Yıl 2015,
Cilt: 18 Sayı: 2, 49 - 53, 24.12.2015
Öz
The Schiff base ligand containing -N=N- group, 4-((E)-(4-bromophenyl)diazenyl)-2-((E)-(phenylimino)methyl)phenol (L1H) (Fig. 1), and its CoII, CuII, NiII, ZnII and FeIII complexes have been prepared and characterized in previous study. According to analytical, UV-visible and IR data, the metal complexes are formed by coordination of the N, O atoms of the ligands and metal:ligand ratio was found to 1:2 for all the complexes. In this study, photoluminescence properties of L1H and its metal complexes were investigated.
Anahtar Kelimeler
Kaynakça
- Shaghaghi, Z., (2014), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Spectrochim Acta A, 131, 67.
- Atabey, H., Findik, E., Sari, H., Ceylan, M., (2014), “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 38(1), 109.
- Huang, D. X., Wang, C. X., Song, Y. B., (2013), “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 83(12), 2361.
- Farhadi. S., Sepahvand, S., (2010), “Na4W10O32/ZrO2 nanocomposite prepared via a sol-gel route: A novel, green and recoverable photocatalyst for reductive cleavage of azobenzenes to amines with 2-propanol”, J Mol Catal A-Chem., 318(1-2), 75.
- Govindaswamy. P., Sinha. C., Kollipara. M. R., (2005), “Syntheses and characterization of eta(5)cyclopentadienyl and eta(5)-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(eta(5)C5H5)Ru(PPh3)(C6H5-N=N-C3H3N2)]”, J Organomet Chem., 690(14), 3465.
- Shinar, J., (Ed.), Organic Light-Emitting Devices: A Survey, Springer-Verlag, NY, 2004.
- Hens, A., Mondal, P., Rajak, K. K., (2015), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Polyhedron, 85, 255.
- Wang, J., Ha, C.-S., (2010), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Tetrahedron, 66, 1846.
- Cheng, Y.-F., Zhao, D.-T., Zhang, M., Liu, Z.-Q., Zhou, Y.-F., Shu, T.-M., Li, F.-Y., Yi, T., Huang, C.-H., (2006), “Azo 8-hydroxyquinoline benzoate as selective chromogenic chemosensor for Hg2+ and Cu2+”, Tetrahedron Lett., 47, 6413.
- A. Misra, M. Shahid, J. Phys. Chem., (2010), “Molecular Dynamics of Phycocyanobilin Binding Bacteriophytochromes: A Detailed Study of Structural and Dynamic Properties”, 114, 16726.
- M. Kumar, J. Nagendra Babu, V. Bhalla, A. Dhir, (2009), Inorg. Chem. Commun., “Chromogenic sensing of Cu(II) by imino linked thiacalix[4]arene in mixed aqueous environment”, 12, 332.
- Lou, X., Qin, J., Li, Z., (2009), “Colorimetric cyanide detection using an azobenzene acid in aqueous solutions”, Analyst, 134, 2071.
- Arabahmadi, R., Orojloo, M., Amani, S., (2014), “Qualitative discrimination between organic and biodynamic Sangiovese red wines for authenticity”, Anal. Methods, 6, 7384.
- Gunnlaugsson, T., Leonard, J. P., (2002), “Synthesis and evaluation of colorimetric chemosensors for monitoring sodium and potassium ions in the intracellular concentration range”, J. Chem. Soc., Perkin Trans., 2,1980.
- Arabahmadi, R., Amani, S., (2013), “Synthesis and studies of selective chemosensors for anions and cations by azo-containing salicylaldiminebased receptors”, J. Coord. Chem. 66 218.
- İkiz, M., İspir, E., Aytar, E., Karabuğa, Ş., Aslantaş, M., Çelik, Ö., Ulusoy, M., (2015), “Chemical fixation of CO2 into Cyclic Carbonates by azo-containing Schiff Bases metal complexes”, New Journal of Chemistry, 39(10), 7786.
- Odabasoglu M, Albayrak C, Ozkanca R, Aykan FZ, Lonecke P. Some polyhydroxy azoazomethine derivatives of salicylaldehyde: Synthesis, characterization, spectroscopic, molecular structure and antimicrobial activity studies. J Mol Struct. 2007;840(1-3):71-89.
- Ceyhan, G., Köse, M., Tümer, M., McKee, V., (2012), “Novel polymeric potassium complex: Its synthesis, structural characterization, photoluminescence and electrochemical properties”, J of Lumin, 132(3), 850.
