekstil Terbiyesi

Bölüm

Araştırma Makalesi

Yazarlar

Büşra Nur Seven
0009-0005-4399-2972
Türkiye

Elif Utlu
0009-0003-4985-2802
Türkiye

Gizem Ceylan Türkoğlu ^*
0000-0001-5809-0916
Türkiye

Gökhan Erkan
0000-0002-2239-9556
Türkiye

Gülşah Ekin Kartal
0000-0001-7364-7049
Türkiye

Yayımlanma Tarihi

3 Mart 2026

Gönderilme Tarihi

26 Eylül 2025

Kabul Tarihi

17 Kasım 2025

Yayımlandığı Sayı

Yıl 2026 Cilt: 29 Sayı: 1

DOI

https://doi.org/10.17780/ksujes.1791729

IZ

https://izlik.org/JA78XD66DE

Kaynak Göster

RIS / Bibtex

APA

Seven, B. N., Utlu, E., Türkoğlu, G. C., Erkan, G., & Kartal, G. E. (2026). EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER). Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 29(1), 187-197. https://doi.org/10.17780/ksujes.1791729

AMA

1.Seven BN, Utlu E, Türkoğlu GC, Erkan G, Kartal GE. EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER). Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi. 2026;29(1):187-197. doi:10.17780/ksujes.1791729

Chicago

Seven, Büşra Nur, Elif Utlu, Gizem Ceylan Türkoğlu, Gökhan Erkan, ve Gülşah Ekin Kartal. 2026. “EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER)”. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi 29 (1): 187-97. https://doi.org/10.17780/ksujes.1791729.

EndNote

Seven BN, Utlu E, Türkoğlu GC, Erkan G, Kartal GE (01 Mart 2026) EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER). Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi 29 1 187–197.

IEEE

[1]B. N. Seven, E. Utlu, G. C. Türkoğlu, G. Erkan, ve G. E. Kartal, “EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER)”, Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, c. 29, sy 1, ss. 187–197, Mar. 2026, doi: 10.17780/ksujes.1791729.

ISNAD

Seven, Büşra Nur - Utlu, Elif - Türkoğlu, Gizem Ceylan - Erkan, Gökhan - Kartal, Gülşah Ekin. “EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER)”. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi 29/1 (01 Mart 2026): 187-197. https://doi.org/10.17780/ksujes.1791729.

JAMA

1.Seven BN, Utlu E, Türkoğlu GC, Erkan G, Kartal GE. EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER). Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi. 2026;29:187–197.

MLA

Seven, Büşra Nur, vd. “EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER)”. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, c. 29, sy 1, Mart 2026, ss. 187-9, doi:10.17780/ksujes.1791729.

Vancouver

1.Büşra Nur Seven, Elif Utlu, Gizem Ceylan Türkoğlu, Gökhan Erkan, Gülşah Ekin Kartal. EFFECTS OF PRE- AND POST-MORDANTING WITH DIFFERENT MORDANTS ON THE PRINTING OF WOOL FABRICS USING RUBIA TINCTORUM L. (MADDER). Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi. 01 Mart 2026;29(1):187-9. doi:10.17780/ksujes.1791729