Yıl 2015,
Cilt: 18 Sayı: 2, 49 - 53, 24.12.2015
Öz
Daha önceki çalışmada 4-((E)-(4-bromophenyl)diazenyl)-2-((E)-(phenylimino)methyl)phenol (L1H) ligandı ve bu ligamndın CoII, CuII, NiII, ZnII ve FeIII komplekslerinin sentezi ve karakterizasyonu yapılmış olup komplekslerin metal:ligand oranı 1:2 olacak şekilde oluştuğu gözlenmiştir. Bu çalışmada sentezi ve karakterizasyonu yapılan ligand ve komplekslerinin fotolüminesans özellikleri incelenmiştir
Anahtar Kelimeler
Kaynakça
- Shaghaghi, Z., (2014), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Spectrochim Acta A, 131, 67.
- Atabey, H., Findik, E., Sari, H., Ceylan, M., (2014), “Comparison of chelating ability of NO-, NS-, ONS-, and ONO-type Schiff base derivatives and their stability constants of Bis-complexes with copper(II)”, Turk J Chem., 38(1), 109.
- Huang, D. X., Wang, C. X., Song, Y. B., (2013), “Immobilized complexes of the salen Schiff's base with metal as oxidation catalysts”, Russ J Gen Chem., 83(12), 2361.
- Farhadi. S., Sepahvand, S., (2010), “Na4W10O32/ZrO2 nanocomposite prepared via a sol-gel route: A novel, green and recoverable photocatalyst for reductive cleavage of azobenzenes to amines with 2-propanol”, J Mol Catal A-Chem., 318(1-2), 75.
- Govindaswamy. P., Sinha. C., Kollipara. M. R., (2005), “Syntheses and characterization of eta(5)cyclopentadienyl and eta(5)-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(eta(5)C5H5)Ru(PPh3)(C6H5-N=N-C3H3N2)]”, J Organomet Chem., 690(14), 3465.
- Shinar, J., (Ed.), Organic Light-Emitting Devices: A Survey, Springer-Verlag, NY, 2004.
- Hens, A., Mondal, P., Rajak, K. K., (2015), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Polyhedron, 85, 255.
- Wang, J., Ha, C.-S., (2010), “Synthesis, structure and photoluminescence properties of functionalized azoimine ligands and their nickel complexes”, Tetrahedron, 66, 1846.
- Cheng, Y.-F., Zhao, D.-T., Zhang, M., Liu, Z.-Q., Zhou, Y.-F., Shu, T.-M., Li, F.-Y., Yi, T., Huang, C.-H., (2006), “Azo 8-hydroxyquinoline benzoate as selective chromogenic chemosensor for Hg2+ and Cu2+”, Tetrahedron Lett., 47, 6413.
- A. Misra, M. Shahid, J. Phys. Chem., (2010), “Molecular Dynamics of Phycocyanobilin Binding Bacteriophytochromes: A Detailed Study of Structural and Dynamic Properties”, 114, 16726.
- M. Kumar, J. Nagendra Babu, V. Bhalla, A. Dhir, (2009), Inorg. Chem. Commun., “Chromogenic sensing of Cu(II) by imino linked thiacalix[4]arene in mixed aqueous environment”, 12, 332.
- Lou, X., Qin, J., Li, Z., (2009), “Colorimetric cyanide detection using an azobenzene acid in aqueous solutions”, Analyst, 134, 2071.
- Arabahmadi, R., Orojloo, M., Amani, S., (2014), “Qualitative discrimination between organic and biodynamic Sangiovese red wines for authenticity”, Anal. Methods, 6, 7384.
- Gunnlaugsson, T., Leonard, J. P., (2002), “Synthesis and evaluation of colorimetric chemosensors for monitoring sodium and potassium ions in the intracellular concentration range”, J. Chem. Soc., Perkin Trans., 2,1980.
- Arabahmadi, R., Amani, S., (2013), “Synthesis and studies of selective chemosensors for anions and cations by azo-containing salicylaldiminebased receptors”, J. Coord. Chem. 66 218.
- İkiz, M., İspir, E., Aytar, E., Karabuğa, Ş., Aslantaş, M., Çelik, Ö., Ulusoy, M., (2015), “Chemical fixation of CO2 into Cyclic Carbonates by azo-containing Schiff Bases metal complexes”, New Journal of Chemistry, 39(10), 7786.
- Odabasoglu M, Albayrak C, Ozkanca R, Aykan FZ, Lonecke P. Some polyhydroxy azoazomethine derivatives of salicylaldehyde: Synthesis, characterization, spectroscopic, molecular structure and antimicrobial activity studies. J Mol Struct. 2007;840(1-3):71-89.
- Ceyhan, G., Köse, M., Tümer, M., McKee, V., (2012), “Novel polymeric potassium complex: Its synthesis, structural characterization, photoluminescence and electrochemical properties”, J of Lumin, 132(3), 850.
Toplam 18 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Bölüm | Araştırma Makalesi |
| Yazarlar | |
| Yayımlanma Tarihi | 24 Aralık 2015 |
| Gönderilme Tarihi | 23 Aralık 2015 |
| Yayımlandığı Sayı | Yıl 2015 Cilt: 18 Sayı: 2 |